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A new physical method, namely boiling treatment, was developed to aid flotation separation of acrylonitrile–butadiene–styrene (ABS) and polystyrene (PS) plastics. Boiling treatment was shown to be effective in producing a hydrophilic surface on ABS plastic. Fourier Transform Infrared analysis was conducted to investigate the mechanism of boiling treatment of ABS. Surface rearrangement of polymer may be responsible for surface change of boiling treated ABS, and the selective influence of boiling treatment on the floatability of boiling treated plastics may be attributed to the difference in the molecular mobility of polymer chains. The effects of flotation time, frother concentration and particle size on flotation behavior of simple plastic were investigated. Based on flotation behavior of simple plastic, flotation separation of boiling treatment ABS and PS with different particle sizes was achieved efficiently. The purity of ABS and PS was up to 99.78% and 95.80%, respectively; the recovery of ABS and PS was up to 95.81% and 99.82%, respectively. Boiling treatment promotes the industrial application of plastics flotation and facilitates plastic recycling. 相似文献
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With large quantity of flux (Na2CO3), lead can be recovered from the funnel glass of waste cathode-ray tubes via reduction–melting at 1000 °C. To reduce flux cost, a technique to recover added flux from the generated oxide phase is also important in order to recycle the flux recovered from the reduction–melting process. In this study, the phase separation of sodium and the crystallization of water-soluble sodium silicates were induced after the reduction–melting process to enhance the leachability of sodium in the oxide phase and to extract the sodium from the phase for the recovery of Na2CO3 as flux. A reductive atmosphere promoted the phase separation and crystallization, and the leachability of sodium from the oxide phase was enhanced. The optimum temperature and treatment time for increasing the leachability were 700 °C and 2 h, respectively. After treatment, more than 90% of the sodium in the oxide phase was extracted in water. NaHCO3 can be recovered by carbonization of the solution containing sodium ions using carbon dioxide gas, decomposed to Na2CO3 at 50 °C and recycled for use in the reduction–melting process. 相似文献
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Determinationofpolycyclicaromatichydrocarbonswithsupercriticalfluidextractionandchromatography(SFE/SFC)YaoWeixi(ResearchCente... 相似文献
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利用正硅酸乙酯水解制备得到"核-壳"结构的磁性吸附剂MZF@SiO2(MZFS),采用X射线衍射(XRD)、透射电子显微镜(TEM)、振动样品磁强计(VSM)和傅利叶变换红外光谱(FT-IR)对MZFS的结构和性能进行表征,并研究MZFS对偶氮染料中性红(NR)的吸附性能.结果表明,拟二级动力学和Freundlich模型均能较好地描述该吸附过程,吸附过程的速率控制步骤为化学吸附;吸附自由能E为0.472-0.773kJ/mol,△G为-20~0kJ/mol,△H为37.5kJ/mol,表明该过程是以物理吸附为主的自发吸热过程.FT-IR结果表明吸附的主要作用力为分子间氢键,MZFS可采用15% wt H2O2进行原位再生.研究结果能为偶氮染料废水处理方法的革新提供基础理论数据. 相似文献
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IntroductionThevolatileorganiccompounds (VOCs)isoneofthefivemajorprimarygasouspollutants(particulates,SOx ,NOx ,VOCs,CO) ,inwhich 31VOCspollutantsincludingbenzene,acroleinandaliphatic ,aromatichalogenatedhydrocarbonsarelistedinall 1 2 9prioritypollutantsbytheEnv… 相似文献
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悬浮填料滤池取代传统二沉池的中试研究 总被引:2,自引:0,他引:2
研究了一种生物氧化固液分离一体化新工艺,该工艺是在投料倒置AAO工艺好氧池末端设置悬浮填料滤池,从而取消原有工艺的二沉池。在现场与具有二沉池的传统投料倒置AAO工艺的中试对比试验中,滤池表面负荷控制为2.5m3/m2.h(进水量为2.0m3/h),出水SS达到18mg/L,低于同等进水量条件下投料倒置AAO工艺二沉池出水SS值(26mg/L),各项生化指标均满足处理要求。研究表明,新工艺在省却二沉池、节省占地的同时,充分发挥滤池内生物降解作用,达到一级出水水质标准的要求。 相似文献