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301.
《环境科学学报(英文版)》2023,35(4):396-407
Based on the experimental and theoretical methods, the NO selective catalytic oxidation process was proposed. The experimental results indicated that lattice oxygen was the active site for NO oxide over the -MnO2(110) surface. In the theoretical study, DFT (density functional theory) and periodic slab modeling were performed on an -MnO2(110) surface, and two possible NO oxidation mechanisms over the surface were proposed. The non-defect -MnO2(110) surface showed the highest stability, and the surface Os (the second layer oxygen atoms) position was the most active and stable site. O2 molecule enhanced the joint adsorption process of two NO molecules. The reaction process, including O2 dissociation and O=N-O-O-N=O formation, was calculated to carry out the NO catalytic oxidation mechanism over -MnO2(110). The results showed that NO oxidation over the -MnO2(110) surface exhibited the greatest possibility following the route of O=N-O-O-N=O formation. Meanwhile, the formation of O=N-O-O-N=O was the rate-determining step. 相似文献
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Experimental data are presented to test and validate a kinetic model for the oxidation of 2-chlorophenol wastewater by photo-assisted Fenton process. The data showed that this process had produced good effects under acidic conductions. Up to 90% 2-chlorophenol was removed after 90-minute reaction time with H2O2 of 25% CODCr. in, while in UV/H2O2 system ordy 16.8% 2-chlorophenol was removed after one hour treatment. The optimal pH in this reaction occurred between pH 3.0 and pH 4.0. The reaction kinetics for photo-assisted Fenton process experimented in this research was investigated. Kinetic models were proposed for the treatment of 2-chlorophenol wastewater. The reaction was found to follow the 2nd order. The equations of reaction kinetics are as follows:-d[RH]/dt=KRH[RH][H2O2]0exp(-KH2o2t);-d[CODCr]/dt=KCODCr[CODCr][H2O2]0exp(-K′t).The prediction of the models was found to be in a good agreement with experimental results, thus confimfing the proposed reaction mechanism. 相似文献
305.
It has been shown that the potential for environmental, and financial improvements through the increased substitution of in-person meetings by virtual communication is considerable. However, it has also been shown that this potential is not automatically realized by investing in the technology that can enable virtual meetings. This paper describes two case studies that explored the factors that influenced communication and meeting behavior. A number of drivers and barriers for virtual meetings are identified, and, in addition, measures are proposed to improve the utilization of virtual tools for business communication. 相似文献
306.
The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity. 相似文献
307.
可持续发展与战略环境评价 总被引:3,自引:0,他引:3
可持续发展的实施需要具体的手段和方法。在对可持续发展和战略环境评价(SEA)的概念、内涵和特征进行概略分析的基础上,通过分析两者之间的内在联系,着重考察以SEA实施可持续发展的理论依据和方法。结果表明:SEA能为实施可持续发展提供整体性方法,全面考虑战略替代方案,系统分析累积环境影响,建立环境监控计划及运用适应性环境管理方法,扩展决策过程中的公众参与。认为SEA是实施可持续发展的一种重要工具。为了贯彻实施我国的可持续发展战略,应在我国进一步开展SEA的理论和实践研究。 相似文献
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309.
磁性吸附材料CuFe2O4吸附砷的性能 总被引:10,自引:1,他引:10
根据Cu(Ⅱ)和Fe(Ⅲ)都对砷有较强的亲和性,制备了同时含有Cu(Ⅱ)和Fe(Ⅲ)的、可用磁分离方法进行分离回收的磁性吸附材料CuFe2O4,并对其进行了表征及吸附砷的性能研究.结果表明,该吸附剂对砷的吸附能力与溶液pH有关,在弱酸性及中性条件下,吸附砷的能力最强,而对As(V)的吸附能力比对As(Ⅲ)更强些,在平衡浓度为10μg/L时,其吸附容量可达10mg/g左右,可以很容易地将水中浓度为1~20mg/L的As(V)降到10μg/L以下.实验考察了几种无机阴离子对吸附砷的影响,表明较高浓度(砷浓度的20倍)的硫酸盐对As(Ⅲ)和As(V)的吸附均有一定影响,盐酸盐及磷酸盐则影响不明显;负载的As(V)可较容易地用0.1mol/L NaOH洗脱下来,使吸附剂再生,而As(Ⅲ)则难以洗脱,这与2种价态砷的吸附机理不同有关. 相似文献
310.
动物的起源主要依赖于氨基酸等有机小分子在海水中能否进行脱水缩合反应而生成生物高分子,后者则依赖于海水pH值升高和大气CO2浓度降低的历史演化进程。有机小分子只有在海水pH值演化到近中性,即寒或纪时彼此才能发生脱水缩合反应而合成生物高分子。只有大气CO2分压降到1000Pa以下,即泥盆纪以后,陆地上才能出现稳定的土壤层和植物,动物也才能从海洋扩展到陆地。随后大气CO2浓度继续降低导致了气温下降和植物生长率的衰减,促使动物进一步演化。 相似文献