Cr(Ⅵ)在Fe(Ⅲ)-柠檬酸盐体系中紫外光还原研究

研究了在紫外光照射下,Fe(Ⅲ)-柠檬酸盐溶液对Cr(Ⅵ)的光还原反应.同时,考察了溶液pH值、Fe(Ⅲ)浓度、柠檬酸盐浓度、Cr(Ⅵ)初始浓度对光还原效率的影响,并分析了光还原反应的动力学.研究结果表明,Fe(Ⅲ)-柠檬酸盐体系能光还原Cr(Ⅵ),在pH为2.0～6.0的范围内,Cr(Ⅵ)的还原率随着溶液初始pH值的降低而增大.当pH值为2.0、Fe(Ⅲ)浓度为10μmol·L-1、柠檬酸盐浓度为250μmol·L-1及Cr(Ⅵ)初始浓度为19.2μmol·L-1时,光照反应8min后Cr(Ⅵ)的最大还原率达到100%,但当pH值增加到6.0时,Cr(Ⅵ)的最大还原率下降到19%;当Cr(Ⅵ)的初始浓度在9.6～96.0μmol·L-1的范围内时,Cr(Ⅵ)光还原反应的初始速率随着Fe(Ⅲ)、柠檬酸盐(cit3)、Cr(Ⅵ)初始-浓度的增加而增加.表观动力学方程为:-dCCr(Ⅵ)/dt=0.1019[Cr(Ⅵ)]0.[Fe(Ⅲ)]0.[cit3]0..536-25     

可渗透反应复合电极法对铬(Ⅵ)污染土壤的电动修复

将Fe0、沸石等活性材料附着在电极上构成可渗透反应复合电极,以Cr(Ⅵ)污染土壤为处理对象,对电动修复过程中可渗透反应复合电极法对土壤pH的控制、Cr的去除效果以及形态变化进行了研究.结果表明,添加可渗透反应材料的复合电极法比单一电极法无论在土壤pH控制还是Cr的去除方面都有明显的改善和提高,其中以在阳极同时添加Fe0和沸石效果最为显著.在施加2 V.cm-1的直流电压,运行5 d后,相比在阳极单纯添加沸石或Fe0可渗透反应层,添加"Fe0+沸石"反应层能在最大程度上减小阳极土壤pH值的波动,可将土壤pH值控制在5.5～8.5范围内,土壤中任意位置Cr(Ⅵ)的去除率可提高到97%以上,土壤中残留的Cr(Ⅲ)更少,可渗透反应层对Cr的截留量可分别提高8倍和1.8倍,并将98%的Cr(Ⅵ)转化为低毒的Cr(Ⅲ).研究结果为开发具有实用意义的可渗透反应复合电极修复技术提供了理论依据.     

盐酸法提取污泥中蛋白质过程的研究

为了探索剩余污泥中蛋白质的提取方法,采用盐酸和氢氧化钠对污泥中蛋白质进行了提取,并对提取液进行了紫外光谱分析。结果证明盐酸提取法更有利于污泥中蛋白质的提取操作,并可以保证蛋白质质量。随后,实验考察了温度、污泥浓度、盐酸浓度以及操作时间对提取液中蛋白质浓度的影响情况。结果表明:蛋白质浓缩随温度呈先慢后快的增加趋势,随污泥浓度呈线性增加趋势,随盐酸浓度呈先快后慢增加趋势,适当延长时间有利于提升提取液中的蛋白质浓度。     

Intensification of adsorption process by using the pyrolytic char from waste tires to remove chromium(Ⅵ) from wastewater

Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C-OH, C=O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) has been identified as pseudo-second- order kinetics. The rate constants of adsorption have been evaluated.     

泰州大桥工程项目建设单位安全管理实践探讨

建设单位做好安全管理工作,对保障大型工程项目建设的顺利进行,以及施工现场安全有着举足轻重的作用。泰州大桥项目作为特大桥梁工程,参建单位及人员众多,施工管理及组织非常复杂,安全管理工作面临着众多难点。本文从建设单位的角度出发,探讨了泰州大桥安全管理工作中的安全生产氛围、现场安全防护、高处作业、特种设备、特种作业人员、临时用电等八个重点内容,严把设计关、狠抓招标准入、强化制度建设、落实各级安全检查、实施安全生产风险抵押金考核等五种管理手段,以及委托专业机构提供现场安全管理及咨询、在全桥范围内建立和推行职业健康安全管理体系的探索性工作。此安全管理模式对其他大型工程项目建设单位抓好安全管理工作具有一定的借鉴意义。     

重大危险源安全与自动化监控系统

对重大危险源实施系统、有效的安全监控是重大工业事故预防控制体系中的关键环节。文中给出了针对重大危险源监控全安全生命周期过程的整体实施流程,提出了重大危险源危险与风险评估的重点,探讨了重大危险安全与自动化监控的三层构建框架和工作过程,研究了安全系统与基本过程控制系统相独立的监控方式,给出了安全仪表系统的设计要求。     

基于可靠度理论的RBI修正模型研究

基于风险的检测技术包括定性RBI判断和定量RBI计算,定性判断得到风险相对的高低,风险相对较低者则不必进行定量RBI计算,风险高者再进行下一步定量RBI计算。在API581中,国外风险分析统计表明,石化企业的风险分布范围有一个所谓的"二八"现象,即"80%的风险是由20%的设备引起",中高风险以上的设备范围一般在20%左右。但我国十套装置风险分析结果发现,这个结论在我国并不适用,我国中高风险设备往往在40%左右。论文分析了API581在中国应用的局限性,引入可靠度理论计算设备失效概率,预估未来的失效概率或可靠度,可以完整地以RBI方法在得知失效后果和失效概率下,评估出此设备在整个系统中所处的地位,从而适当地分配检测、维修资源,在RBI完成后再进行风险评价进而完成风险评估过程。     

装备使用风险管理模型研究

在军事行动中,使用了大量复杂的装备系统,存在相当多的风险因素。如果对其中的风险因素管理不善,风险转化为事故,将造成极大的损失,严重影响部队的战斗力。装备使用风险管理是针对这一问题提出的概念。装备使用风险管理是在提高绩效和最大化作战能力时,用来识别、评估和控制风险的一个逻辑化的决策过程。本文通过分析装备使用风险管理的系统模型——"人-装备-环境-管理-任务"之间的关系及相互作用,并且详细的说明了装备使用风险管理的过程,危险识别、风险评估、分析风险控制、风险控制决策、实施风险控制、监督与评审等六个步骤的过程模型,探讨了风险管理的实施,并且认为风险管理过程的目标就是达到5M模型的最优化。为部队实施风险管理提供参考。     

碱改性活性炭对VOCs的吸附性能

选用3种经氢氧化钠改性的活性炭,研究了其对4种代表性VOCs(丁酮、乙酸乙酯、甲苯和四氯化碳)的吸附规律。结果表明:活性炭经碱改性后吸附性能有较大改善,吸附量的大小与其比表面积呈正相关性,而其比表面积多为微孔提供;改性活性炭对有机气体的吸附以物理吸附为主;吸附质的相对分子质量、密度、熔点与其在改性活性炭上的吸附量具有线性相关性,而沸点、饱和蒸气压、分子动力学直径则与吸附量无明显相关性;对于同一吸附剂,170℃再生时的性能最好,130℃次之,210℃最差。     

Changes in chromium distribution during the electrodialytic remediation of a Cr (VI)-contaminated soil

A laboratory study has been carried out to determine the feasibility of in situ remediation of chromium (VI)-contaminated soil using electrodialysis in relation to its speciation in soil. This technique is best suited for low-permeability soils or sediments, which may be difficult to remediate by other means and implies the application of a low-intensity direct current to the soil, which is separated from the electrode compartments by ion-exchange membranes. A clayey soil was prepared for use in the experiments and was characterized before being mixed with a solution of potassium dichromate for several days to produce a final Cr content of 4,056 mg/kg of soil dry wt. Remediation tests were carried out under constant-voltage conditions for periods of 7–14 days and the evolution of applied current to the cell, pH, and conductivity of the electrolytes were recorded periodically. Fractionation of chromium was determined for soil samples before and after remediation using a standardized four-step sequential extraction procedure (SEP) with acetic acid, hydroxylamine, hydrogen peroxide, and aqua regia solutions. Results show that chromium is mobilized from the most labile phases (soluble/exchangeable/carbonate). In a 15 V test, SEP results show that the amount of chromium extracted in the first step drops from 80% to 9%, but also that changes in the total chromium distribution occur during the treatment with some transferred to other soil phases that are more difficult to mobilize.