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91.
通过色谱柱、固定相以及载气流速的选择性实验 ,提高了气相色谱仪在观测地下水中H2 、He分离效能和检测效能。本文对此作介绍 ,以期对使用气相色谱仪进行地下水H2 、He观测的台站能有所启发和借鉴 相似文献
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在单因素试验、Plackett-Burman设计试验基础上,采用Box-Behnken响应面法对养殖水体中炔雌醇(EE2)的固相萃取条件进行优化。结果表明,洗脱液体积、洗脱液组成和淋洗液体积是影响EE2固相萃取回收率的3个主要因素;EE2的最佳固相萃取条件为:水样pH值为3,进样流量为3.0 mL/min,淋洗液为体积分数为10%的甲醇水溶液,淋洗液体积7.0 mL,洗脱液为乙酸乙酯-正己烷混合溶液(体积比为9∶1),洗脱液体积12.0 mL。该条件下养殖水样中EE2固相萃取回收率为81.6%~86.7%。 相似文献
95.
The purpose of the research was to improve prediction of response of buildings to blast waves by including the negative phase and considering clearing of both positive and negative phases. Commonly used structural design practices, which trace their origins to military design manuals, often ignore the negative phase as well as positive phase clearing. For high explosive threats, this approach is conservative in most circumstances. However, negative phase clearing had not previously been studied for blast waves, and the implications for structural response had not been evaluated. This paper presents results of modeling negative phase blast clearing behavior for a typical blast wave and discusses the differences from positive phase clearing. The implications of including positive and negative phase clearing in building blast damage analysis are also investigated through single-degree-of-freedom (SDOF) analyses.Blast waves from explosion sources like a vapor cloud explosion (VCE), pressure vessel burst or high explosive exhibit both positive and negative phases, and the relative magnitude of the positive and negative phases varies among explosion sources and the specific circumstances of each source. A fully reflected blast wave is produced if an incident blast wave were to strike an infinitely tall and wide wall in a normal orientation. Both the positive and negative phases of the blast wave are enhanced by the reflection process. However, when an incident blast wave strikes a wall of finite size in a normal orientation, rarefaction waves are created at the edges of the wall, and the rarefactions sweep down from the roof and inward from sides. The rarefaction waves result in a clearing effect for both the positive and negative phases.Clearing relieves some of the applied blast load on the reflected wall for the positive phase. However, this is not always the case for the negative phase. As shown by the results presented in this paper, clearing may either relieve or enhance the applied negative phase blast load, depending on the duration of the blast wave and the wall dimensions.The impact of negative phase clearing on structural response for generic building components was also investigated. Nonlinear SDOF methods were used to characterize response in terms of peak positive and negative displacements. It was found that the influence of the negative phase is significant and the peak structural response can occur during negative (outward) displacement. 相似文献
96.
为解决干冰膨胀烟丝生产线冷端液体工艺泵因机械密封长期超压和气缚现象造成损坏发生CO2泄漏而导致紧急停机抢修的问题,对干冰膨胀线冷端工艺罐系统进行了优化改进。在工艺泵吸口前管路引一根气相平衡管至工艺罐顶部,当泵吸口前管路有CO2液体时,输送管路内气化的CO2气体通过气相平衡管线释放回工艺罐内,不会进入工艺泵体内。应用结果表明,工艺泵内的憋压和气缚现象消失了,机械密封受到保护。改造前机械密封平均一个季度更换一次,改造后机械密封使用5年未损毁,达到保护干冰膨胀线冷端工艺泵机械密封的目的。 相似文献
97.
开展对典型可燃物燃烧烟尘的物化特性差异性研究,是全面了解烟尘信息的基础.基于可控条件下的燃烧试验,对典型可燃物燃烧烟尘物理特性和化学组分进行了分析.通过对比分析汽油燃烧烟尘、聚苯乙烯燃烧烟尘、ABS燃烧烟尘及柴油烟尘和正庚烷烟尘的透射电镜图片,对透射电镜图的紧凑性、复杂性及灰度值进行了深入分析,探讨了燃烧烟尘的物理差异性.利用固相微萃取-气质联用技术(SPME-GC-MS),对汽油燃烧烟尘、聚苯乙烯燃烧烟尘、ABS燃烧烟尘化学组分进行了分析和对比.通过燃烧烟尘的特征物质组分的分析,得到3种燃烧烟尘在特征物质的分布和出峰时间等方面的差异性.这些差异性可作为对烟尘来源及燃烧条件等因素判别的依据. 相似文献
98.
Analysis of trace dicyandiamide in stream water using solid phase extraction and liquid chromatography UV spectrometry 总被引:1,自引:0,他引:1
An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction. The extraction procedure (including loading, washing, and eluting) used a flow rate of 1.0 mL/min, and dicyandiamide was eluted with 20 mL of a methanol/acetonitrile mixture (V/V = 2:3), followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography–ultraviolet spectroscopy (HPLC–UV). Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge (with activated carbon). Separation was achieved on a ZIC®-Hydrophilic Interaction Liquid Chromatography (ZIC-HILIC) (50 mm × 2.1 mm, 3.5 μm) chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions (R2 > 0.999). Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations (RSDs, n = 3) were below 6.1% with a detection limit of 5.0 ng/mL for stream water samples. 相似文献
99.
利用紫外及红外吸收光谱等分析手段对365 nm光照下HNO3在气相与SiO2表面的光解反应进行了研究.考察了HNO3浓度、光照时间、相对湿度等条件对反应的影响.结果表明:随着HNO3浓度及光照时间的增加,光解产生的NO2和NO浓度均呈指数增加;无水汽情况下,400 Pa的HNO3光解45 min后,产生NO2及NO浓度比气相光解产生的分别高约3及1.7倍.HNO3光解产生的HONO的浓度随相对湿度的增加而呈线性增加,在SiO2颗粒物表面光解产生的NO2浓度随着相对湿度的增加而减少,而NO浓度则随之增大.400 Pa的HNO3光照45 min后,SiO2表面光解产生的HONO浓度是气相光解的3倍、SiO2表面暗反应的约30倍. 相似文献
100.
采用固相萃取超高效液相色谱串联质谱法(SPE-UPLC-MS/MS)同时测定地下水中涕灭威、克百威、2,4滴和五氯酚等4种农药残留,通过优化试验条件,使方法在10.0μg/L~200μg/L范围内线性良好,检出限为0.003μg/L~0.006μg/L.标准溶液低、中2个质量浓度水平的加标回收率为84.1% ~98.8... 相似文献