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131.
132.
133.
采用Ce-BTC(均苯三甲酸)为模板,通过尿素溶液浸渍合成了具有富氧空位/梯次结构的CeO2催化剂,并用X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、拉曼光谱(Raman)和紫外可见漫反射(DRS)等手段对其进行了表征.结果表明,与金属有机框架(MOFs)浸渍尿素高温煅烧可以获得金属氧化物/g-C3N4复合材料不同,Ce-BTC/尿素体系煅烧后产品中未检测到g-C3N4,这可能与CeO2的存在抑制了尿素分解产物的热缩聚过程,影响了g-C3N4的生成有关,但尿素的引入改变了Ce-BTC煅烧产物CeO2的氧空位浓度,且获得梯次结构.将具有富氧空位/梯次结构的CeO2-5用于光催化CO2还原,催化结果表明:反应4h的CO产率可达2.06μmol/g,CH4产率可达1.42μmol/g,性能是Ce-BTC未... 相似文献
134.
Exposure to iron oxides dusts may lead to lung cancers among exposed population. To evaluate the involvement of iron‐containing particles in lipid peroxidation by production of reactive oxygen species, hematite, magnetite (iron oxides), and crocidolite (asbestos compound) were tested. The peroxidation was followed by the evaluation of some degradation products of lino‐lenic acid. In a buffered medium, magnetite is higher active than hematite. The addition of an iron chelator (EDTA) or of a reducing agent (ascorbate) in this medium enhances the activity of hematite and magnetite, and the combination of both EDTA and ascorbate increases their activity. Crocidolite is the most active whatever the medium. The appearance of the EDTA‐iron‐oxygen complexes related to the reactivity of these oxides is postulated. These results suggest that the oxidizing activity triggered by hematite and magnetite, in a medium containing an iron chelator and a reducing agent, may lead to damages in biological medium. 相似文献
135.
E.I. Vanguelova S. Benham A.J. Moffat T. Nisbet N. Barsoum F. Bochereau S. Broadmeadow P. Taylor 《Environmental pollution (Barking, Essex : 1987)》2010,158(5):1857-1869
Long term trend analysis of bulk precipitation, throughfall and soil solution elemental fluxes from 12 years monitoring at 10 ICP Level II forest sites in the UK reveal coherent national chemical trends indicating recovery from sulphur deposition and acidification. Soil solution pH increased and sulphate and aluminium decreased at most sites. Trends in nitrogen were variable and dependant on its form. Dissolved organic nitrogen increased in bulk precipitation, throughfall and soil solution at most sites. Nitrate in soil solution declined at sites receiving high nitrogen deposition. Increase in soil dissolved organic carbon was detected - a response to pollution recovery, changes in soil temperature and/or increased microbial activity. An increase of sodium and chloride was evident - a possible result of more frequent storm events at exposed sites. The intensive and integrated nature of monitoring enables the relationships between climate/pollutant exposure and chemical/biological response in forestry to be explored. 相似文献
136.
John R. Thene Heinz G. Stefan Ekaterini I. Daniil 《Journal of the American Water Resources Association》1989,25(6):1189-1198
ABSTRACT: A method to evaluate the effect of hydropower development on downstream dissolved oxygen (DO) is presented for a low head dam. Water, previously aerated during release over spillways and under gates, is diverted through the hydropower facility without further aeration. The oxygen transfer that occurs as a result of air entrainment at the various release points of a dam is measured. Oxygen transfer efficiencies are calculated and incorporated into an oxygen transfer model to predict average release DO concentrations. This model is used to systematically determine the effect of hydropower operation on downstream DO. Operational alternatives are investigated and a simple operational guide is developed to mitigate the effects of hydropower operation. Combinations of reduced generation and optimal releases from the dam allow the hydropower facility to operate within DO standards. 相似文献
137.
Model simulations of dissolved oxygen characteristics of Minnesota lakes: Past and future 总被引:1,自引:0,他引:1
A deterministic, one-dimensional, unsteady numerical model has been developed, tested, and applied to simulate mean daily
dissolved oxygen (DO) characteristics in 27 lake classes in the state of Minnesota. Reaeration and photosynthesis are the
oxygen sources, while respiration, sedimentary, and biochemical water column oxygen demand are the sinks of oxygen in the
model. The lake classes are differentiated by surface area (A
s), maximum depth (H
max), and trophic status expressed as Secchi depth (Z
s). Because lake stratification is most important to lake oxygen dynamics, simulated DO characteristics are plotted in terms
of a stratification parameterA
s/H
max
0.25
and Secchi depthZ
s. Simulations provide DO profiles on a daily time scale. Specific DO characteristics of ecological and environmental interest
are epilimnetic DO, hypolimnetic DO, DO gradient from surface to bottom, and DO minima and maxima. Specific results are as
follows: Simulated mean daily and weekly DO values in the epilimnion of all lakes for both past and future climate scenarios
are near saturation over the summer season. Hypolimnetic DO values depend strongly on lake morphometry, trophic status, and
time throughout the summer season. Future climate conditions are specified as the historical records from 1955 to 1979, adjusted
(monthly) by the 2 × CO2 GISS model output to account for doubling of atmospheric CO2. With this climate change, weekly averaged epilimnetic DO is projected to drop by less than 2 mg/liter, and will remain above
7 mg/liter throughout the open water season. The hypolimnetic DO reductions after climate change are on the order of 2–8 mg/liter.
Periods of anoxia are longer by as much as 80 days. Those changes would alter water quality dynamics in lakes and have a profound
effect on lake ecosystems including indigenous fishes. The results presented are useful for evaluating environmental management
options. 相似文献
138.
Clifford W. Randall Bruce S. Huloher Paul H. King 《Journal of the American Water Resources Association》1970,6(4):648-660
The activated sludge process can remove significant amounts of phosphorus from sewage, but the removal efficiency is usually significantly reduced by the release of phosphate back to solution during subsequent treatment steps. This research presents a study of soluble phosphate release from activated sludge with emphasis on defining the factors that affect such release and the actual release mechanisms. Laboratory units were used for experimental purposes. The experiments were designed to study the relationship between soluble phosphate release and various environmental factors such as redox potential (ORP), dissolved oxygen (DO), pH, solids concentration, solids destruction, and sulfate salt addition. The effect of substrate utilization on phosphate uptake and the relationship between uptake characteristics and subsequent phosphate release were also studied. The results show that some phosphate storage occurs during aerobic substrate utilization. Following substrate utilization, activated sludge phosphate release is directly related to the amount of biological stress the organisms are subjected to, and the mechanism of release is primarily cell lysis. The phosphate released per unit sludge under anoxic conditions is relatively constant. Under normal environmental conditions, neither ORP or pH change have a significant affect on phosphate release. 相似文献
139.
S. H. Lin L. T. Fan C. L. Hwang 《Journal of the American Water Resources Association》1973,9(4):689-702
A modified transient version of the Streeter-Phelps model along with the energy balance equation is employed to analyze the effects of waste heat discharge from power plants on stream water quality. Analysis is also made to examine the effects of the upstream water quality and stream velocity on the downstream DO concentration level. The resulting coupled nonlinear hyperbolic partial differential equations representing the energy, BOD and DO concentrations are solved by the method of characteristics and simulated on a digital computer. Final numerical results indicate that the allowable quantity of thermal discharge does heavily depend on the upstream quality. 相似文献
140.