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111.
Y.F. Khalil 《Journal of Loss Prevention in the Process Industries》2013,26(6):1027-1038
This paper aims to develop quantitative insights based on measured deflagration parameters of hybrid mixtures of activated carbon (AC) dust and hydrogen (H2) gas in air. The generated experimental evidence is used to reject the claim of the null hypothesis (H0) that severity of deflagrations of H2/air mixtures always bound the severity of deflagrations of heterogenous combustible mixtures of AC dust/H2/air containing the same H2 concentrations as in the H2/air binaries. The core insights of this investigation show that the maximum deflagration pressure rise (ΔPMAX) and maximum rate of pressure rise ((dP/dt)MAX) of this hybrid mixture are greater than those corresponding to deflagrations of H2/air mixtures for all the dust and H2 concentrations being examined. The deflagration severity indices (KSt and ES) of the hybrid mixture containing 29 mol% H2 are found to be greater than those of the H2/air mixture containing 29 mol% H2. Also, the minimum explosible concentration (MEC) of the hybrid mixture is lower than that of the AC dust in air only. The insights gained should lead to better realization of the severity of a postulated safety-significant accident scenario associated with on-board cryoadsorption H2 storage systems for fuel-cell (FC) powered light-duty vehicles. The identified insights could also be relevant to other industrial processes where combustible dusts are generated in the vicinity of solvent vapors. Moreover, these insights should be useful for supporting quantitative risk assessment (QRA) of on-board H2 storage systems, designing improved safety measures for cryoadsorption H2 storage tanks, and guiding H2 safety standards and transportation regulations. 相似文献
112.
T. Matsuda M. Yashima M. Nifuku H. Enomoto 《Journal of Loss Prevention in the Process Industries》2001,14(6):449-453
The dust explosion committee of the Association of Powder Process Industry and Engineering, Japan recently established two testing standards for dust explosions. In the investigations for the standardization, many experimental data have been obtained for the dusts currently used in Japanese industries. Data for zirconium, tantalum and silicone dusts are presented to discuss the use of test methods, which have been accepted internationally. The test methods for dust explosions have to consider a variety of kinds and forms of dusts to be tested. 相似文献
113.
Temperature profile across the combustion zone propagating through an iron particle cloud 总被引:7,自引:0,他引:7
Jin-hua Sun Ritsu Dobashi Toshisuke Hirano 《Journal of Loss Prevention in the Process Industries》2001,14(6):463-467
Knowledge of the mechanism of combustion zone propagation during dust explosion is of great importance to prevent damage caused by accidental dust explosions. In this study, the temperature profile across the combustion zone propagating through an iron particle cloud is measured experimentally by a thermocouple to elucidate the propagation mechanism. The measured temperature starts to increase slowly at a position about 5 mm ahead of the leading edge of the combustion zone, increases quickly at a position about 3 mm ahead of the leading edge, reaches a maximum value near the end of the combustion zone, and then decreases. As the iron particle concentration increases, the maximum temperature increases at lower concentration, takes a maximum value, and then decreases at higher concentration. The relation between the propagation velocity of the combustion zone and the maximum temperature is also examined. It is found that the propagation velocity has a linear relationship with the maximum temperature. This result suggests that the conductive heat transfer is dominant in the propagation process of the combustion zone through an iron particle cloud. 相似文献
114.
Przemyslaw Zydak Rudolf Klemens 《Journal of Loss Prevention in the Process Industries》2007,20(4-6):417-426
Dust dispersion from a layer is a complicated problem, which has not been completely solved yet, especially if an Eulerian–Eulerian approach has to be used to model the two-phase dusty flow. In previous investigation, a phenomenological model of the dust dispersion process from a layer was developed, but the evaluation of the model revealed some weaknesses. In the current paper, the model of the dust dispersion process was presented and three improvements of the model were studied: Saffman force, Magnus force and particles collisions. The implementation of Magnus and Saffman forces into the code did not improve the numerical results and it was shown that it had very little influence on the dust lifting process, in case the phenomenological model of the layer is used. Some explanations were proposed in the paper. Besides, an empirical model of particles collisions was also added to the code and its influence on the results was studied. It was shown that the particles collisions model improved the obtained results, but further modifications are to be studied in the future. 相似文献
115.
116.
The bioprocessing industry is regarded as one of the fastest growing sectors with an estimated compound annual growth rate of 8.6%. The global market for biopharmaceuticals is projected to rise to a market value of USD 727.1 billion by 2025. Due to the unique nature of bioprocessing industries wherein micro-organisms are employed to manufacture the desired products, these processes are prone to additional hazards such as biological hazards and dust explosion amongst others. This necessitates the need to review the existing research in the fields of biotechnology and bioprocessing to reduce/eliminate these hazards and pave the path towards a safer bioprocessing industry. The study involves developing a framework comprising of studying the recent technologies that reduce/eliminate these hazards involved in the bioprocessing industries that include dust explosions, loss of containment of toxic chemicals, loss of containment of biohazard/active product ingredient, fire, and explosion and mapping these technologies with respect to inherent safety principles that include substitution, minimization, moderation and simplification with an overall objective of minimizing the risk associated with bioprocesses and moving towards an inherently safer bioprocessing industry. 相似文献
117.
Measurements of flammability and explosion parameters for dust/air mixtures require uniform dispersion of the dust cloud inside the test vessel. In a previous work, we showed that, in the standard 20 L sphere, the dust injection system does not allow generation of a uniform cloud, but rather high gradients of dust concentration are established. In this work, we used a previously validated three-dimensional CFD model to simulate the dust dispersion inside the 20 L sphere at different dust nominal concentrations (and fixed dust diameter). Results of numerical simulations have shown that, as the dust nominal concentration is increased, sedimentation prevails and, thus, when ignition is provided, the dust is mainly concentrated at the vessel walls. 相似文献
118.
Abstract The feasibility of using diatomaceous earth (diatomite) as an insecticidal dust was investigated under conditions of high (80%) and low (10%) relative humidity, using the adult red flour beetle, Tribolium castaneum. Tested were diatomite and two lots of a commercial formulation of the same diatomite, containing 0.2% pyrethrins and 1.0% piperonyl butoxide. For comparison, talcum and a talcum‐based commercial formulation, containing the same concentrations of pyrethrins and piperonyl butoxide, were included in the tests. The insects were exposed to 0.08 mg/cm2 of each material tested, equivalent to the label recommendation of 7 lb/acre for the diatomite‐based commercial insecticide. At 10% RH, higher doses of diatomite were also tested. Mortalities were determined at intervals for up to 84 hours. Diatomite caused no mortalities at the experimental concentration, regardless of RH. At about four times that rate and 10% RH, it caused less than 5% mortality. At 80% RH, the diatomite‐based product (P. C. P. Act #14074) was significantly more effective than the talcum‐based one (#13074). At 10% RH, however, the latter acted more quickly than the diatomite‐based formulations, but all produced nearly 100% mortality after 68 hours. The results are discussed in terms of the physical characteristics of diatomite and in terms of the modes of insecticidal actions of diatomite and pyrethrins. It is concluded that diatomite alone, despite its attractiveness to environmental interests, is not likely to become an effective agent for controlling red flour beetles and other pest insects with similar water‐proofing mechanisms. 相似文献
119.
The prevention of dust explosions is still a challenge for the process industry. Ignition, in particular, is a phenomenon that is still not completely understood. As a consequence, safety conditions pertaining to ignition suppression are rarely identified to an adequate level. It is well known that, in general, the ignition attitude of a dust depends on several factors, such as the nature of the chemical, the particle size, moisture content, etc., but there is still a lack of knowledge on the effect of the single variables.This paper has the aim of providing data on the Minimum Ignition Temperatures of dust mixtures obtained from a mixing of a combustible dust (flour, lactose, sucrose, sulphur) and an inert dust (limestone, extinguishing powders) as well as from the mixing of two different combustible dusts. Various mixtures with different weight ratios have been tested in a Godbert Greenwald (GG) furnace and on a hot plate in order to measure the effect of mixture composition on the Minimum Ignition Temperature (MITL) of the layer and on the Minimum Ignition Temperature (MITC) of the cloud. In order to further verify the effects of inert dust particle size, inerts sieved to different size ranges have been tested separately. Generally, both MITL and MITC increase as the inert content is increased. MITC is poorly affected by inert particle size when limestone is used. The MITL of pure flour is higher than the MITL of mixtures containing up to 40% of 32–75 μm of limestone. This was probably due to the behaviour of pure flour during the test, which demonstrated strong tendency to produce char, cracks in the layer and detachment from the hot plate. 相似文献
120.
This work uses the ISO 1 m3 dust explosion equipment to study the explosion properties and combustion characteristics of pulverized biomass dust clouds. An unreported feature of this apparatus is that in rich concentrations only about half the dust injected is burned in the explosion, while the overpressures remain high. This work was undertaken to try to understand the mechanisms of these phenomena, through the accounting of the debris at the end of the explosion, some of which was found in the form of impacted “cake” against the vessel wall. One possible explanation is that the residue material was biomass dust blown ahead of the flame by the explosion induced wind, impacted on the walls where then the flame side underwent flame impingement pyrolysis and the metal (wall) side material was compacted but largely chemically unchanged. The results also show that the heat transfer insulation provided by the powder wall layer contributes to the higher observed pressures. The risk of explosion with significant overpressures remains at 100% in very rich environments (equivalence ratios of up to 6) although these environments are leaner than thought due to material sequestration within the “cake”. There was little indication that a rich combustion limit was approached, this was determined in standard testing equipment that has been modified and calibrated to handle larger quantities of powder than normal. 相似文献