Benchmarking Optical/Thermal Satellite Imagery for Estimating Evapotranspiration and Soil Moisture in Decision Support Tools

Generally, one expects evapotranspiration (ET) maps derived from optical/thermal Landsat and MODIS satellite imagery to improve decision support tools and lead to superior decisions regarding water resources management. However, there is lack of supportive evidence to accept or reject this expectation. We “benchmark” three existing hydrologic decision support tools with the following benchmarks: annual ET for the ET Toolbox developed by the United States Bureau of Reclamation, predicted rainfall‐runoff hydrographs for the Gridded Surface/Subsurface Hydrologic Analysis model developed by the U.S. Army Corps of Engineers, and the average annual groundwater recharge for the Distributed Parameter Watershed Model used by Daniel B. Stephens & Associates. The conclusion of this benchmark study is that the use of NASA/USGS optical/thermal satellite imagery can considerably improve hydrologic decision support tools compared to their traditional implementations. The benefits of improved decision making, resulting from more accurate results of hydrologic support systems using optical/thermal satellite imagery, should substantially exceed the costs for acquiring such imagery and implementing the remote sensing algorithms. In fact, the value of reduced error in estimating average annual groundwater recharge in the San Gabriel Mountains, California alone, in terms of value of water, may be as large as $1 billion, more than sufficient to pay for one new Landsat satellite.     

A study on oxidative degradation of polyacrylamide in wastewater with UV/FENTON/C4H4O62−

The degradation of polyacrylamide (PAM) in simulate wastewater was studied in UV/Fenton/C₄H₄O₆^2? system. The factors such as molecular ratio of H₂O₂/Fe²⁺/C₄H₄O₆^2?, pH, and the dosage of Fenton reagent that could affect the PAM degradation in the UV/Fenton/C₄H₄O₆^2? system were investigated. The experimental results showed that adding C₄H₄O₆^2? to UV/Fenton system could form photosensitive ferrous complexes, which led to higher degradation efficiency of PAM. The degradation rate of PAM could be up to 95.2% under the following conditions: the concentration of H₂O₂, Fe²⁺, and C₄H₄O₆^2? were 22.5, 2.25, and 2.25 mmol/L, respectively (i.e., molecular ratio of H₂O₂/Fe²⁺/C₄H₄O₆^2? was 10:1:1), the pH value was 3.0.     

Comparative study on performances of a heat-pipe PV/T system and a heat-pipe solar water heating system

The heat-pipe solar water heating (HP-SWH) system and the heat-pipe photovoltaic/thermal (HP-PV/T) system are two practical solar systems, both of which use heat pipes to transfer heat. By selecting appropriate working fluid of the heat-pipes, these systems can be used in the cold region without being frozen. However, performances of these two solar systems are different because the HP-PV/T system can simultaneously provide electricity and heat, whereas the HP-SWH system provides heat only. In order to understand these two systems, this work presents a mathematical model for each system to study their one-day and annual performances. One-day simulation results showed that the HP-SWH system obtained more thermal energy and total energy than the HP-PV/T system while the HP-PV/T system achieved higher exergy efficiency than the HP-SWH system. Annual simulation results indicated that the HP-SWH system can heat the water to the available temperature (45°C) solely by solar energy for more than 121 days per year in typical climate regions of China, Hong Kong, Lhasa, and Beijing, while the HP-PV/T system can only work for not more than 102 days. The HP-PV/T system, however, can provide an additional electricity output of 73.019 kWh/m², 129.472 kWh/m², and 90.309 kWh/m² per unit collector area in the three regions, respectively.     

Photovoltaic-thermal (PV/t) panel to minimize electrical and air conditioning energy consumption of a typical office in Beirut

A combined photovoltaic–thermal (PV/t) panel is proposed to produce simultaneously electricity and heat from one integrated unit. The unit utilizes effectively the solar energy through achieving higher PV electrical efficiency and using the thermal energy for heating applications. To predict the performance of the PV/t at a given environmental conditions, a transient mathematical model was developed. The model was integrated in a heating application for a typical office space in the city of Beirut to provide the office needs for electricity, heating during winter season, and dehumidification and evaporative cooling during the summer season. To minimize the yearly office energy (electrical and heat) needs, the PV/t panel cooling air flow rate and the dehumidification regeneration temperature were determined for opimal unit operation. Thermal energy savings of up to 85% in winter and 71% in summer were achived compared to conventional systems at a payback period of 8 years for the panels.     

Variability of pesticide residues in cauliflower units collected from a field trial and market places in Greece

To estimate the variability of pesticide residue levels present in cauliflower units, a total of 142 samples were collected from a field trial of a cooperative farmer, and 120 samples were collected from different market places in Thessaloniki, Greece. The collected samples were extracted using the quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction technique, and the residues were determined by liquid chromatography–tandem mass spectrometry. The developed method was validated by evaluating the accuracy, precision, linearity, limit of detection (LOD), and limit of quantification (LOQ). The average recoveries for all the analytes, derived from the data of control samples fortified at 0.01, 0.05, 0.1, and 0.2 mg/kg, ranged from 74 to 110% with a relative standard deviation of ≤8%. The correlation coefficient (R²) was ≥0.997 for all the analytes using matrix-matched calibration standards. The LOD values ranged from 0.001 to 0.003 mg/kg, and the LOQ was determined at 0.01 mg/kg for all the sought analytes. The matrix effect was found to be at a considerable level, especially for cypermethrin and deltamethrin, amounting to +90% and +145%, respectively. For the field samples, the unit-to-unit variability factors (VFs) calculated for cypermethrin and deltamethrin were 2.38 and 2.32, respectively, while the average VF for the market basket samples was 5.11. In the market basket samples, residues of cypermethrin, deltamethrin, chlorpyrifos, and indoxacarb were found at levels ≥LOQ and their respective VFs were 7.12, 5.67, 5.28, and 2.40.     

Effects of humic acids derived from lignite and cattle manure on antioxidant enzymatic activities of barley root

To investigate the effects of humic acids (HAs) on the ability of plants to defend themselves against oxidative stress, barley was hydroponically cultured in the absence and presence of HAs, and the antioxidant enzymatic activities (catalase, superoxide dismutase, ascorbate and glutathione peroxidases) of root tissue were evaluated. Auxin-like structures in HAs, which were extracted from an oxidation product of lignite (LHA) and compost derived from cattle manure (CHA), were identified by pyrolysis-gas chromatography/mass spectrometry (GC/MS) with tetramethylammonium hydroxide. The LHA, which had the lower molecular weight, was more effective in promoting the growth of barley root than CHA. However, the amounts of auxin-like structures in the CHA were much higher than those for LHA. The antioxidant enzymatic activities were initially decreased in the presence of LHA and CHA at the first day after refreshing the culture solution, but were significantly increased on the second day. The CHA sample, which contained relatively high levels of phenolic acids that contained auxin-like structures, was effective in increasing four types of enzymatic activities, while the activities of catalase and ascorbate peroxidase were increased in the presence of LHA, which contains naphthalene derivatives. These results indicate that using HAs as a supplement can be effective in enhancing antioxidation enzymatic activities, while the appearance of the effects is retarded because of the decomposition and release of auxin-like compounds from HAs by organic acids from the plant roots.     

Determination of neonicotinoids in Estonian honey by liquid chromatography–electrospray mass spectrometry

The aim of the study was to provide a comprehensive overview of neonicotinoid pesticide residues in honey samples for a single country and compare the results with the import data for neonicotinoid pesticides. The levels of four neonicotinoid pesticides, namely thiamethoxam, imidacloprid, acetamiprid, and thiacloprid, were determined in 294 honey samples harvested from 2005 to 2013 from more than 200 locations in Estonia. For the analyzed honey samples, 27% contained thiacloprid, and its levels in all cases were below the maximum residue level set by the European Union. The other neonicotinoids were not detected. The proportion of thiacloprid-positive samples for different years correlates well with the data on thiacloprid imports into Estonia, indicating that honey contamination with neonicotinoids can be estimated based on the import data.     

洪泛区林地的开发对鱼类栖息地面积的影响模拟

洪泛区的开发利用,必然会导致洪泛区林地糙率的改变。河漫滩也是河流洪泛区的一部分。洪泛区糙率的减小,会使河水流速增大,从而减小鱼类可用栖息地面积。因此,在洪水发生时,为了给鱼类提供避险场所,保护有效栖息地面积,需研究洪泛区林地的开发对鱼类的影响。利用River 2D软件模拟在一定频率的洪水条件下,不同的河漫滩糙率对应的鱼类栖息地加权可用面积(WUA),分析了糙率的改变对河流鱼类栖息地的影响。结果表明:随着河漫滩糙率的降低,加权可用面积(WUA)逐渐减小,河漫滩范围内WUA的变化幅度比较大,河漫滩的特性对鱼类栖息地面积的影响很大。洪泛区植被的砍伐,会使鱼类栖息地面积减小。因此,应防止洪泛区的过度开发,保护河流生态环境。     

中国旅游业CO_2排放区域差异的空间分析

在旅游业节能减排形势严峻的背景下,深入研究中国旅游业CO_2排放问题,制定科学的区域节能减排政策已刻不容缓。本文首先运用"自下而上"法,估算了1993-2012年中国整体旅游业、旅游业各分部门、大陆各省区(不含西藏)旅游业CO_2排放量。在此基础上,对全国及三大地带旅游业CO_2排放的总体特征进行分析;利用Theil指数法分析了中国旅游业CO_2排放强度的区域差异、区域内差异和区域间差异;运用AreView软件对中国旅游业CO_2排放强度的省际差异进行直观图示。分析结果显示:1993-2012年,中国旅游业CO_2排放量从1 480.868×10~4t升至6 274.129×10~4t;全国及三大地带旅游业CO_2排放强度整体上呈现出先显著下降、再缓慢梯度下降的趋势;中国旅游业CO_2排放强度空间分布不均匀,东部地区旅游业CO_2排放强度低于中部和西部地区;中国旅游业CO_2排放强度的区域总体差异、区域间差异和区域内差异整体呈逐渐缩小的趋势,区域间差异对总体差异的贡献率为94%-98%,区域间差异占主导地位;中国旅游业CO_2排放强度省际差异明显,属于旅游业CO_2排放强度弱显著区的省区基本位于东部沿海地区,河北、湖南、河南、广西、甘肃和新疆等省区频繁出现在旅游业CO_2排放强度强显著区之列,因此上述省区应是中国旅游业CO_2未来节能减排的区域重点。据此提出差别化的CO_2减排对策:东部地区应通过技术改进和调整产业结构、能源消费结构来降低CO_2排放强度,并以此带动中部和西部地区旅游业节能减排;中部和西部地区应加强与东部地区合作,将提高能源使用率、降低CO_2排放强度作为旅游业减排工作的重点。     

Impact of European legislation on marketed pesticides — A view from the standpoint of health impact assessment studies

The very significant impact of European legislation (Directive 91/414/EEC) on the authorization of plant protection products is reviewed herein, which has resulted in withdrawal of 704 active substances (AS) out of 889 assessed so far. The list of currently approved 276 AS includes 194 AS “existing” in the market before 1993 and 82 “new” AS introduced during the last 15 years. Results of toxicity characterization of the approved AS are also summarized, utilizing several well-known databases. Although significant data gaps exist for a rather large part of the approved AS, it is found that 84 AS are positive for at least one health effect (after chronic and/or acute exposure) including carcinogenicity, reproductive and neuro-developmental disorders, as well as endocrine disruption. The toxicity characterization results of this study are compared to those of recent assessments by other organizations (KemI, the Swedish Chemicals Agency, and the Pesticide Safety Directorate of the UK), where interpretation and use is made of AS “cut-off” criteria foreseen in new EU legislation. These studies report a comparatively smaller AS number with positive toxicity characterization. The possibility of some additional AS withdrawal in the near future, combined with the rather small rate of new AS introduction (approx. 5 per year) suggest that the list of approved AS over the next 10–15 years may not change very drastically. Consideration of the above trends is necessary and instructive in evaluating results of existing health impact assessment (HIA) studies, as well as in planning new ones. Due to the very drastic change in the number and type of marketed AS, that took place within the past 8–9 years, it is suggested that new HIA studies (based on epidemiological data after year 2000) should focus on a rather short time frame and, therefore, on appropriate cohort groups, e.g. young children. For the same reason, results of epidemiological studies of the past (involving banned AS) should be carefully interpreted and used with caution.