Effects of a fire-retardant chemical to fathead minnows in experimental streams

BACKGROUND: Each year millions of liters of fire-retardant chemicals are applied to wildfires across the nation. Recent laboratory studies with long-term fire-retardant chemicals indicate a significant photoenhanced toxicity of products containing sodium ferrocyanide corrosion inhibitors. Our objective of this study was to determine the toxicity of fire-retardant chemicals to fathead minnows during exposure in experimental outdoor streams. METHODS: Stream tests were conducted to determine the potential toxicity of a pulse of exposure as might occur when fire retardant chemical is rinsed from the watershed by rainfall. Two artificial 55-meter experimental streams were dosed with different concentrations of Fire-Trol GTS-R, or uncontaminated for a control. Replicate groups of fathead minnows were added to screened containers (10 fish per container) and exposed to retardant chemicals in the recirculating flow of the stream for up to 6 hours. RESULTS AND DISCUSSION: Under field conditions toxicity of GTS-R only occurred in the presence of sunlight. When GTS-R was tested on sunny days, 100% mortality occurred. However, when tested during heavily overcast conditions, no mortality occurred. CONCLUSIONS: Lethal concentrations of cyanide were measured when GTS-R with YPS exposures were conducted under sunny conditions, but not under cloudy conditions, indicating that a minimum UV level is necessary to induce toxicity as well as the release of cyanide from YPS. The toxicity observed with GTS-R was likely associated with lethal concentrations of cyanide. Rainwater runoff following applications of this fire-retardant at the recommended rate could result in lethal concentrations in small ponds and streams receiving limited water flow under sunny conditions. RECOMMENDATIONS AND OUTLOOK: In addition to avoiding application to aquatic habitats, it is important to consider characteristics of the treated site including soil binding affinity and erosive properties.     

Experimental design of Fenton and photo-Fenton reactions for the treatment of cellulose bleaching effluents

Multivariate experimental design was applied to the treatment of a cellulose conventional bleaching effluent in order to evaluate the use of the Fenton reagent under solar light irradiation. The effluent was characterised by the general parameters total organic carbon (TOC), chemical oxygen demand and color, and it was analysed for chlorinated low molecular weight compounds using GC–MS. The main parameters that govern the complex reactive system: Fe(II) and H₂O₂ initial concentration, and temperature were simultaneously studied. Factorial experimental design allowed to assign the weight of each variable in the TOC removal after 15 min of reaction. Temperature had an important effect in the organic matter degradation, especially when the ratio of Fenton reagents was not properly chosen. Fenton reagent under solar irradiation proved to be highly effective for these types of wastewaters. A 90% TOC reduction was achieved in only 15 min of treatment. In addition, the GC–MS analysis showed the elimination of the chlorinated organic compounds initially detected in the studied bleaching effluents.     

Thermal performance of ice-making machine with a multi-channel evaporator

An experimental investigation is presented in this paper on the vapor compression refrigeration cycle used in an ice-making machine with a multi-channel evaporator. To study the operation performance of the refrigeration system in the ice-making machine, the fluid temperature distribution in multi-channel evaporating coils are tested and the dynamic variations in each cooling loop are investigated during the ice-generating phase. The results show that the external cooling loops have the largest temperature fluctuations caused by the large initial refrigerant injecting mass flow and the external environmental disturbances. For the inner cooling loops, the related temperature profiles of different test points have relative stable variations. To reduce the temperature fluctuations of the outside loops, it is suggested to reduce the initial refrigerant mass flow and adjust the initial opening of the thermal expansion valve. Moreover, it is the normal phenomenon for the slight temperature variations for the temperature curves of different test points, caused by the adjustment of thermal expansion valve. During the ice-making process, both the sensible heat removal phase and latent heat removal phase are experienced successively. To remove the sensible heat of water, the refrigerant system is operating in high efficiency with test points having a rapid linear temperature reduction. While for eliminating the latent heat of ice, it requires much more power supply, the relating test points have a temperature decrease with fluctuations. To improve the operation performance of ice machine, some suggestions and improvements are proposed.     

Effects of premixed methane concentration on distribution of flame region and hazard effects in a tube and a tunnel gas explosion

Study of flame distribution laws and the hazard effects in a tunnel gas explosion accident is of great importance for safety issue. However, it has not yet been fully explored. The object of present work is mainly to study the effects of premixed gas concentration on the distribution law of the flame region and the hazard effects involving methane-air explosion in a tube and a tunnel based on experimental and numerical results. The experiments were conducted in a tube with one end closed and the other open. The tube was partially filled with premixed methane-air mixture with six different premixed methane concentrations. Major simulation works were performed in a full-scale tunnel with a length of 1000 m. The first 56 m of the tunnel were occupied by methane–air mixture. Results show that the flame region is always longer than the original gas region in any case. Concentration has significant effects on the flame region distribution and the explosion behaviors. In the tube, peak overpressures and maximum rates of overpressure rise (dp/dt)_max for mixtures with lower and higher concentrations are great lower than that for mixtures close to stoichiometric concentration. Due to the gas diffusion effect, not the stoichiometric mixture but the mixture with a slightly higher concentration of 11% gets the highest peak overpressure and the shock wave speed along the tube. In the full-scale tunnel, for fuel lean and stoichiometric mixture, the maximum peak combustion rates is achieved before arriving at the boundary of the original methane accumulation region, while for fuel rich mixture, the maximum value appears beyond the region. It is also found that the flame region for the case of stoichiometric mixture is the shortest as 72 m since the higher explosion intensity shortens the gas diffusion time. The case for concentration of 13% can reach up to a longest value of 128 m for longer diffusion time and the abundant fuel. The “serious injury and death” zone caused by shock wave may reach up to 3–8 times of the length of the original methane occupied region, which is the widest damage region.     

Price perceptions in water demand

Economists advocate for using the price mechanism to manage water scarcity, but complex nonlinear rate structures prevalent in markets for municipal water obscure price signals. We conduct a randomized field experiment that jointly elicits knowledge about the cost of water and examines the impact of improved information on demand by linking a survey to water billing records. Half of our sample of 30,000 single family homeowners are randomly sent an invitation to a survey that asks questions about the water bill and the costs of water-use activities (e.g. the cost of taking a shower), and subsequently provides personalized accurate information. Results show that consumers have poor information about the marginal price of water and overestimate the costs of using water. Respondents are relatively better informed about their total bill and water consumption. In aggregate, respondents increase water use in response to the survey, potentially due to learning that water is cheaper than they previously thought. Increased consumption is concentrated among low users who are more likely to over-estimate the costs of using water.     

开展清洁生产审计实现企业经济与环境双效益─—绍兴市清洁生产示范项目企业试点及其效益分析

对绍兴市清洁生产示范项目的试点企业清洁生产审计方法、程序及初步成果作了系统的分析。论述了采用清洁生产审计，进行污染预防，是企业实现经济与环境双重效益的最佳途径。提出了现阶段企业开展清洁生产的部份政策和制度的建议。对我国的清洁生产审计方法学与政策制订具有一定的理论与实践意义。     

受限空间烟气运动的盐水模拟实验初探

考虑到盐水在清水中扩散过程与烟气在受限空间内运动的相似性，本文用实验的方法，初步探讨了用盐水的扩散来模拟烟气在建筑物（单室）内运动的可行性。并对烟羽流主轴线速度和顶篷水平分层烟气流厚度的生长规律进行了测量。本文所得结果基本合理，正确，对建筑火灾烟气控制和人员疏散有参考作用．     

Experimental investigation of the influence of inert solids on ignition sensitivity of organic powders

This work presents the results of the experimental characterization of the ignition sensitivity of solid inertant/combustible powders mixtures. Three inert solids (alumina, Kieselguhr, aerosil) and eleven organic powders have been considered and the following parameters have been determined: (1) the minimum ignition energy, (2) the minimum ignition temperature in cloud and (3) the minimum ignition temperature in 5 mm layer. The effects of the addition of inert solids are described and a simple model is proposed to represent the experimental results.Generally, increasing inert solid content in a powder leads to a higher minimum ignition energy as well as a higher minimum ignition temperatures in cloud and in layer. In some cases, the flammability is influenced above a threshold concentration value, which can be quite high (up to 85 wt.%). Indeed, the proposed model shows a zone below the minimum ignition concentration (MIC), which does not enable an efficient or safe inerting: either the admixed inert solid does not provide a sufficient effect, or it can even facilitate the ignition of the dust by notably improving its dispersability.The influence of key parameters such as the thermal conductivity or optical properties on the efficiency of the inerting by admixed solid need to be further assessed in a future work in view to better understand the mechanisms involved and to extend the scope to other types of oxidizable materials.     

地震动对人生理反应的影响初探

本文采用实验心理学的基本原理和方法,在模拟地震振动台上进行了在真实地震波作用下心理反应试验,研究了地震动作用下人的生理变化过程。     

多层建筑火灾烟气运动的模拟实验研究

火灾烟气是导致多层建筑火灾中人员伤亡的主要原因。结合多层建筑的实际情况 ,利用缩尺度模型实验楼模拟多层建筑火灾的典型情况 ,对其火灾烟气自火源产生后的运动特性进行实验研究。结果表明 ,烟气沿程由于热交换温度不断降低 ,会迅速达到顶部楼层并立即沉降 ,而且不同工况条件下所包含的有毒成分浓度随着火源温度的升高而上升。实验结果的分析能够较好地符合实际火灾的一些典型调查结果。