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191.
192.
义乌市TSP中3种重金属元素的沉降 总被引:1,自引:0,他引:1
测定了义乌市TSP及其中的重金属Fe,Mn和Cu的浓度,通过扫描电镜和降雨冲洗效果分析了含有这3种重金属的颗粒物的粒径,计算了3种重金属的沉降通量。结果表明相对于世界其他城市,义乌市TSP中这3种重金属浓度偏高;绝大部分TSP的半径小于4.5μm;Fe和Mn的湿沉降量大于干沉降量,而Cu以干沉降为主。 相似文献
193.
Ni/Fe双金属降解四氯化碳和四氯乙烯的对比试验 总被引:3,自引:0,他引:3
以四氯化碳(CT)和四氯乙烯(PCE)为目标污染物,以批试验方法研究Ni/Fe双金属对CT和PCE的还原性脱氯.结果表明:Ni/Fe双金属可有效去除水中的CT和PCE;Ni/Fe双金属对CT和PCE的降解反应均符合准一级反应动力学方程;在相似的反应条件下,Ni/Fe双金属对CT和PCE脱氯的反应速率常数(kobs)之比为1.48和1.67,说明Ni/Fe双金属对CT的脱氯速率要快于对PCE的脱氯速率;Ni/Fe双金属可对PCE完全脱氯,但对CT脱氯过程中产生少量三氯甲烷(TCM). 相似文献
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Dissimilatory Fe(Ⅲ) reduction is a universal process with irreplaceable biological and environmental importance in anoxic environments. Our knowledge about Fe(Ⅲ) reduction predominantly comes from pure cultures of dissimilatory Fe(Ⅲ) reducing bacteria (DFRB). The objective of this study was to compare the effects of glucose and a selection of short organic acids (citrate, succinate, pyruvate, propionate, acetate, and formate) on Fe(Ⅲ) reduction via the anaerobic culture of three paddy soil solutions with Fe(OH)3 as the sole electron acceptor. The results showed significant differences in Fe(Ⅲ) reduction among the three paddy soil solutions and suhstrate types. Bacteria from the Sichuan paddy soil responded quickly to substrate supply and showed higher Fe(Ⅲ) reducing activity than the other two soil types. Bacteria in the Jiangxi paddy soil culture solution could not use propionate as a source of electrons for Fe(Ⅲ) reduction. Similarly, bacteria in the Jilin paddy soil culture could not use succinate effectively. Pyruvate was readily used by cultures from all three paddy soil solutions, thus indicating that there were some similarities in substrate utilization by bacteria for Fe(Ⅲ) reduction. The use of glucose and citrate as substrate for dissimilatory Fe(Ⅲ) reduction indicates important ecological implications for this type of anoxic respiration. 相似文献
196.
地下水中铁、锰的存在形式及去除技术探讨 总被引:3,自引:0,他引:3
地下水中铁、锰存在形式复杂 ,铁锰超标产生一定的危害性 ,本文通过研究地下水除铁除锰技术的发展趋势 ,对现有除铁除锰技术进行比较 ,阐明了生物除铁除锰技术的发展前景 相似文献
197.
IntroductionArhaReservoirislocatedintheplateauregionofSouthwestChina.Thisreservoir,withavolumeof445millionm3,wasbuiltin1960andisth?.. 相似文献
198.
环境水样中痕量Fe3+的测定方法研究 总被引:2,自引:0,他引:2
在酸性介质中(pH
5.0),Fe3+能与硫氰酸盐生成稳定的配离子[Fe(SCN)6]3-,该配阴离子能与碱性717型阴离子交换树脂定量交换缔合,形成阴离子交换树脂(R+)--金属离子(Mn+)--硫氰酸盐(SCN-)三元配合缔合体系,其最大吸收波长分别为490
μm,与二元水相最大吸收波长相同,通过制作薄层测定了水中Fe3+含量.本法具有较高的灵敏度ε630Fe3+=2.4×105
L·mol-1·cm-1,测定0.6 μgFe3+6次,RSD=2.7%,实测了水样中,Fe3+含量并与AAS法测定结果比较,Fe3+测定的线性范围0~10
μg/25mL,体系检出限为0.12 μmol/L. 相似文献
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Herpin U Siewers U Markert B Rosolen V Breulmann G Bernoux M 《Environmental science and pollution research international》2004,11(1):57-66
This paper shows the geographic distribution in Germany of iron (Fe), nickel (Ni) and lead (Pb) analyzed in mosses in 1995/96 and compares it with the results of the 1990/91 pilot study within a European moss-monitoring programme. Other elements (As, Cd, Cr, Cu, Ti, V, Zn) are compared on basis of the overall element medians for Germany of the 1990/91 and 1995/96 survey. Samples of Pleurozium schreberi, Scleropodium purum, Hypnum cupressiforme and Hylocomium splendens were taken at a total of 1026 sites. In the 1995/96 monitoring campaign, 95% of the original sites of the 1990/91 study were resampled. The results from 1995/96 display local elevated values and many cases of areas affected by known sources of heavy-metal emissions. The industrialized and urban regions of Germany are shown up clearly by the 1995/96 moss-monitoring results: the Ruhr area, parts of Saarland and Baden-Württemberg, as well as areas in eastern Germany. Relatively low values for many elements were found in large areas of Lower Saxony and Bavaria. A comparison of the results of the 1990/91 and 1995/96 moss-monitoring programmes shows a fall in the concentration of the presented elements (except cadmium, copper and zinc) over the relevant period. Especially in the former GDR, chromium (Cr), iron (Fe), titanium (Ti) and vanadium (V) decreased significantly. This is, firstly, a reflection of the closure of and/or technological improvements to large power plants; secondly it is due to the fact that lignite has given way to other fuels. Vanadium (V) and nickel (Ni), typical constituents of crude oil, also show a decrease in the western part and thus document changes in the type of fuel consumed. The significant fall in lead concentration in 1995/96 as compared to 1990/91 in what used to be East and West Germany probably results from the increasing use of lead-free petrol. A comparison of the median values for 1990/91 and 1995/96 in mosses to the rate of emission of heavy metals in Germany for 1990 and 1995 shows similar trends in the case of elements such as arsenic (As), chromium (Cr), nickel (Ni), and lead (Pb). The comparison of the medians of the elements analyzed for 19 European countries indicates for most of the elements a general tendency to lower values in 1995, except for Lithuania, Netherlands, Portugal, Italy and United Kingdom. 相似文献