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291.
Interactions between engineered nanoparticles and dissolved organic matter: A review on mechanisms and environmental effects 总被引:1,自引:0,他引:1
Dissolved organic matter (DOM) is ubiquitous in the environment and has high reactivity. Once engineered nanoparticles (ENPs) are released into natural systems, interactions of DOM with ENPs may significantly affect the fate and transport of ENPs, as well as the bioavailability and toxicity of ENPs to organisms. However, because of the complexity of DOM and the shortage of useful characterization methods, large knowledge gaps exist in our understanding of the interactions between DOM and ENPs. In this article, we systematically reviewed the interactions between DOM and ENPs, discussed the effects of DOM on the environmental behavior of ENPs, and described the changes in bioavailability and toxicity of ENPs caused by DOM. Critical evaluations of published references suggest further need for assessing and predicting the influences of DOM on the transport, transformation, bioavailability, and toxicity of ENPs in the environment. 相似文献
292.
Xiaojia He Sabrieon Sanders Winfred G.Aker Yunfeng Lin Jessica Douglas Huey-min Hwang 《环境科学学报(英文版)》2016,28(4):50-60
In this study,the cytotoxicity of two different crystal phases of TiO2 nanoparticles,with surface modification by humic acid(HA),to Escherichia coli,was assessed.The physicochemical properties of TiO2 nanoparticles were thoroughly characterized.Three different initial concentrations,namely 50,100,and 200 ppm,of HA were used for synthesis of HA coated TiO2 nanoparticles(denoted as A/RHA50,A/RHA100,and A/RHA200,respectively).Results indicate that rutile(LC50(concentration that causes 50%mortality compared the control group)=6.5)was more toxic than anatase(LC50=278.8)under simulated sunlight(SSL)irradiation,possibly due to an extremely narrow band gap.It is noted that HA coating increased the toxicity of anatase,but decreased that of rutile.Additionally,AHA50 and RHA50had the biggest differences compared to uncoated anatase and rutile with LC50of 201.9 and21.6,respectively.We then investigated the formation of reactive oxygen species(ROS)by TiO2 nanoparticles in terms of hydroxyl radicals(OH)and superoxide anions(O2-).Data suggested that O2- was the main ROS that accounted for the higher toxicity of rutile upon SSL irradiation.We also observed that HA coating decreased the generation of OH and O2- on rutile,but increased O2- formation on anatase.Results from TEM analysis also indicated that HA coated rutile tended to be attached to the surface of E.coli more than anatase. 相似文献
293.
Silver nanoparticle (SNP) is a threat to soil, water and human health. Protection of environment from silver nanoparticles is a
major concern. A sewage isolate, Bacillus pumilus treated with SNPs showed similar growth kinetics to that without nanoparticles.
A reduction in the amount of exopolysaccharides was observed after SNPs – B. pumilus culture supernatant interaction. The Fourier
transform infrared spectroscopy (FT-IR) peaks for the exopolysaccharides extracted from the bacterial culture supernatant and the
interacted SNPs were almost similar. The exopolysaccharide capping of the SNPs was confirmed by UV-Visible, FT-IR and X-ray
di raction analysis. The study of bacterial exopolysaccharides capped SNPs with E. coli, S. aureus and M. luteus showed less toxicity
compared to uncoated SNPs. Our studies suggested that the capping of nanoparticles by bacterially produced exopolysaccharides serve
as the probable mechanism of tolerance. 相似文献
294.
295.
Developing various approaches for preparing high performance materials has long been topics and tasks both for scientists and for engineers.Despite that many methods have been developed for preparing nanomaterials,developing simple and environment-friendly ways for preparing nanomaterials is very attractive.A simple approach of synthesizing Fe3O4 nanoparticles by arc-discharge submerging in water was reported.The results showed that by this method Fe3O4 nanoparticles can be synthesized in large scale.The as-prepared Fe3O4 nanoparticles exhibit uniform spherical shape and their diameters varied with arc-discharging parameters.The experimental results showed that the size of the synthesized Fe3O4 nanoparticles can be controlled through adjusting the processing parameters.Since no vacuum system has been used,the synthesizing process is greatly simplified.In addition,only cheap deionized water and industrial iron bar are used and no pollution or harmful by-products are found in the synthesis process.It indicated that the present approach is a simple,low-cost and environment-friendly for preparing nanoparticles. 相似文献
296.
Evaluation of the adsorption potential of titanium dioxide nanoparticles
for arsenic removal 总被引:1,自引:1,他引:0
The adsorption potential of titanium dioxide (TiO2) nanoparticles for removing arsenic from drinking water was evaluated. Pure and iron-doped TiO2 particles are synthesized via sol-gel method. The synthesized TiO2 nanoparticles were then immobilized on ordinary sand for adsorption studies. Adsorption isotherms were conducted on the synthesized nanoparticles as well as the sand coated with TiO2 nanoparticles under varying conditions of air and light, namely, the air-sunlight (A-SL), air-light (AL), air-dark (AD) and nitrogen-dark (ND). X-Ray diffraction (XRD) analysis showed that the pure and the iron-doped TiO2 nanoparticles were in 100% anatase crystalline phase with crystal sizes of 108 and 65 nm, respectively.Adsorption of arsenic on the three adsorbents was non-linear that could be described by the Freundlich and Langmuir adsorption models. Iron doping enhanced the adsorption capacity of TiO2 nanoparticle by arresting its grain growth and making it visible light responsive resulting in a higher affinity for arsenic. Similarly, the arsenic removal by adsorption on the sand coated with TiO2 nanoparticles was the highest among the three types of sand used. In all cases, As(V) adsorbed more compared with As(III). Solution pH appeared to be the most important factor in controlling the amount of arsenic adsorbed. 相似文献
297.
298.
Jakub Mikiciuk Ewa Mikiciuk Anna Wrońska Arkadiusz Szterk 《Journal of environmental science and health. Part. B》2016,51(4):222-229
The application of nanotechnology in the agriculture and food sector is relatively recent compared to its usage in drug delivery or pharmaceuticals. Therefore, this paper presents a study of the effect of silver nanoparticles on probiotic bacteria based on the example of Lactobacillus acidophilus LA-5, Bifidobacterium animalis subsp. lactis BB-12 and Streptococcus thermophilus ST-Y31 isolated from fermented milk products. Probiotic bacteria are one of the most crucial groups of bacteria for the food industry, because of their claimed health-promoting properties. Studies have shown that the type and concentration of silver nanoparticle solutions have a significant impact on the tested probiotic bacteria which are profitable for the digestive system. In the presence of all tested silver nanoparticles, St. thermophilus ST-Y31 growth was inhibited significantly by the dilution method as opposed to the disk-diffusion method. Both the disk-diffusion and the dilution methods showed no significant differences between L. acidophilus LA-5 and B. animalis subsp. lactis BB-12. The concentrations 2 μg mL?1 and 0.25 μg mL?1 had the highest antibacterial activity and statistically significant impacts on the tested probiotic strains. To our knowledge, this is the first report on potential antimicrobial effect of nanosilver against the health-promoting probiotic bacteria L. acidophilus LA-5, B. animalis subsp. lactis BB-12 and St. thermophilus ST-Y31 isolated from fermented milk products. 相似文献
299.
Determination of nephrotoxicity and genotoxic potential of silver nanoparticles in Swiss albino mice
Silver nanoparticles (AgNPs) possess properties that are important for industrial and medical applications. This study is aimed to investigate intra-peritoneal toxicity of AgNPs at 26, 52 or 78 mg/kg/day for 5 days in mice Swiss albino mice. The effects on oxidative stress markers activities of serum superoxide dismutase (SOD) and catalase (CAT), levels of serum glutathione (GSH), apoptosis (TUNEL assay), DNA strand breaks (comet assay) in lymphocytes, as well as histopathological of kidney tissue were determined. AgNPs significantly increased SOD and CAT activities reduced GSH levels. In kidney apoptosis (TUNEL assay) while DNA strand breaks (comet assay) in lymphocytes revealed that AgNPs at concentration 78 mg/kg produced significant apoptosis and DNA damage. AgNPs also produced associated histological renal tissue damage. Evidence suggests that AgNPs-mediated alterations may be attributed to oxidative stress. 相似文献
300.
采用共沉淀法合成Fe3O4纳米磁性颗粒,用透射电子显微镜(TEM)、X射线衍射仪(XRD)以及振动样品磁强计(VSM)对Fe3O4纳米磁性颗粒的粒径、形貌和磁性进行表征并研究Fe3O4纳米磁性微粒对全氟辛磺酸盐的吸附。结果表明:在PFOS初始浓度4 mg/L,pH为3,反应时间24 h,Fe3O4纳米磁性微粒投加量1.25 g/L,对全氟辛磺酸盐去除率达到90%。Fe3O4纳米磁性微粒对PFOS的吸附符合Freundlich吸附方程。 相似文献