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31.
Anaerobic tapered fluidized bed reactor for starch wastewater treatment and
modeling using multilayer perceptron neural network 总被引:1,自引:0,他引:1
Anaerobic treatability of synthetic sago wastewater was investigated in a laboratory anaerobic tapered fluidized bed reactor(ATFBR) with a mesoporous granular activated carbon(GAC)as a support material.The experimental protocol was defined to examine the effect of the maximum organic loading rate(OLR),hydraulic retention time(HRT),the efficiency of the reactor and to report on its steady- state performance.The reactor was subjected to a steady-state operation over a range of OLR up to 85.44 kg COD/(m~3.d).The COD removal efficiency was found to be 92% in the reactor while the biogas produced in the digester reached 25.38 m~3/(m~3·d) of the reactor. With the increase of OLR from 83.7 kg COD/(m~3.d),the COD removal efficiency decreased.Also an artificial neural network(ANN) model using multilayer perceptron(MLP)has been developed for a system of two input variable and five output dependent variables. For the training of the input-output data,the experimental values obtained have been used.The output parameters predicted have been found to be much closer to the corresponding experimental ones and the model was validated for 30% of the untrained data.The mean square error(MSE)was found to be only 0.0146. 相似文献
32.
Susceptibility indexing method for irrigation water management planning: applications to K. Menderes river basin, Turkey 总被引:2,自引:0,他引:2
A susceptibility indexing method was developed based on vulnerability and quality indices. The contamination susceptibility index (SI) at a given location was calculated by taking the product of the vulnerability index (VI) and the quality index (QI): SI = VI × QI. This method incorporates both hydrogeological and hydrochemical data for a comprehensive index mapping. The DRASTIC index methodology was used for the hydrogeological data evaluations. The quality index calculation procedure based on a water quality classification scheme was introduced to evaluate hydrochemical data. The suggested susceptibility indexing method was applied to the Küçük Menderes river basin located in western Turkey. The susceptibility index map shows both hydrogeological and hydrochemical data related to the contamination problem including areas that should be taken into consideration during water management planning. The index map indicates that the most susceptible groundwater is located along the river channel between Kiraz and Tire towns, in the Selçuk area and along the Fertek stream channel to the north of Torbal? town. The results indicate that the incorporation of both hydrogeological and hydrochemical datasets enables more realistic evaluations than those of an individual dataset to estimate the groundwater contamination susceptibility of an aquifer. The numerical procedure applied could be extended further by including other parameters such as retardation, potential contaminant sources, etc. that affect the water quality in a given basin. 相似文献
33.
Dongmei Han Xing Liang Menggui Jin Matthew J. Currell Ying Han Xianfang Song 《Environmental management》2009,44(2):243-255
Based on analysis of groundwater hydrochemical and isotopic indicators, this article aims to identify the groundwater flow
systems in the Yangwu River alluvial fan, in the Xinzhou Basin, China. Groundwater δ2H and δ18O values indicate that the origin of groundwater is mainly from precipitation, with local evaporative influence. d-excess values lower than 10% in most groundwaters suggest a cold climate during recharge in the area. Major ion chemistry,
including rCa/rMg and rNa/rCl ratios, show that groundwater salinization is probably dominated by water–rock interaction (e.g.,
silicate mineral weathering, dissolution of calcite and dolomite and cation exchange) in the Yangwu River alluvial fan, and
locally by intensive evapotranspiration in the Hutuo River valley. Cl and Sr concentrations follow an increasing trend in
shallow groundwater affected by evaporation, and a decreasing trend in deep groundwater. 87Sr/86Sr ratios reflect the variety of lithologies encountered during throughflow. The groundwater flow systems (GFS) of the Yangwu
River alluvial fan include local and intermediate flow systems. Hydrogeochemical modeling results, simulated using PHREEQC,
reveal water–rock interaction processes along different flow paths. This modeling method is more effective for characterizing
flow paths in the intermediate system than in the local system. Artificial exploitation on groundwater in the alluvial fan
enhances mixing between different groundwater flow systems. 相似文献
34.
An Assessment of Stakeholder Perceptions and Management of Noxious Alien Plants in Spain 总被引:1,自引:1,他引:0
Despite biological invasions being a worldwide phenomenon causing significant ecological, economic, and human welfare impacts,
there is limited understanding regarding how environmental managers perceive the problem and subsequently manage alien species.
Spanish environmental managers were surveyed using questionnaires to (1) analyze the extent to which they perceive plant invasions
as a problem; (2) identify the status, occurrence, and impacts of noxious alien plant species; (3) assess current effort and
expenditure targeting alien plant management; and, finally, (4) identify the criteria they use to set priorities for management.
In comparison to other environmental concerns, plant invasions are perceived as only moderately problematic and mechanical
control is the most valued and frequently used strategy to cope with plant invasions in Spain. Based on 70 questionnaires
received, 193 species are considered noxious, 109 of which have been the subject of management activities. More than 90% of
species are found in at least one protected area. According to respondents, the most frequently managed species are the most
widespread across administrative regions and the ones perceived as causing the highest impacts. The perception of impact seems
to be independent of their invasion status, since only half of the species identified as noxious are believed to be invasive
in Spain, while 43% of species thought to only be casual aliens are causing a high impact. Records of management costs are
poor and the few data indicate that the total actual expenditure amounted to 50,492,437 € in the last decade. The majority
of respondents stated that management measures are insufficient to control alien plants due to limited economic resources,
lack of public awareness and support, and an absence of coordination among different public administrations. Managers also
expressed their concern about the fact that much scientific research is concerned with the ecology of alien plants rather
than with specific cost-efficient strategies to manage alien species. 相似文献
35.
Vinicius F. Farjalla André M. Amado Albert L. Suhett Frederico Meirelles-Pereira 《Environmental science and pollution research international》2009,16(5):531-538
Background, aim, and scope Dissolved humic substances (HS) usually comprise 50–80% of the dissolved organic carbon (DOC) in aquatic ecosystems. From
a trophic and biogeochemical perspective, HS has been considered to be highly refractory and is supposed to accumulate in
the water. The upsurge of the microbial loop paradigm and the studies on HS photo-degradation into labile DOC gave rise to
the belief that microbial processing of DOC should sustain aquatic food webs in humic waters. However, this has not been extensively
supported by the literature, since most HS and their photo-products are often oxidized by microbes through respiration in
most nutrient-poor humic waters. Here, we review basic concepts, classical studies, and recent data on bacterial and photo-degradation
of DOC, comparing the rates of these processes in highly humic ecosystems and other aquatic ecosystems.
Materials and methods We based our review on classical and recent findings from the fields of biogeochemistry and microbial ecology, highlighting
some odd results from highly humic Brazilian tropical lagoons, which can reach up to 160 mg C L−1.
Results and discussion Highly humic tropical lagoons showed proportionally lower bacterial production rates and higher bacterial respiration rates
(i.e., lower bacterial growth efficiency) than other lakes. Zooplankton showed similar δ13C to microalgae but not to humic DOC in these highly humic lagoons. Thus, the data reviewed here do not support the microbial
loop as an efficient matter transfer pathway in highly humic ecosystems, where it is supposed to play its major role.
In addition, we found that some tropical humic ecosystems presented the highest potential DOC photo-chemical mineralization
(PM) rates reported in the literature, exceeding up to threefold the rates reported for temperate humic ecosystems. We propose
that these atypically high PM rates are the result of a joint effect of the seasonal dynamics of allochthonous humic DOC input
to these ecosystems and the high sunlight incidence throughout the year. The sunlight action on DOC is positive to microbial
consumption in these highly humic lagoons, but little support is given to the enhancement of bacterial growth efficiency,
since the labile photo-chemical products are mostly respired by microbes in the nutrient-poor humic waters.
Conclusions HS may be an important source of energy for aquatic bacteria in humic waters, but it is probably not as important as a substrate
to bacterial growth and to aquatic food webs, since HS consumption is mostly channeled through microbial respiration. This
especially seems to be the case of humic-rich, nutrient-poor ecosystems, where the microbial loop was supposed to play its
major role. Highly humic ecosystems also present the highest PM rates reported in the literature. Finally, light and bacteria
can cooperate in order to enhance total carbon degradation in highly humic aquatic ecosystems but with limited effects on
aquatic food webs.
Recommendations and perspectives More detailed studies using C- and N-stable isotope techniques and modeling approaches are needed to better understand the
actual importance of HS to carbon cycling in highly humic waters. 相似文献
36.
37.
Nadeem W. Shah Steven F. Thornton Simon H. Bottrell Michael J. Spence 《Journal of contaminant hydrology》2009,103(3-4):119-133
The potential for aerobic biodegradation of MTBE in a fractured chalk aquifer is assessed in microcosm experiments over 450 days, under in situ conditions for a groundwater temperature of 10 °C, MTBE concentration between 0.1 and 1.0 mg/L and dissolved O2 concentration between 2 and 10 mg/L. Following a lag period of up to 120 days, MTBE was biodegraded in uncontaminated aquifer microcosms at concentrations up to 1.2 mg/L, demonstrating that the aquifer has an intrinsic potential to biodegrade MTBE aerobically. The MTBE biodegradation rate increased three-fold from a mean of 6.6 ± 1.6 μg/L/day in uncontaminated aquifer microcosms for subsequent additions of MTBE, suggesting an increasing biodegradation capability, due to microbial cell growth and increased biomass after repeated exposure to MTBE. In contaminated aquifer microcosms which also contained TAME, MTBE biodegradation occurred after a shorter lag of 15 or 33 days and MTBE biodegradation rates were higher (max. 27.5 μg/L/day), probably resulting from an acclimated microbial population due to previous exposure to MTBE in situ. The initial MTBE concentration did not affect the lag period but the biodegradation rate increased with the initial MTBE concentration, indicating that there was no inhibition of MTBE biodegradation related to MTBE concentration up to 1.2 mg/L. No minimum substrate concentration for MTBE biodegradation was observed, indicating that in the presence of dissolved O2 (and absence of inhibitory factors) MTBE biodegradation would occur in the aquifer at MTBE concentrations (ca. 0.1 mg/L) found at the front of the ether oxygenate plume. MTBE biodegradation occurred with concomitant O2 consumption but no other electron acceptor utilisation, indicating biodegradation by aerobic processes only. However, O2 consumption was less than the stoichiometric requirement for complete MTBE mineralization, suggesting that only partial biodegradation of MTBE to intermediate organic metabolites occurred. The availability of dissolved O2 did not affect MTBE biodegradation significantly, with similar MTBE biodegradation behaviour and rates down to ca. 0.7 mg/L dissolved O2 concentration. The results indicate that aerobic MTBE biodegradation could be significant in the plume fringe, during mixing of the contaminant plume and uncontaminated groundwater and that, relative to the plume migration, aerobic biodegradation is important for MTBE attenuation. Moreover, should the groundwater dissolved O2 concentration fall to zero such that MTBE biodegradation was inhibited, an engineered approach to enhance in situ bioremediation could supply O2 at relatively low levels (e.g. 2–3 mg/L) to effectively stimulate MTBE biodegradation, which has significant practical advantages. The study shows that aerobic MTBE biodegradation can occur at environmentally significant rates in this aquifer, and that long-term microcosm experiments (100s days) may be necessary to correctly interpret contaminant biodegradation potential in aquifers to support site management decisions. 相似文献
38.
A.A.L. Oiffer J.F. Barker F.M. Gervais K.U. Mayer C.J. Ptacek D.L. Rudolph 《Journal of contaminant hydrology》2009,108(3-4):89-106
An anaerobic plume of process-affected groundwater was characterized in a shallow sand aquifer adjacent to an oil sands tailings impoundment. Based on biological oxygen demand measurements, the reductive capacity of the plume is considered minimal. Major dissolved components associated with the plume include HCO3, Na, Cl, SO4, and naphthenic acids (NAs). Quantitative and qualitative NA analyses were performed on groundwater samples to investigate NA fate and transport in the subsurface. Despite subsurface residence times exceeding 20 years, significant attenuation of NAs by biodegradation was not observed based on screening techniques developed at the time of the investigation. Relative to conservative tracers (i.e., Cl), overall NA attenuation in the subsurface is limited, which is consistent with batch sorption and microcosm studies performed by other authors. Insignificant biological oxygen demand and low concentrations of dissolved As (< 10 µg L− 1) in the plume suggest that the potential for secondary trace metal release, specifically As, via reductive dissolution reactions driven by ingress of process-affected water is minimal. It is also possible that readily leachable As is not present in significant quantities within the sediments of the study area. Thus, for similar plumes of process-affected groundwater in shallow sand aquifers which may occur as oil sands mining expands, a reasonable expectation is for NA persistence, but minimal trace metal mobilization. 相似文献
39.
Laurence Gourcy Nicole Baran Benoit Vittecoq 《Journal of contaminant hydrology》2009,108(3-4):107-117
Numerous successful examples of CFC and SF6 groundwater dating applications were recently published. However the proposed CFC/SF6 method needs various hydrodynamic parameters that are not always available. In order to predict groundwater-quality trends in areas where the hydrogeological context is poorly known, a dating method using tritium, CFC and SF6 was successfully implemented in Martinique. Hydrogeological understanding is limited in this volcanic island where groundwater contamination by pesticides and nitrate has been recently proven in various areas. A negative correlation was observed between nitrate concentrations and groundwater ages while pesticide contamination showed a more complex schema. Consequently the presence of old groundwater clearly explained the absence or low pesticide and nitrate concentrations in some areas. However a possible degradation of the water quality is to be feared in the future. In view of the relatively long transfer times and the complexity of the remobilization processes of solutes, the expected effects of any modifications in the use of fertilizers, or of changes in pesticide-use legislation, would take a long time to become apparent. 相似文献
40.
Degassing of H/He, CFCs and SF6 by denitrification: Measurements and two-phase transport simulations
Ate Visser Joris D. Schaap Hans Peter Broers Marc F.P. Bierkens 《Journal of contaminant hydrology》2009,103(3-4):206-218
The production of N2 gas by denitrification may lead to the appearance of a gas phase below the water table prohibiting the conservative transport of tracer gases required for groundwater dating. We used a two-phase flow and transport model (STOMP) to study the reliability of 3H/3He, CFCs and SF6 as groundwater age tracers under agricultural land where denitrification causes degassing. We were able to reproduce the amount of degassing (R2 = 69%), as well as the 3H (R2 = 79%) and 3He (R2 = 76%) concentrations observed in a 3H/3He data set using simple 2D models. We found that the TDG correction of the 3H/3He age overestimated the control 3He/3He age by 2.1 years, due to the accumulation of 3He in the gas phase. The total uncertainty of degassed 3H/3He ages of 6 years (± 2 σ) is due to the correction of degassed 3He using the TDG method, but also due to the travel time in the unsaturated zone and the diffusion of bomb peak 3He. CFCs appear to be subject to significant degradation in anoxic groundwater and SF6 is highly susceptible to degassing. We conclude that 3H/3He is the most reliable method to date degassed groundwater and that two-phase flow models such as STOMP are useful tools to assist in the interpretation of degassed groundwater age tracer data. 相似文献