全文获取类型
收费全文 | 572篇 |
免费 | 7篇 |
国内免费 | 32篇 |
专业分类
安全科学 | 31篇 |
废物处理 | 7篇 |
环保管理 | 111篇 |
综合类 | 131篇 |
基础理论 | 54篇 |
污染及防治 | 182篇 |
评价与监测 | 70篇 |
社会与环境 | 20篇 |
灾害及防治 | 5篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 12篇 |
2021年 | 8篇 |
2020年 | 17篇 |
2019年 | 11篇 |
2018年 | 8篇 |
2017年 | 11篇 |
2016年 | 16篇 |
2015年 | 18篇 |
2014年 | 15篇 |
2013年 | 29篇 |
2012年 | 11篇 |
2011年 | 40篇 |
2010年 | 22篇 |
2009年 | 46篇 |
2008年 | 61篇 |
2007年 | 45篇 |
2006年 | 33篇 |
2005年 | 19篇 |
2004年 | 17篇 |
2003年 | 21篇 |
2002年 | 19篇 |
2001年 | 20篇 |
2000年 | 22篇 |
1999年 | 6篇 |
1998年 | 19篇 |
1997年 | 14篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1983年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有611条查询结果,搜索用时 15 毫秒
101.
In-situ bio-remediation is a viable cleanup alternative for aquifers contaminated by hydrocarbons such as BTEX. Transport models of varying complexity and capabilities are used to quantify their degradation. A model that has gained wide acceptance in applications is BIOPLUME II, which assumes that oxygen-limited biodegradation takes place as an instantaneous reaction. In this work we have employed theoretical analysis, using non-dimensional variables, and numerical modelling to establish a quantitative criterion demarcating the range of validity of the instantaneous reaction approximation against biodegradation kinetics. Oxygen was the limiting species and sorption was ignored. This criterion relates (o), the Dahmk?hler number at oxygen depletion, to O(o)*, the ratio of initial to input oxygen concentration, (o) > or = 0.7(O(o)*)(2) + 0.1O(o)* + 1.8. The derived (o) reflects the intrinsic characteristics of the physical transport and of the biochemical reaction, including the effect of biomass density. Relative availability of oxygen and hydrocarbons exerts a small influence on results. Theory, verified and refined via numerical simulations, showed that significant deviations of instantaneous reactions from kinetics are to be expected in the space-time region s相似文献
102.
Nitrate in groundwater: an isotopic multi-tracer approach 总被引:12,自引:0,他引:12
Widory D Kloppmann W Chery L Bonnin J Rochdi H Guinamant JL 《Journal of contaminant hydrology》2004,72(1-4):165-188
In spite of increasing efforts to reduce nitrogen inputs into groundwater from intensive agriculture, nitrate (NO3) remains one of the major pollutants of drinking-water resources worldwide. Determining the source(s) of NO3 contamination in groundwater is an important first step for improving groundwater quality by emission control, and it is with this aim that we investigated the viability of an isotopic multi-tracer approach (delta15N, delta11B, 87Sr/86Sr), in addition to conventional hydrogeologic analysis, in two small catchments of the Arguenon watershed (Brittany, France). The main anthropogenic sources (fertilizer, sewage effluent, and hog, cattle and poultry manure) were first characterized by their specific B, N and Sr isotope signatures, and compared to those observed in the ground- and surface waters. Chemical and isotopic evidence shows that both denitrification and mixing within the watershed have the effect of buffering NO3 contamination in the groundwater. Coupled delta11B, delta15N and 87Sr/86Sr results indicate that a large part of the NO3 contamination in the Arguenon watershed originates from the spreading of animal manure, with hog manure being a major contributor. Point sources, such as sewage effluents, contribute to the NO3 budget of the two watersheds. 相似文献
103.
The use of coal fly ash (CFA), municipal solid waste incinerator bottom ash (MSWIBA) and flue gas desulfurization residue (FGDR) in road construction has become very common owing to its economical advantages. However, these residues may contain toxic constituents that pose an environmental risk if they leach out and flow through the soil, surface water and groundwater. Therefore, it is necessary to assess the ecotoxicity and groundwater impact of these residues before decisions can be made regarding their utilization for road construction. In this study, the physico-chemical characteristics, leaching and phytotoxicity of these residues were investigated. Specifically, multivariate analyses were used to evaluate the contributions of the leaching constituents of the CFA, MSWIBA and FGDR leachates to the germination index of wheat seeds. B, Ba, Cr, Cu, Fe and Pb were found to be more toxic to the wheat seeds than the other heavy metals. Furthermore, the leached concentrations of the constituents from the CFA, MSWIBA and FGDR were below the regulatory threshold limits of the Chinese identification standard for hazardous wastes. Analyses conducted using a numerical groundwater model (WiscLEACH) indicated that the predicted field concentrations of metals from the CFA, MSWIBA and FGDR increased with time up to about 30 years at the point of compliance, then decreased with time and distance. Overall, this study demonstrated that the risks resulting from MSWIBA, CFA and FGDR leaching could be assessed before its utilization for road construction, providing crucial information for the adoption of these alternative materials. 相似文献
104.
Chronosequences are useful to evaluate long-term changes in ecosystem services but assessing groundwater quality changes using this approach has rarely been done. In this study, groundwater level and quality comparisons were made in a watershed-scale reconstructed prairie chronosequence that extended back in time approximately 13 years at the Neal Smith National Wildlife Refuge (NSNWR) near Prairie City, Iowa. Our objectives were to determine whether groundwater conditions varied significantly across the chronosequence and quantify the rate of nitrate concentration reduction when row crop fields are replaced by prairie. We installed 19 groundwater wells at upland locations selected to provide similar soil type, landscape position and slope. Water samples were collected on five occasions in 2006 and 2007 and analyzed for field parameters, anions and NO3-N, NH4-N and PO4-P. Significant groundwater changes were primarily associated with groundwater levels, and groundwater nitrate and chloride concentrations. The groundwater was deeper under the older prairie plantings but fluctuated similarly among all well sites. Groundwater nitrate and chloride concentrations decreased 0.58 and 0.52 mg/l per year over the 13-year chronosequence, respectively. Results are seen to provide some guidance to land managers regarding possible nitrate concentration reductions achievable from converting cropland to perennial land cover in similar geomorphic settings. 相似文献
105.
Norovirus Detection in Groundwater 总被引:2,自引:0,他引:2
106.
107.
108.
高斯轨迹烟云扩散模型在贵阳空气质量预报中的应用 总被引:4,自引:0,他引:4
选择在复杂地区应用较好的高斯轨迹烟云扩散模型,作为贵阳市空气质量预报的数学扩散模式,并利用贵阳市现有的污染源排放资料和气象资料,对贵阳市的大气污染物分布进行了模拟计算,经与实测结果比较表明:实测值与监测值基本一致,相关性较好。该模式可以作为贵阳市空气质量预报的数学扩散模式,对其他城市也具有一定的借鉴作用。 相似文献
109.
110.
Even in the absence of mobilization of dense nonaqueous phase liquid (DNAPL), the microemulsion that forms when the surfactant solubilizes a dense contaminant such as trichloroethylene will be more dense than water and tends to migrate downward. This paper addresses the issue of migration with a new concept: surfactant enhanced aquifer remediation at neutral buoyancy. Laboratory results of surfactant remediation in two-dimensional model aquifers show that downward migration of microemulsion containing solubilized dense contaminants can be reduced to an acceptable level, even in the absence of capillary barriers in the aquifer. One model experiment was designed to exhibit a small degree of vertical migration and full capture of the microemulsion at the extraction well. The second experiment was designed to demonstrate the effect of large buoyancy forces that lead to excessive downward migration of the microemulsion. Density measurements of aqueous solutions containing sodium dihexyl sulfosuccinate surfactant, isopropanol, trichloroethylene, and sodium chloride are presented. A companion paper presents the results of the flow and transport calculations needed for this approach to surfactant flooding. 相似文献