土壤原位修复技术研究与应用进展

土壤原位修复技术是指不经挖掘,直接在污染场地就地修复污染土壤的土壤修复技术,具有投资低,对周边环境影响小的特点,是土壤修复的研究热点。土壤原位修复技术主要有淋洗,气相抽提（SVE）,多相抽提（MPVE）,气相喷射（IAS）,生物降解,原位化学氧化（ISCO）,原位化学还原,污染物固定,植物修复等。淋洗法主要用于治理高渗透性土壤中的重金属和难挥发降解的有机物。土壤气相抽提和喷射技术适用于处理土壤中的易挥发污染物,并有常与加热技术,生物处理技术等联用,可以起到促进污染物挥发,增氧促分解的作用。多相抽提法主要用于治理存在大量非水相流体的污染场地,可将土壤中有机相污染物直接抽出。生物降解有生物好氧降解、生物厌氧降解、生物还原降解多种,降解方式由污染物种类和地质条件决定。化学方法可将污染物氧化或还原为低毒无毒物质,周期一般较短。固定污染物可以直接加入药剂反应生成沉淀,也可制造合适条件使微生物生成可沉淀重金属的离子。植物修复主要用于富集重金属,成本低廉,但富集了重金属的植物体的有效利用尚待进一步研究。土壤原位修复需要因地制宜,灵活结合工期、污染情况、地质条件、地面设施等,得出最经济实用的修复方法,并在辅助提高技术上展开更多研究,使原位修复技术更经济有效。     

Industrial ecology flows of agriculture and food industry in Finland: utilizing by-products and wastes

Although half of the administrative units in China are said to have implemented their local Agenda 21, the promotion of sustainable communities is not pervasive. In this paper, we adopted a relatively untried mode of analysis and a socio-economic context to illustrate the potentials and failures of China's grassroots local government bodies in achieving sustainable waste management. Our study shows that, among the three main functions of sustainable waste management (ensuring environmental hygiene, provision of recycling logistics and changing the consumption pattern of the local community) for local governments, grassroots local government bodies in mainland China are only able to do the minimum, i.e. ensuring environmental hygiene and handling complaints. One of the reasons for the failure is that, despite the emphasis on capacity building in China's Agenda 21, the reality is that no action is taken to empower grassroots local government. Despite the high profile accorded by the Chinese central government to motivating local governments to formulate their own Agenda 21, local sustainability and waste management performance have little relevance to the appraisal systems of these government agents.     

Heavy metals distribution and risk assessment in soils affected by tannery effluents

Effluents collected from tanneries in Sialkot showed considerably higher levels of heavy metals. Sodium (12 660.91 mg/L) among macronutrients and Cr (592.20 mg/L) among heavy metals were found in the highest concentrations. Effluent parameters, i.e. biological oxygen demand (BOD; 12.40), chemical oxygen demand (COD; 16.53), Cd (5.90), Cr (592.20) and Fe (18.59) were the respective times higher than Pakistan National Environmental Quality Standards and their continuous unchecked discharge into agricultural soils poses a potential risk. Mean concentrations (mg/L) of Cr (592.20), Ni (2.66), Mn (1.16), Fe (37.17), Zn (0.90), Cd (0.59) and Pb (1.18) in this study exceeded levels recorded to date from different tanning hubs in Pakistan. Factor analysis/principal components analysis (FA/PCA) for the effluent parameters resulted in six varimax factors, i.e. VF1 (salinity, electrical conductivity, total dissolved solids, chloride, phosphate, BOD and COD; including characteristic tannery effluent features), VF2 (pH, Cr and alkalinity; tanning operations), VF3 (Cd and Pb; dyeing processes), VF4 (Mn and Fe; finishing operations), VF5 (Ni; retaining processes) and VF6 (hardness, Ca and Cu; bating processes). Cluster analysis performed on metal data resulted in three clusters confirming metal–metal relations obtained either from FA/PCA or a correlation matrix. The results of this study are useful for heavy metal source apportionment, assessment of risk to peripheral soils and the future management of environments around tanneries.     

Impact of heavy metals of industrial plant wastewater on benthic communities of Bizerte Lagoon (Tunisia)

ABSTRACT

The aim of this study was to assess the consequences of human impact on the characteristics of sediments heavy metal concentration, grain size and its influence on the structure of the microbial and meiofaunal community assemblages. A survey was carried out in July 2013 within six sites located in the Bizerte Lagoon (Tunisia), both downstream and upstream of industrial effluents. The highest total sediment metal concentrations were detected in stations located close to the industrial sewage discharge points. In these stations, the lowest densities of the total meiofauna (33?±?13?ind/10?cm^?2) and conversely the highest densities of cultivable bacteria that are heavy metal resistant have been reported (16?±?80.34?CFU?g^?1). Univariate (ANOVA) and multivariate (MDS/CCA) analyses demonstrate high dissimilarity (0.06) in meiofaunal and bacterial community structures between downstream and upstream industrial sewages. Furthermore, canonical correspondence analysis CCA results indicated that heavy metal sediment contamination promoted bacteria that are resistant to heavy metals, while heterotrophic bacteria supported the development of meiofauna taxa. The results highlight the importance of bacteria/meiofauna interactions, as both meiofaunal and microbial communities give indications of the ecological impact of heavy metal contamination in sediment.     

Environmental federalism and environmental liability

Environmental federalism considers what level of government should optimally regulate pollution. This paper addresses this question for accidental pollution, which government regulates through the ex post liability regimes of either negligence or strict liability. We find that decentralizing the choice between these regimes does not, in general, induce the socially optimal outcome. When firms can pay all damages, all regions may choose negligence and impose an overly strict standard of due care. When firms may be bankrupted by damages, all regions may choose strict liability, which induces too little care. In addition, asymmetric equilibria are possible in which some regions choose negligence, others strict liability. Combining negligence with a Pigovian tax, or strict liability with a bonding requirement can align regional authorities' incentives with those of a central government.     

RAPID-N: Rapid natech risk assessment and mapping framework

Natech accidents at industrial plants are an emerging risk with possibly serious consequences. For the mitigation of natech risk, authorities need to identify natech prone areas in a systematic manner. In order to facilitate probabilistic natech risk mapping, a unified methodology was developed that is based on the estimation of on-site natural hazard parameters, determination of damage probabilities of plant units, and assessment of probability and severity of possibly triggered natech events. The methodology was implemented as an on-line, extensible risk assessment and mapping software framework called RAPID-N, which allows rapid local and regional natech risk assessment and mapping with minimal data input. RAPID-N features an innovative data estimation framework to complete missing input data, such as on-site natural hazard parameters and plant unit characteristics. The framework is also used for damage assessment and natech consequence analysis, and allows easy modification of input parameters, dynamic generation of consequence models according to data availability, and extension of models by adding new equations or substituting existing ones with alternatives. Results are presented as summary reports and interactive risk maps, which can be used for land-use and emergency planning purposes by using scenario hazards, or for rapid natech consequence assessment following actual disasters. As proof of concept, the framework provides a custom implementation of the U.S. EPA's RMP Guidance for Offsite Consequence Analysis methodology to perform natech consequence analysis and includes comprehensive data for earthquakes. It is readily extendible to other natural hazards and more comprehensive risk assessment methods.     

Energy Consumption in the Turkish Industrial Sector

Turkey's primary energy resources seem limited as indigenous energy production meets nearly 31 % of the total primary energy demand. But the growth of Turkey's industry gives rise to a substantial increase in energy demand. Final energy consumption grew from 52.6 Mtoe (million tons of oil equivalent) in the year 1990 to 78.4 Mtoe in the year 2002. Industrial demand accounts for about 41.6 % of the final energy demand in Turkey. Basic metal industries, non-metallic material products and chemical and petroleum products have the highest energy consumption in industrial sector. In this work, industrial energy consumption and energy consumption of different indsutrial subsectors in Turkey are investigated.     

The Spanish building crisis and its effect in the gypsum quarry production (1998–2012)

Gypsum is one of the most important mined mineral commodities of the world. As an industrial rock, it is primarily used by the construction industry. Therefore, the economics of the gypsum market can be correlated with parameters that have controlled the origin and development of the Spanish building bubble between years 1998 and 2006. The burst of this building bubble has been interpreted as the main triggering factor for Spain's current crisis.     

Corporate environmental responsibility in the supply chain

A continuing trend in outsourcing increases the complexity of supply chains. Global supply chains extend over numerous echelons of countless companies. In parallel, the company-internal view on corporate environmental responsibility is being challenged as customers and legislation alike broaden a company's environmental responsibility to include organisations' upstream as well as downstream in the supply chain. Therefore, the aim of this study was to examine corporate environmental responsibility beyond corporate boundaries, i.e. in the supply chain. A cross-industrial study based on 16 case studies in Finnish trans-national corporations sheds light on various dimensions of corporate environmental responsibility upstream and downstream of product and process supply chains. Conclusions were drawn for corporate environmental responsibility as well as for the role of supply chain management in extending environmental demand over several echelons and diverse industries.     

Will progress in science and technology avert or accelerate global collapse? A critical analysis and policy recommendations

Industrial society will move towards collapse if its total environmental impact (I), expressed either in terms of energy and materials use or in terms of pollution, increases with time, i.e., dI/dt > 0. The traditional interpretation of the I = PAT equation reflects the optimistic belief that technological innovation, particularly improvements in eco-efficiency, will significantly reduce the technology (T) factor, and thereby result in a corresponding decline in impact (I). Unfortunately, this interpretation of the I = PAT equation ignores the effects of technological change on the other two factors: population (P) and per capita affluence (A). A more heuristic formulation of this equation is I = P(T)·A(T)·T in which the dependence of P and A on T is apparent. From historical evidence, it is clear that technological revolutions (tool-making, agricultural, and industrial) have been the primary driving forces behind successive population explosions, and that modern communication and transportation technologies have been employed to transform a large proportion of the world’s inhabitants into consumers of material- and energy-intensive products and services. In addition, factor analysis from neoclassical growth theory and the rebound effect provide evidence that science and technology have played a key role in contributing to rising living standards. While technological change has thus contributed to significant increases in both P and A, it has at the same time brought about considerable eco-efficiency improvements. Unfortunately, reductions in the T-factor have generally not been sufficiently rapid to compensate for the simultaneous increases in both P and A. As a result, total impact, in terms of energy production, mineral extraction, land-use and CO₂ emissions, has in most cases increased with time, indicating that industrial society is nevertheless moving towards collapse. The belief that continued and even accelerated scientific research and technological innovation will automatically result in sustainability and avert collapse is at best mistaken. Innovations in science and technology will be necessary but alone will be insufficient for sustainability. Consequently, what is most needed are specific policies designed to decrease total impact, such as (a) halting population growth via effective population stabilization plans and better access to birth control methods, (b) reducing total matter-energy throughput and pollution by removing perverse subsidies, imposing regulations that limit waste discharges and the depletion of non-renewable resources, and implementing ecological tax reform, and (c) moving towards a steady-state economy in which per-capita affluence is stabilized at lower levels by replacing wasteful conspicuous material consumption with social alternatives known to enhance subjective well-being. While science and technology must play an important role in the implementation of these policies, none will be enacted without a fundamental change in society’s dominant values of growth and exploitation. Thus, value change is the most important prerequisite for avoiding global collapse.