Calculation of the stability criterion in the reaction of energetic materials

The stability in the energetic materials' thermal decomposition reaction is developed from both transient mass and heat transfer equations simultaneously. The derived equation is the sufficient and necessary condition for the reaction system's stability, which was expressed as:

In this stability equation, a modified Semenov number φ is the expressed function of three kinetic parameters, i.e., n, and β and two variables, i.e., x and θ, respectively. A reaction system is stable if its evaluated modified Semenov number satisfies this stability criterion. In the case of the minimum modified Semenov number φ_m, we can deduce the stability equation at critical condition as

The criteria of stability for the explosives TNT, RDX, PETN and HMX were evaluated using this formula, which was expressed θ_c as function of x at given n, η and various β as parameters.     

爆破动载影响矿柱稳定性的研究

针对铜坑锡矿细脉带17~#采场16~#矿柱,用模拟试验方法研究和分析了爆破动载对该矿柱稳定性的影响,并用现场验证结果修正了动载安全系数。指出爆破动载作用是影响矿柱稳定性的主要方面,从爆破动载的角度提出了设计安全、可靠矿柱的具体要求,建议在设计地下采场矿柱时,不但要考虑静载的作用,而且要考虑撂破动载的作用,相应地提出了与所研究的现场矿柱岩性相适应的具体矿柱设计经验公式,为同类矿体设计提供了科学依据。     

用液膜分离技术处理含铅废水

探讨了水中Ｐｂ＾２＋在以Ｐ５０７为流动载体、ＬＭＳ－２为表面活性剂的煤油－柠檬酸乳状液液膜体系的传输过程。考察了外相酸度,内水相酸度和浓度,膜相载体浓度,膜相表面活性剂肖度以及乳水比等因素对铅去除率的影响,找到了乳状液液膜体系最佳组成。采用这种分离技术对含Ｐｂ＾２＋１００ｍｇ／Ｌ的水样进行处理,铅去除率可达９４％。     

Norms for Behavior and Conditions in Two National Park Campgrounds in Korea

/ This study was conducted to examine norm prevalence, norm agreement, and norm stability in an international setting. Data were collected at two campgrounds in Chiri-Mountain National Park, Korea, in 1993 and 1994. Results showed that a high proportion of users could specify norms for various types of campground impacts. Users who rated high importance on impacts tended to show a higher level of norm prevalence. Generally there were differences in social norms and norm agreement across locations. Among those impacts that showed differences, social norms in a less developed area were more restrictive and norm agreement was higher. The results of this study are consistent with normative studies conducted in North America, suggesting that a normative approach can be applied in a variety of settings. Social norms for selected impact indicators were also stable over a one-year time period. Implications are discussed.KEY WORDS: Norms; Norm prevalence; Norm agreement; Norm stability     

ASSESSING STREAM CHANNEL STABILITY THRESHOLDS USING FLOW COMPETENCE ESTIMATES AT BANKFULL STAGE1

ABSTRACT: Stream channel stability is affected by peak flows rather than average annual water yield. Timber harvesting and other land management activities that contribute to soil compaction, vegetation removal, or increased drainage density can increase peak discharges and decrease the recurrence interval of bankfull discharges. Increased peak discharges can cause more frequent movement of large streambed materials, leading to more rapid stream channel change or instability. This study proposes a relationship between increased discharge and channel stability, and presents a methodology that can be used to evaluate stream channel stability thresholds on a stream reach basis. Detailed surveys of the channel cross section, water surface slope, streambed particle size distribution, and field identification of bankfull stage are used to estimate existing bankfull flow conditions. These site specific stream channel characteristics are used in bed load movement formulae to predict critical flow conditions for entrainment of coarse bed material (D₈₄ size fraction). The “relative bed stability” index, defined as the ratio of critical flow condition to the existing condition at bankfull discharge, can predict whether increased peak discharges will exceed stream channel thresholds.     

煤与瓦斯突出延期发生的原因探讨──“球壳失稳”假说的解释性研究之一

依据球壳失稳假说的原理对煤与瓦斯突出延期发生的原因进行了探讨，并且针对延期突出的危害和特点提出了相应的对策。     

HUMAN STABILITY IN A HIGH FLOOD HAZARD ZONE1

ABSTRACT: The delineation of high flood hazard zones within a flood plain is usually independent of the hydraulic parameters that constitute a life threatening situation. In order to define human instability in high hazard areas, a study was conducted to identify when an adult human could not stand or maneuver in a simulated flood flow. An analysis was performed on a rigid body monolith resulting in a toppling hazard envelope curve (velocity vs. depth). A 120 lb monolith was then constructed and tested to relate the actual flow velocity and depth at toppling to theory. A series of human subjects (90–201 Ibs) were placed in a recirculating flume and tested to determine the velocity and depth of flow that caused their instability. The test results determined that the product number, which is the product of the velocity and depth at toppling of the monolith, closely compared to the theoretical envelope curve. The monolith results represent the lower limit of human stability. Also, the product number appeared to be a predictor of human instability in flood flow. A relationship was developed to estimate the product number at which a human subject becomes unstable as a function of the height and weight of the subject.     

FLUVIAL PROCESSES AND MORPHOLOGICAL THRESHOLDS IN INCISED CHANNEL RESTORATION1

ABSTRACT: Incised channels are those in which an imbalance between sediment transport capacity and sediment supply has led to degradation of their beds. This is a frequent response to stream channelization, changes in land use, or lowering of base level. If the degradation causes a critical bank-height threshold to be exceeded, which is dependent on the geotechnical properties of the bank materials, then bank failure and channel widening follow. Interdependent adjustments of channel slope and cross-sectional area occur until a new state of dynamic equilibrium with the imposed discharge and sediment load is attained. These geomorphic adjustments can be described and quantified by using location-for-time substitution and a model of channel evolution can be formulated. Three approaches to rehabilitation of the degraded channels are possible; geomorphic, engineering and rational. The rational approach, which integrates elements of both the engineering and geomorphic approaches, is based on the channel evolution model, and it generally involves control of grade, control of discharge, or a combination of both.     

Changes in interacting species with disturbance

Human-influenced changes in the diversity and abundance of native wildlife in a southern boreal forest area, which became a national park in 1975, are used to develop working hypotheses for predicting and subsequently measuring the effects of disturbance or restoration programs on groups of interacting species. Changes from presettlement conditions began with early 1900 hunting, which eliminated woodland caribou (Rangifer tarandus) and elk (Cervus elaphus), and reduced moose (Alces alces) to the low numbers which still persist. Increases in white-tailed deer (Odocoileus virginianus), as these other cervid species became less abundant or absent, provided enough alternative food to sustain the system's carnivores until plant succession on previously burned or logged areas also caused deer to decline. With increased competition for reduced food, carnivore species also became less abundant or absent and overexploited some prey populations. The abilities of interacting species to maintain dynamically stable populations or persist varied with their different capacities to compensate for increased exploitation or competition. These relationships suggested a possible solution to the problem of predicting the stability of populations in disturbed systems. For the 1976–1985 period, a hypothesis that the increased protection of wildlife from exploitation in a national park would restore a more diverse, abundant, and productive fauna had to be rejected.     

A study on hexachromic ion selective electrode based on supported liquid membranes

An ion selective electrode (ISE) for determining Cr(VI) using supported liquid membranes (SLMs) containing trioctylphosphine oxide (TOPO) was investigated in this study. TOPO, as a carrier, had a high selectivity for Cr(VI) against interfering ions such as sulfate, nitrate, nitrite, and chloride. The composition of the SLM was optimized as 0.193 g TOPO/1 mL NPOE (o-nitrophenyl octyl ether)/0.5 g poly (vinyl chloride) for detection of Cr(VI). The Cr(VI) concentration was measured in the range of1 × 10^-3 to 1 × 10^-6 M with the SLM prepared in the study. It seemed that Cr(VI) was transported in the SLM as a triply charged ion indicated by the slope of the emf response. Selectivity coefficients and detection limits of Cr(VI) in the presence of interfering ions were determined experimentally using the fixed interference method.