Preparation of cross-linked magnetic chitosan with quaternary ammonium and its application for Cr(VI) and P(V) removal

Pollutants that exist in anionic species are issues of concern in water treatment. Compared to cationic pollutants, the removal of anionic pollutants by adsorption is more difficult because most adsorbents carry predominantly negative charges in neutral and alkaline environments. In this study, a cross-linked chitosan derivative with quaternary ammonium and magnetic properties（QM-chitosan） was prepared and employed to remove chromium（VI） and phosphorus（V）（Cr（VI） and P（V）） from aqueous environments. The QM-chitosan was characterized by Fourier transform infrared spectrometry（FT-IR）,thermogravimetric analysis（TGA）, energy dispersive X-ray（SEM-EDX） and zeta potential.Batch experiments show that QM-chitosan can effectively remove Cr（VI） and P（V）, and the main mechanism was believed to be electrostatic interaction. A pseudosecond-order model was fitted to describe the kinetic processes of Cr（VI） and P（V） removal. The adsorption isotherms of both Cr（VI） and P（V） on the QM-chitosan were well fitted by the Langmuir isotherm equation. The saturated adsorption capacity of P（V）（2.783 mmol/g） was found to be higher than that of Cr（VI）（2.323 mmol/g）, resulting from the size of the H2PO-4ions being smaller than that of the HCr O-4ions. However, the theoretical calculation and experimental results showed that QM-chitosan had a stronger affinity for Cr（VI） than P（V）. The adsorption–desorption of the QM-chitosan was evaluated, and high regeneration rates were demonstrated.     

Magnetic properties of the microorganism Candidatus Magnetoglobus multicellularis

Magnetotactic microorganisms use the interaction of internal biomineralized nanoparticles with the geomagnetic field to orientate. The movement of the magnetotactic multicellular prokaryote Candidatus Magnetoglobus multicellularis under an applied magnetic field was observed. A method using digital image processing techniques was used to track the organism trajectory to simultaneously obtain its body radius, velocity, U-turn diameter, and the reorientation time. The magnetic moment was calculated using a self-consistent method. The distribution of magnetic moments and radii present two well-characterized peaks at (9 ± 2) × 10⁻¹⁵ and (20 ± 3) × 10⁻¹⁵ A m² and (3.6 ± 0.1) and (4.3 ± 0.1) μm, respectively. For the first time, simultaneous determination of the distribution of the organism radii and magnetic moment was obtained from the U-turn method by a new digital imaging processing. The bimodal distributions support an organism reproduction process model based on electron microscopy observations. These results corroborate the prokaryote multicellular hypothesis for Candidatus M. multicellularis.     

Homing pigeons (<Emphasis Type="Italic">Columba livia</Emphasis> f. <Emphasis Type="Italic">domestica</Emphasis>) can use magnetic cues for locating food

An experimental group of homing pigeons (Columba livia f. domestica) learned to associate food with a magnetic anomaly produced by bar magnets that were fixed to the bowl in which they received their daily food ration in their home loft; the control group lacked this experience. Both groups were trained to search for two hidden food depots in a rectangular sand-filled arena without obvious visual cues; for the experimental birds, these depots were also marked with three 1.15 × 10⁶ μT bar magnets. During the tests, there were two food depots, one marked with the magnets, the other unmarked; their position within the arena was changed from test to test. The experimental birds searched within 10 cm of the magnetically marked depot in 49% of the test sessions, whereas the control birds searched there in only 11% of the sessions. Both groups searched near the control depot in 11 and 13% of the sessions, respectively. The significant preference of the magnetically marked food depot by the experimental birds shows that homing pigeons cannot only detect a magnetic anomaly but can also use it as a cue for locating hidden food in an open arena.     

基于环境磁学响应监测林地土壤中金属元素

采集并测试广州市林地土壤样品600余组,分析土壤中As、Cr、Cd、Hg、Cu、Pb、Zn、Ni和磁学性质的相关性。结果表明：土壤磁性颗粒以软磁性矿物为主,北部以超顺磁、多畴颗粒为主,南部以单畴、多畴颗粒为主。相关性分析表明：北部Cu、Ni、Cr、Cd与较粗的磁性颗粒共存,Cd与软磁性矿物共存,As与超顺磁颗粒共存且为自然源;南部相关关系不显著,Ni和As来源为人为源;不同污染程度土壤回归方程相关系数均较好,南部深〖CD*2〗浅层回归方程证明上述8种元素和磁性相关性不受自然来源或人类活动影响。     

Enhancement on the ammonia oxidation capacity of ammonia-oxidizing archaeon originated from wastewater: Utilizing low-density static magnetic field

• AOA’s ammonia oxidizing capacity was enhanced under moderate magnetic field. • AOA possessed a certain magnetotaxis under uneven magnetic field. • Enhanced ammonia oxidizing capacity was lost once magnetic field was removed. Ammonia-oxidizing archaeon (AOA) could play important roles for nitrogen removal in the bioreactors under conditions such as low pH and low dissolved oxygen. Therefore, enhancing ammonia oxidation capability of AOA has great significance for water and wastewater treatment, especially under conditions like low dissolved oxygen concentration. Utilizing a novel AOA strain SAT1, which was enriched from a wastewater treatment plant by our group, the effect of magnetic field on AOA’s ammonia oxidation capability, its magnetotaxis and heredity were investigated in this study. Compared with control experiment, AOA’s maximum nitrite-N formation rate during the cultivation increased by 56.8% (0.65 mgN/(L·d)) with 20 mT magnetic field. Also, it was testified that AOA possessed a certain magnetotaxis. However, results manifested that the enhancement of AOA’s ammonia oxidation capability was not heritable, that is, lost once the magnetic field was removed. Additionally, the possible mechanism of improving AOA’s ammonia oxidation capability by magnetic field was owing to the promotion of AOA single cells’ growth and fission, rather than the enhancement of their ammonia oxidation rates. The results shed light on the application of AOA and methods to enhance AOA’s ammonia oxidation capability, especially in wastewater treatment processes under certain conditions.     

Fabrication of magnetic multi-template molecularly imprinted polymer composite for the selective and efficient removal of tetracyclines from water

• Magnetic multi-template molecularly imprinted polymer composite was synthesized. • MIP composite was used as the adsorbent for removal of tetracyclines from water. • MIP composite showed excellent adsorption selectivity toward tetracyclines. • MIP composite possessed good reusability. Antibiotic contamination of the water environment has attracted much attention from researchers because of their potential hazards to humans and ecosystems. In this study, a multi-template molecularly imprinted polymer (MIP) modified mesoporous silica coated magnetic graphene oxide (MGO@MS@MIP) was prepared by the surface imprinting method via a sol-gel process and was used for the selective, efficient and simultaneous removal of tetracyclines (TCs), including doxycycline (DC), tetracycline (TC), chlorotetracycline (CTC) and oxytetracycline (OTC) from water. The synthesized MIP composite was characterized by Fourier transform infrared spectroscopy, transmission electron microscope and thermogravimetric analysis. The adsorption properties of MGO@MS@MIP for these TCs were characterized through adsorption kinetics, isotherms and selectivity tests. The MIP composite revealed larger adsorption quantities, excellent selectivity and rapid kinetics for these four tetracyclines. The adsorption process was spontaneous and endothermic and followed the Freundlich isotherm model and the pseudo-second-order kinetic model. The MGO@MS@MIP could specifically recognize DC, TC, CTC and OTC in the presence of some chemical analogs. In addition, the sorption capacity of the MIP composite did not decrease significantly after repeated application for at least five cycles. Thus, the prepared magnetic MIP composite has great potential to contribute to the effective separation and removal of tetracyclines from water.     

Optimized pre-treatment of high strength food waste digestate by high content aluminum-nanocluster based magnetic coagulation

Coagulation-based pre-treatment efficiency of high strength digestate of food waste (HSDFW) anaerobic digestion is negated by organic ligand-catalyzed decomposition of coagulants. In this study, an efficient HSDFW pre-treatment method, magnetic seeds (MS) coagulation, was employed by using highly stable Keggin Al₃₀ nanocluster (PAC₃₀), MS and polyacrylamide (PAM), and its operation was optimized by evaluating the performance of removing turbidity, total suspended solids (TSS), chemical oxygen demand (COD), and total phosphorous (TP) phosphate. Results showed that at the optimum dosage of 4.82 g/L, PAC₃₀ demonstrated excellent removals as high as 98.93% ± 0.1% of turbidity, 98.04% ± 0.1% of TSS, 58.28% ± 0.3% of total COD, 99.98% ± 0.01% of TP and 99.50% ± 0.01% of dissolved phosphate, respectively. Apparent molecular weight (AMW) and three-dimensional excitation-emission matrix (3D-EEM) fluorescence spectroscopy analyses demonstrated more efficient removal of dissolved organic matter (DOM), particularly non-biodegradable and hydrophobic components by PAC₃₀ than commercial coagulant. The sedimentation was much improved from 40 min by coagulation/flocculation to about 5 min settling by MS coagulation. The PAC₃₀ based magnetic coagulation (MC) presents theoretical guidance on a cost-effective and much less footprint pre-treatment alternative for high strength wastewater.