全文获取类型
收费全文 | 103篇 |
免费 | 0篇 |
国内免费 | 34篇 |
专业分类
安全科学 | 11篇 |
废物处理 | 1篇 |
环保管理 | 16篇 |
综合类 | 71篇 |
基础理论 | 16篇 |
污染及防治 | 11篇 |
评价与监测 | 8篇 |
社会与环境 | 2篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 11篇 |
2020年 | 9篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 6篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 8篇 |
2013年 | 5篇 |
2012年 | 3篇 |
2011年 | 9篇 |
2010年 | 2篇 |
2009年 | 5篇 |
2008年 | 8篇 |
2007年 | 12篇 |
2006年 | 4篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2003年 | 7篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 5篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
排序方式: 共有137条查询结果,搜索用时 109 毫秒
31.
Regeneration of pure water is an important issue not only for the healthy life but also for the fine control of precise processes in various industries.One important issue in ultrahigh purified water is to reduce the amount of total organic carbon(TOC).Herein,we introduce a new approach to reduce the TOC using the surface silanized nanoparticles,in which the magnetic nanoparticles(mNPs) are silanized and then complexed with ion exchange resin(IER) beads.The Fe_3O_4 mNPs are surface modified by using high concentrated vinyltrimethoxysilane(VTMS) and then adhered on the surface of IER beads.The surface modified mNPs have a thick-shell of polysiloxane layer varying from 5 to 22 nm depending on the amount of VTMS used,which leads the significant increase of specific surface area.The IER beads embedding VTMS-silanized mNPs achieves about 7 μg/L of the TOC level in ultrapure water system,which is two orders less than 228 μg/L of the feeding water and one order less than 96 μg/L from the system using pristine IER beads.This result is mainly attributed to the polysiloxane layer forming broccoli-like surface structure and some part by the vinyl group of VTMS exposed to the amines in the water. 相似文献
32.
Excessive nitrate(NO_3~-) is among the most problematic surface water and groundwater pollutants.In this study,a type of magnetic cationic hydrogel(MCH) is employed for NO_3~-adsorption and well characterized herein.Its adsorption capacity is considerably pHdependent and achieves the optimal adsorption(maximum NO_3~--adsorption capacity is95.88±1.24 mg/g) when the pH level is 5.2-8.8.The fitting result using the homogeneous surface diffusion model indicates that the surface/film diffusion controls the adsorption rate,and NO_3~-approaches the center of MCH particles within 30 min.The diffusion coefficient(D_s) and external mass transfer coefficient(k_F) in the liquid phase are1.15 × 10~(-6) cm~2/min and 4.5 × 10~(-6) cm/min,respectively.The MCH is employed to treat surface water that contains 10 mg/L of NO_3~-,and it is found that the optimal magnetic separation time is 1.6 min.The high-efficiency mass transfer and magnetic separation of MCH during the adsorption-regeneration process favors its application in surface water treatment.Furthermore,the study of the mechanism involved reveals that both-N~+(CH_3)_3 groups and NO_3~-are convoluted in adsorption via electrostatic interactions.It is further found that ion exchange between NO_3~-and chlorine occurs. 相似文献
33.
Magnetic Fe0/Fe3O4/graphene has been successfully synthesized by a one-step reduction method and investigated in rapid degradation of dyes in this work. The material was characterized by N2 sorption–desorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), vibrating-sample magnetometer (VSM) measurements and X-ray photoelectron spectroscopy (XPS). The results indicated that Fe0/Fe3O4/graphene had a layered structure with Fe crystals highly dispersed in the interlayers of graphene, which could enhance the mass transfer process between Fe0/Fe3O4/graphene and pollutants. Fe0/Fe3O4/graphene exhibited ferromagnetism and could be easily separated and re-dispersed for reuse in water. Typical dyes, such as Methyl Orange, Methylene Blue and Crystal Violet, could be decolorized by Fe0/Fe3O4/graphene rapidly. After 20 min, the decolorization efficiencies of methyl orange, methylene blue and crystal violet were 94.78%, 91.60% and 89.07%, respectively. The reaction mechanism of Fe0/Fe3O4/graphene with dyes mainly included adsorption and enhanced reduction by the composite. Thus, Fe0/Fe3O4/graphene prepared by the one-step reduction method has excellent performance in removal of dyes in water. 相似文献
34.
Maghemite (ϒ-Fe2O3) nanoparticles were impregnated to nanoporous carbon obtained from tomato waste (TWNC). The prepared magnetic composite (MTWNC) was characterized and used to remove tetracycline (TC) from water and then easily be separated from the medium by a magnetic technique. The morphologies and surface chemistries of both magnetic and non-magnetic nanoporous carbons were studied by FTIR, XRD, SEM, SEM-EDX, VSM, BET surface area, proximate and elemental analysis determinations. Batch adsorption studies were carried out and the effects of pH, initial TC concentration, adsorbent dose, ionic strength and temperature were investigated. The adsorption kinetics of TC on MTWNC could be expressed well by the pseudo-second order model, and sorption isotherms were described by Langmuir equation with maximum adsorption capacity of 60.60 mg/g at pH 4 and 50 °C. Thermodynamic parameters showed that the adsorption of TC onto MTWNC was feasible, spontaneous and endothermic. Furthermore, the recyclability of the adsorbent was tested with 0.01 M NaOH solution, and the results show that the synthesized composite adsorbent could be employed repeatedly in wastewater treatment. 相似文献
35.
实验以取自浙江湖州有机微污染水作为研究对象,研究了PAC,PFS,PAFC,KAl(SO4)2及FeCl3等常用混凝剂对该有机微污染水的CODMn的去除效果,结果表明PAC为处理该有机微污染水的最佳混凝剂,最佳投加量为30 mg/L。同时还研究了加载磁粉对有机微污染水混凝处理效果的影响,结果表明加载磁粉粒径为45μm,投加量为30 mg/L时,同一原水的CODMn去除率从常规混凝的39.3%提高到45.6%,且加载磁粉后大大缩短了混凝沉淀时间,符合微污染水源的应急处理要求,最佳投放顺序为:“磁粉+PAC+PAM”。 相似文献
36.
Mehri Kaviani Moghadam Saied Mohammad Firoozabadi Mahyar Janahmadi 《The Environmentalist》2008,28(4):341-347
In spite of growing concern about the influence of magnetic fields on biological systems, the interaction between extremely
low frequency magnetic field (ELF magnetic fields) and biological structures at the cellular level remains obscure. The aim
of this study was to investigate if 50 Hz magnetic fields could have an effect on the neuronal excitability and firing responses.
Under Current-Clamp condition, exposure to 50 Hz ELF magnetic fields at 2 mT or 0.8 mT intensities resulted in an increase
in the peak amplitude of action potential and after hyperpolaization potential in a time dependent manner. Both magnetic field
intensities decreased also the firing frequency and the duration of action potential. Taken together, these data suggest that
50 Hz ELF magnetic fields at 2 mT or 0.8 mT intensities may change the electrophysiological behavior of neuronal cells and
underlying ion channel currents. 相似文献
37.
磁种-磁滤技术处理污染河水的试验研究 总被引:1,自引:0,他引:1
采用磁种-磁滤技术处理广州市两条河涌的污染水,考察了磁种投加量、混凝剂用量、磁场强度和磁滤速度对出水浊度的影响,并确定了最佳试验条件。结果表明,该工艺对TP、SS和浊度的去除效果较好,去除率分别为96.2%、92.4%和93.9%,对CODCr有一定的去除效果,去除率为68.2%,但对NH4^ -N的去除效果较差,去除率仅为25%。 相似文献
38.
39.
Occupational exposure to radiofrequency (RF) and static magnetic fields at magnetic resonance imaging (MRI) suites is of continuing
concern to personnel who routinely work in this environment. Questions regarding the levels of occupational RF and static
field exposure have increased with the increasing demand for anesthetics to be administered in this environment. The present
study was thus designed towards addressing the above-mentioned problem by gaining information regarding exposure levels of
clinical personnel at MRI units in South Africa. Three 1.5 MRI units in Bloemfontein, South Africa were utilized to evaluate
the exposure of clinical personnel to the electromagnetic fields present in the MRI environment over a period of time and
during different clinical MRI procedures. Three rounds of measurements of RF fields in the MRI environment were done. All
the three measurement rounds were focused on the low frequencies, 5 Hz–32 kHz, as well as on the high frequencies, 300 kHz–40 GHz.
First round measurements were done to establish the background of the RF fields in and around the magnet room during an MRI
examination. Second round RF field measurements were done at a specific location, 1 m away from the bore on the right-hand
side of the bed, in the MRI room. The third round measurements were of the same format as the second round, but the specific
location was against the magnet bore. Two pieces of Narda Safety Test Solution instruments, the EFA-300 and EMR-300, were
used to measure the electromagnetic and magnetic exposure fields generated from the MRI scanners. Results of the measurements
indicate that the electromagnetic fields measured during different clinical procedures do not exceed the International Commission
on Non-Ionizing Radiation Protection (2000) guidelines in these units. Results from round two and three showed that the RF
and gradient exposure 1 m and up against the bore entrance does not exceed these guidelines (rms average over 6 min). Ongoing
new developments in MRI scanning create the need for continuously monitoring exposure of patients and workers to the EMF fields
in the MRI environment. 相似文献
40.
The magnetic properties of tree leaves along with their ecological, economical and aesthetic importance can be used to control
road derived respirable particulates. Isothermal remanent magnetization (IRM300 mT) of three different tree leaves viz. Mango (Mangifera indica), Sisso (Dalbergia sisso) and Banyan (Ficus benghalensis) were determined and IRM300 mT normalized for the leaf area. The normalized 2-D magnetization of leaves as shown by results is dominantly controlled
by leaf morphology and traffic density. F. benghalensis (Banyan) leaf has highest 2-D magnetization and D. sisso (Sisso) leaf having least 2-D magnetization suggesting greater ability of F. benghalensis (Banyan) tree leaves to reduce magnetic particulates. The particle size of the magnetic grains falls in the category of PM2.5,
a particle size hazardous to human health due to its capacity to be inhaled deeply into the lungs. 相似文献