城市污水处理厂及其受纳水体中5种典型PPCPs的赋存特征和生态风险

以5种药品及个人护理用品(pharmaceuticals and personal care products,PPCPs)包括氯贝酸、酮洛芬、萘普生、双氯芬酸和布洛芬为目标物,初步研究了它们在上海某生活污水处理厂不同污水处理单元中的赋存特征和去除特性,探讨了污水处理厂受纳河流中5种PPCPs的分布情况,并对其在受纳水体中的生态风险进行了初步评估.结果表明,5种PPCPs在污水处理厂进水中均被检出,表明生活污水是污水处理厂中PPCPs的来源之一.5种PPCPs在整个污水处理工艺中不能全部去除,微生物转化/降解是主要降解机制.受纳污水河流中5种PPCPs的分布特征与污水处理厂出水中的相似,且排污口下游水体中目标物浓度普遍高于上游,反映出污水处理厂排放可能是其受纳水体中PPCPs的主要来源之一.初步风险评估结果表明,受纳水体中双氯芬酸存在高生态风险,而酮洛芬、萘普生、氯贝酸和布洛芬的生态风险相对较低.     

Effect of TiO2 nanoparticle aggregation on marine microalgae Isochrysis galbana

TiO_2 nanoparticles(NPs) could adversely impact aquatic ecosystems. However, the aggregation of these NPs could attenuate this effect. In this work, the biological effects of TiO_2 NPs on a marine microalgae Isochrysis galbana were investigated. The aggregation kinetics of TiO_2 NPs under different conditions was also investigated to determine and understand these effects. Results showed that, though TiO_2 NPs had no obvious impact on the size and reproducibility of algal cells under testing conditions, they caused a negative effect on algal chlorophyll, which led to a reduction in photosynthesis. Furthermore, fast aggregation of TiO_2 NPs occurred under all conditions, especially at the pH close to the p Hzpc. Increasing ionic strength and NP concentration also enhanced the aggregation rate.The aggregation and the following sedimentation of TiO_2 NPs reduced their adverse effects on I. galbana.     

浅议环境法的绿色专利

人们通常强调新颖性和经济效用的一个创新,而忽略了对环境造成的影响。这一思想体现到制度设计专利制度。一般来说,如果能够通过三个条件：新颖性、实用性和创新性,可授予专利。这种制度设计制约思维过程中创新者的回报,他们努力发明一件新颖的且有利可图的专利,但是忽略了对环境造成的影响。因此,牺牲的最终是环境。在这项研究中,试图探索一种体制上的补救。在为了改变科技发展的方向,建议完善政策背景下的创新,特别是专利制度。引进一个新的考核标准,绿色专利制度,并探讨其可行性和可能带来的影响。通过把这项环保的关注到专利审查,专利制度可以鼓励创新发明的＂创新,实用和绿色＂的产品以及程序,称之为＂绿色专利＂。     

油码头污染防治对策初探

随着石油化工企业规模的扩大和进出口油品的需要，海上油品运输量的比例越来越大，油码头的规模也在不断扩大。近年来油码头在储运过程中也经常发生一些环境污染事故。根据油码头储运过程中发生的环境问题，通过对油码头生产工艺流程、设备及储运过程中主要污染物产生来源的分析基础上，提出了油码头烃类大气污染物、含油污水、噪声等的污染防治措施。     

Comparative Toxicities of Polar and Non-Polar Organic Fractions From Sediments Affected By the Exxon Valdez Oil Spill in Prince William Sound, Alaska

Standardized tests were applied to aromatic and polar fractions of sediment extracts to determine whether polar constituents or oxidative degradation products contributed significantly to the toxicity of sediments oiled by the Exxon Valdez spill. Intertidal sediment and pore-water samples were collected in September 1990 from two heavily oiled sites and an unoiled site in Prince William Sound (PWS). Methylene chloride extracts from these samples were fractionated by liquid chromatography into aliphatic, aromatic and polar fractions, and the aromatic and polar fractions were tested for toxicity using the Microtox^R test, bivalve larval mortality and development (Mytilus); several measures of genotoxicity in Mytilus, including SOS Chromotest^R, anaphase aberrations and sister chromatid exchange; and survival, anaphase aberrations and teratogenicity in coho salmon (Onchorhynchus kisutch). Microtox^R and SOS Chromotest^R protocols were applied in a screening mode to all samples, whereas other tests were applied only to selected fractions from two sites. Samples from Bay of Isles (oiled) were consistently more toxic (usually only 2 to 5-fold) than the Mooselips Bay (unoiled) samples, which gave very low responses in all tests. for both sites, however, responses to polar and aromatic fractions were about the same in most tests, suggesting that while the overall toxicity of the oil was low in these samples, at least part of that toxicity was derived from polar constituents. Compared to the parent hydrocarbons, polar oxidation products partition preferentially into pore-water and are more rapidly diluted and dispersed in the water column. These results suggest that polar oxidation products of petroleum hydrocarbons pose little risk to marine organisms, except possibly for infauna continuously exposed to pore-water in heavily oiled sediments. Independent surveys showed that sediment toxicity in PWS declined during 1989-1991 to near background levels, in accord with previous understanding of oil weathering and toxicity.     

Hydroxyurea explosion: a thermoanalytical and calorimetric study

An accident occurred during a production process of hydroxyurea. Several thermoanalytical techniques were used in order to understand the reason for the accident, even utilising a simulation program. Thermogravimetric analysis and Fourier transform infra-red spectroscopy were performed to identify the decomposition products according to European Directive 96/82/EC, the so-called Seveso II.     

POLLUTION THREATS IN THE MEDITERRANEAN SEA: AN OVERVIEW

This overview summarises the present knowledge on major sources of pollution, which are of concern for the Mediterranean Sea. Eutrophication, red tides, organic loads, hydrocarbon spills, heavy metal contamination and their biological effects are described on the light of the ecological characteristics of the Mediterranean. In particular special attention is paid to the "new pollution" processes; i.e. , the introduction of novel substances with biological activity that might have synergetic effects with "classical pollutants". Different compartments and marine ecosystems are considered and compared. The degree of anthropogenic impact and its apparent trends are discussed. Possible monitoring plans and remedial actions for a sustainable management of coastal zones subjected to increasing pollution are also suggested.     

双降解地膜生物降解及降解产物的研究

本文主要介绍了双降解地膜生物降解性。包括生物接种，田间复膜土壤菌群分析等各种生物检测方法。并对复膜土壤中降解产物的化学检测方法也简要做了介绍。     

Environmental occurrence of Q1, a C9H3C17N2 compound,that has been identified as a natural bioaccumulative organochlorine

Environmental appearance of Q1, a natural heptachloro compound with the molecular formula C₉H₃Cl₇N₂, was studied in samples from different sites all over the world. Q1 was expected to have a bipyrrole backbone, similar to other compounds ascribed to natural sources. A method for isolation of Q1 was developed by combination of adsorption chromatography on silica and normal phase HPLC with an amino phase. UV-detection of Q1 supports the aromatic character of the compound.

The high levels detected in samples of marine mammals and birds suggested that Q1 is both a persistent and a bioaccumulative contaminant. This was underscored by calculated log K_OW in the range of other lipophilic organohalogens. In accordance with earlier studies, highest Q1 concentrations were found in the Southern Hemisphere, but with a highly selective GC/ECNI-MS-SIM method, detection of Q1 was also achieved in many samples from the Northern Hemisphere. In addition to marine mammals and birds, Q1 was also detected in fish from the Mediterranean Sea and the Antarctic. Traces were also detected in SRM 1588 certified cod liver oil, but Q1 was not detected in fish from Hong Kong and Lake Baikal.     

从LCA角度评价塑料用品与木制用品对环境的影响

通过对一次性塑料与纸制用品（木制品）的评价研究的基础上，对木制品与塑料制品从生命周期评价（LCA）的角度上对问题作进一步的探讨和研究，得出结论为塑料制品为环保型产品。