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471.
Factors affecting nitrate distribution in shallow groundwater under a beef farm in South Eastern Ireland 总被引:2,自引:0,他引:2
O. Fenton K.G. Richards L. Kirwan M.I. Khalil M.G. Healy 《Journal of environmental management》2009,90(10):3135-3146
Groundwater contamination was characterised using a methodology which combines shallow groundwater geochemistry data from 17 piezometers over a 2 yr period in a statistical framework and hydrogeological techniques. Nitrate–N (NO3-N) contaminant mass flux was calculated across three control planes (rows of piezometers) in six isolated plots. Results showed natural attenuation occurs on site although the method does not directly differentiate between dilution and denitrification. It was further investigated whether NO3-N concentration in shallow groundwater (<5 m below ground level) generated from an agricultural point source on a 4.2 ha site on a beef farm in SE Ireland could be predicted from saturated hydraulic conductivity (Ksat) measurements, ground elevation (m Above Ordnance Datum), elevation of groundwater sampling (screen opening interval) (m AOD) and distance from a dirty water point pollution source. Tobit regression, using a background concentration threshold of 2.6 mg NO3-N L−1 showed, when assessed individually in a step wise procedure, Ksat was significantly related to groundwater NO3-N concentration. Distance of the point dirty water pollution source becomes significant when included with Ksat in the model. The model relationships show areas with higher Ksat values have less time for denitrification to occur, whereas lower Ksat values allow denitrification to occur. Areas with higher permeability transport greater NO3-N fluxes to ground and surface waters. When the distribution of Cl− was examined by the model, Ksat and ground elevation had the most explanatory power but Ksat was not significant pointing to dilution having an effect. Areas with low NO3 concentration and unaffected Cl− concentration points to denitrification, low NO3 concentration and low Cl− chloride concentration points to dilution and combining these findings allows areas of denitrification and dilution to be inferred. The effect of denitrification is further supported as mean groundwater NO3-N was significantly (P < 0.05) related to groundwater N2/Ar ratio, redox potential (Eh), dissolved O2 and N2 and was close to being significant with N2O (P = 0.08). Calculating contaminant mass flux across more than one control plane is a useful tool to monitor natural attenuation. This tool allows the identification of hot spot areas where intervention other than natural attenuation may be needed to protect receptors. 相似文献
472.
Occupational exposure to radon and natural gamma radiation in the La Carolina, a former gold mine in San Luis Province, Argentina 总被引:1,自引:0,他引:1
R.M. Anjos N. Umisedo L. Estellita E.M. Yoshimura A.M.A. Santos 《Journal of environmental radioactivity》2010,101(2):153-362
Radon and gamma radiation level measurements were carried out inside the La Carolina mine, one of the oldest gold mining camps of southern South America, which is open for touristic visits nowadays. CR-39 track-etch detectors and thermoluminescent dosimeters of natural CaF2 and LiF TLD-100 were exposed at 14 points along the mine tunnels in order to estimate the mean 222Rn concentration and the ambient dose equivalent during the summer season (November 2008 to February 2009). The values for the 222Rn concentration at each monitoring site ranged from 1.8 ± 0.1 kBq m−3 to 6.0 ± 0.5 kBq m−3, with a mean value of 4.8 kBq m−3, indicating that these measurements exceed in about three times the upper action level recommended by ICRP for workplaces. The correlations between radon and gamma radiation levels inside the mine were also investigated. Effective doses due to 222Rn and gamma rays inside the mine were determined, resulting in negligible values to tourists. Considering the effective dose to the mine tourist guides, values exceeding 20 mSv of internal contribution to the effective doses can be reached, depending on the number of working hours inside the mine. 相似文献
473.
Effect of pre-ozonation on optimized coagulation of a typical North-China source water 总被引:3,自引:0,他引:3
Although ozone is widely used as a pre-oxidant before coagulation in water treatment, the effect of pre-ozonation on optimized coagulation for removal of particle and natural organic matter (NOM) is still not fully understood. In this paper, pilot-scale investigation was conducted to examine the impact of pre-ozonation on coagulation for particle and NOM removal. Changes in the particle and NOM distributions were characterized by various methods, including laser light granularity system, particle counter, ultrafiltration, and resin absorbent fractionation. A novel composite flocculant–HPAC was compared with the traditional ferric chloride coagulant in terms of coagulation efficiency under the influence of pre-ozonation. Typical micro-polluted North China surface water was used for pilot coagulation tests. The results show that the effect of pre-ozonation on coagulation is associated with the dosage of ozone, coagulant type, and water contamination characteristics. For FeCl3, pre-ozonation acts as a coagulation aid at low dosage (1.0 mg L−1 O3) for turbidity and UV254 removal; while at higher dosage (2.0 mg L−1 O3), pre-ozonation is detrimental to UV254 removal although it is still beneficial for turbidity removal. In the case of composite flocculant–HPAC, pre-ozonation demonstrates negligible influence on both turbidity and UV254 removal. Ozone can simultaneously aggregate fine particles and break down large ones, making them more mineralized and easier to remove. NOM with intermediate molecular weight and hydrophobic neutral property increases at lower ozone dosage, favoring removal by coagulation. At higher ozone dosages, NOM becomes more hydrophilic and its molecular weight becomes smaller, decreasing NOM removal. 相似文献
474.
Over a period of several decades multiple leaks of large volumes from storage facilities located near Hnevice (Czech Republic) have caused the underlying Quaternary aquifer to be severely contaminated with nonaqueous phase liquid (NAPL) petroleum hydrocarbons. Beginning in the late 1980's the NAPL plume started to shrink as a consequence of NAPL dissolution exceeding replenishment and due to active remediation. The subsurface was classified geochemically into four different zones, (i) a contaminant-free zone never occupied by NAPL or dissolved contaminants, (ii) a re-oxidation zone formerly occupied by NAPL, (iii) a zone currently occupied by NAPL, and (iv) a lower fringe zone between the overlying NAPL and the deeper underlying contaminant-free zone. The study investigated the spatial and temporal variability of the redox zonation at the Hnevice site and quantified the influence of iron-cycling on the overall electron balance. As a first step inverse geochemical modelling was carried out to identify possible reaction models and mass transfer processes. In a subsequent step, two-dimensional (forward) multi-component reactive transport modelling was performed to evaluate and quantify the major processes that control the geochemical evolution at the site. The study explains the observed enrichment of the lower fringe zone with ferrihydrite as a result of the re-oxidation of ferrous iron. It suggests that once the NAPL zone started to shrink the dissolution of previously formed siderite and FeS by oxygen and nitrate consumed a significant part of the oxidation capacity for a considerable time period and therefore limited the penetration of electron acceptors into the NAPL contaminated zone. 相似文献
475.
During in situ chemical oxidation with permanganate, natural organic matter and other reduced species in the subsurface compete with the target compounds for the available oxidant and can exert a significant natural oxidant demand. This competition between target and nontarget compounds can have a significant impact on the permeation, dispersal, and persistence of permanganate in the subsurface. The kinetics of natural oxidant demand by permanganate was investigated using a composite sample made up of aquifer material collected from three different sites. The study found that although the depletion of organic carbon increased with increased permanganate dosage and increased reaction period, the mass ratio of MnO(4)(-):OC (wt/wt) was relatively constant over time (11.4+/-0.9). The reaction order and rate with respect to permanganate were found to decrease with time suggesting a continuum of reactions with the slower reactions becoming more controlling with time. However, the data also suggests that this continuum of reactions can be simplified into short- and long-term kinetic expressions representing fast and slow reactions. An independent first-order kinetic model with separate fast and slow reaction rate constants was used to successfully describe the complete kinetic expression of natural oxidant demand. The kinetic parameters used in the model are easily determined and can be used to better understand the complex kinetics of natural oxidant demand. 相似文献
476.
Maria Rutkowska Katarzyna Krasowska Aleksandra Heimowska Grażyna Adamus Michał Sobota Marta Musioł Henryk Janeczek Wanda Sikorska Andrej Krzan Ema Žagar Marek Kowalczuk 《Journal of Polymers and the Environment》2008,16(3):183-191
Degradation of atactic poly[(R,S)-3-hydroxybutyrate] (a-PHB) binary blends with natural poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV, 12 mol% of 3HV units), has been investigated and compared with plain PHBV in the compost containing
activated sludge and under marine exposure conditions in the dynamic water of the Baltic Sea. Characteristic parameters of
compost and the Baltic Sea water were monitored during the incubation period (6 weeks) and their influence on the degree of
biodegradation is discussed. After specified degradation times of the experiments the weight loss of the samples, surface
changes, changes in molecular weight and polydispersity as well as changes of the composition and thermo-mechanical properties
of the blends have been evaluated. Macroscopic observations of the samples were accompanied by investigations using optical
microscopy, size-exclusion chromatography (SEC), nuclear magnetic resonance (NMR), differential scanning calorimetry (DSC)
and tensile testing. The degree of degradation of blends of a-PHB with PHBV depends on the blend composition and environmental
conditions. In both environments studied the weight loss of plain PHBV was more significant than changes the molecular weight.
In both environments only enzymatic degradation of the blends, which proceeds via surface erosion mechanisms, was observed
during the incubation period. 相似文献
477.
Engaging with the natural environment: The role of affective connection and identity 总被引:1,自引:0,他引:1
Research has shown pro-environmental behaviour to be positively associated with the strength of emotional connection towards the natural environment. The present study (N=199) investigated the predictive utility of an extended model of the theory of planned behaviour (TPB) [ Ajzen, I. (1991). The theory of planned behaviour. Organizational Behaviour and Human Decision Processes, 50, 179–211] for people's intentions to engage with the natural environment. It was hypothesised that both affective connection and identification with the natural environment would contribute significantly to the prediction of people's intentions. A secondary hypothesis was that participants who had grown up in rural areas would report more positive orientations towards engaging with the natural environment than would urban participants. The research found that affective connection was a significant independent predictor of intentions to engage with the natural environment. Environmental identity was only a significant predictor in the absence of affective connection in the regression model. As predicted, rural and urban participants differed significantly along the measured variables. 相似文献
478.
Aragón-Correa JA Hurtado-Torres N Sharma S García-Morales VJ 《Journal of environmental management》2008,86(1):88-103
In spite of the widespread recognition of the important roles that small and medium sized enterprises (SMEs) play in most economies, limited research has focused on their impacts on the natural environment and the strategies such enterprises adopt to reduce these impacts. It is usually assumed that SMEs lack the resources to implement proactive environmental strategies that go beyond minimum regulatory compliance. In this study of 108 SMEs in the automotive repair sector in Southern Spain, we found that SMEs undertake a range of environmental strategies from reactive regulatory compliance to proactive pollution prevention and environmental leadership. These strategies are associated with three organizational capabilities: shared vision, stakeholder management, and strategic proactivity, hypothesized based on the unique strategic characteristics of SMEs--shorter lines of communication and closer interaction within the SMEs, the presence of a founder's vision, flexibility in managing external relationships, and an entrepreneurial orientation. We also found that firms with the most proactive practices exhibited a significantly positive financial performance. 相似文献
479.
In this work, the potential for natural attenuation (NA) of Cr(VI) is evaluated for sub-wetland ground water at a chromium-contaminated site in Connecticut, incorporating the experimental findings of previous work at the site. Experimental data is assessed through long-term attenuation capacity calculations and modeling, which incorporates statistical uncertainty of parametric values. The NA evaluation yielded the following results: (1) Significant increases in Cr(VI) concentration and extremely long chromium source dissolution timeframes are required to exceed the attenuation capacity of the sub-wetland region soils studied in this work; and (2) Based on the 1-D transport modeling and incorporating input parameter uncertainty, there is an approximately 92% and 98% probability that the applicable regulatory criteria will not be exceeded at Point C, near a river which serves as the receptor, for the cases of (1) sorption of Cr(VI) only and (2) pseudo first order disappearance of Cr(VI) from the aqueous phase only, respectively. 相似文献
480.
In order to assess the potential risk of pipeline underwater leakage, a self-designed experimental setup is carried out to study the gas release rate and dispersion behavior in different release scenarios. A transparent organic glass tank with dimension of 1 m × 0.5 m × 0.5 m (height × width × length) was placed in a wind tunnel. The release pipeline made by stainless-steel with diameter of 25 mm were used to simulate for variation release depth. The different size and shape of leakage orifices in 1 mm, 3 mm, 5 mm in round and 3.5 × 2 mm, 7 × 1 mm in rectangle were designed for comparison. The medium of methane gas was released from the controllable cylinder. The variation parameters of flow rate and pressure were measured by a flow meter and pressure gauge respectively. A high speed camera was employed to recorded the phenomenology of dispersion characteristics and breakup process for a wide range of orifice size in the time-resolved images. The dynamic plume diameter on water surface was measured by a Vernier caliper placed above the water tank. The considered factors including orifice size, leakage pressure and water depth effect on gas flow rate and dispersion behavior was quantitative investigated. The fitting correlation between the gas flow rate and variation parameters can provide fundamental information for evaluation the hazard consequences of gas release in engineering application. 相似文献