Assay of some volatile compounds in human exhalation

ＡｓａｙｏｆｓｏｍｅｖｏｌａｔｉｌｅｃｏｍｐｏｕｎｄｓｉｎｈｕｍａｎｅｘｈａｌａｔｉｏｎＱｉｎＴａｏ，ＸｕＸｉａｏｂａｉＲｅｓｅａｒｃｈＣｅｎｔｅｒｆｏｒＥｃｏＥｎｖｉｒｏｎｍｅｎｔａｌＳｃｉｅｎｃｅｓ，ＣｈｉｎｅｓｅＡｃａｄｅｍｙｏｆＳｃｉｅ...     

Quantitative structure activity relationships for carp kidney ATPase endpoint

ＩｎｔｒｏｄｕｃｔｉｏｎＭｏｓｔｏｆｎｉｔｒｏａｒｏｍａｔｉｃｓａｒｅｉｍｐｏｒｔａｎｔｅｎｖｉｒｏｎｍｅｎｔａｌｐｏｌｌｕｔａｎｔｓ.ＴｈｅｃａｒｐｉｓｔｈｅｍａｊｏｒｅｃｏｎｏｍｉｃｆｉｓｈｉｎＣｈｉｎａａｎｄｉｓｏｎｅｏｆｔｈｅｆｉｖｅｓｔａｎ?..     

水环境中痕量有机有害物质的监测

论述了水中有机有害物质的监测,实质上是一项复杂系统的痕量分析课题。重点评述了痕量富集、色谱分离与监测、综合分析的主要进展。     

上海市大气PM2.5中溶剂可抽提有机物的特征研究

利用溶剂抽提、分离、毛细管气相色谱-质谱联用技术对2000年10月至2001年8月上海市5个不同功能区采集的大气PM_(2.5)样品中的溶剂可抽提有机物进行了检测,共检测出正构烷烃、单环芳烃、多环芳烃、有机酸、有机醇、有机酯等各类溶剂可抽提有机化合物267种。检出的82种多环芳烃中有15种属于美国EPA优先控制污染物名单。比较了不同季节、不同区域PM_(2.5)样品中正构烷烃、多环芳烃等化合物分布特征的差异。检出的喹啉类含氮杂环类化合物以及有机酸等污染物表现出一定的机动车排放特征。     

生物法净化废气中低浓度挥发性有机物的过程机理研究

 针对生物法净化低浓度挥发性有机废气的过程机理研究表明，生物膜填料塔净化低浓度甲苯气体是一个以气膜控制为主的传质过程，其中甲苯的生化降解属于瞬时快速化学反应，即甲苯的生化降解反应速率远远超过甲苯在液膜中的扩散速率，甲苯的生化降解在气液相界面处即可发生，其宏观表现即为甲苯气体直接吸附在润湿的生物膜上后迅速被微生物生化降解。因此，可以从气体吸附理论的新角度去解释生物法净化废气中低浓度挥发性有机物的动力学过程。对于低浓度挥发性有机废气的生物法净化装置的设计与操作而言，凡能改善传质条件、减少气膜阻力的措施均能强化这一生物吸收净化过程。     

一种新的拓扑指数及其在有机化合物结构/性质相关性研究中的应用

以距离矩阵为基础，提出一种表征化合物分子结构的拓扑指数，并将其用于预报饱和链烃类、醇类和含氮芳香类化合物的性质和活性，获得了满意的结果。     

主次波长新分光光度法测定天然水硝酸盐

在硫酸介质中,邻苯氨基苯甲酸与硝酸盐(NO_3~-)生成紫红色络合物.本文依据悬浮颗粒对光的吸收性质研究利用该灵敏反应测定 NO_3~—N 新光度法——(?)次双波长法,通过对样品分析,可提高分析灵敏度和精密度,回收良好,且操作简单快速,计算曲线稳定,适合于测定地下水,湖水等天然水体 NO_3~-—N.     

毛细管柱气相色谱质谱法分析优先监测物的质量控制研究——Ⅰ.半挥发性有机物

报道了毛细管柱气相色谱质谱联用(GC-MS)方法分析半挥发性有机物的质量控制研究结果.对分析的全过程提出了质量控制标准.应用同位素标记内标物(IS),替代掺样物(SS)和基质掺样/重复基质掺样(MS/MSD)的回收率来判断样品处理与分析结果的可靠性.根据77种目标化合物,特别是标定检验化合物(CCC)和系统检验化合物(SPCC)的响应系数范围,确定GC-MS系统的工作状态和最终结果的正确性.给出了满足质量控制标准的12个土壤样品的结果.     

沉淀混凝法处理含硫气田水

本文介绍用沉淀混凝法处理含硫气田水的室内试验及现场试验情况。用三氯化铁、聚合氯化铝及ＳＷ－Ⅰ处理含硫气田水，能有效地去除硫化物，而且处理后水不会因三氯化铁过量而发黄。该方法的特点是工艺简单，处理效果显著，能很好地解决含硫污水的污染问题。     

Comparison of UV-based advanced oxidation processes for the removal of different fractions of NOM from drinking water

This study examined the effectiveness for degradation of hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions of natural organic matter (NOM) during UV/H₂O₂, UV/TiO₂ and UV/K₂S₂O₈ (UV/PS) advanced oxidation processes (AOPs). The changing characteristics of NOM were evaluated by dissolved organic carbon (DOC), the specific UV absorbance (SUVA), trihalomethanes formation potential (THMFP), organic halogen adsorbable on activated carbon formation potential (AOXFP) and parallel factor analysis of excitation–emission matrices (PARAFAC-EEMs). In the three UV-based AOPs, HPI fraction with low molecular weight and aromaticity was more likely to degradate than HPO and TPI, and the removal efficiency of SUVA for HPO was much higher than TPI and HPI fraction. In terms of the specific THMFP of HPO, TPI and HPI, a reduction was achieved in the UV/H₂O₂ process, and the higest removal rate even reached to 83%. UV/TiO₂ and UV/PS processes can only decrease the specific THMFP of HPI. The specific AOXFP of HPO, TPI and HPI fractions were all able to be degraded by the three UV-based AOPs, and HPO content is more susceptible to decompose than TPI and HPI content. UV/H₂O₂ was found to be the most effective treatment for the removal of THMFP and AOXFP under given conditions. C1 (microbial or marine derived humic-like substances), C2 (terrestrially derived humic-like substances) and C3 (tryptophan-like proteins) fluorescent components of HPO fraction were fairly labile across the UV-based AOPs treatment. C3 of each fraction of NOM was the most resistant to degrade upon the UV-based AOPs. Results from this study may provide the prediction about the consequence of UV-based AOPs for the degradation of different fractions of NOM with varied characteristics.