全文获取类型
收费全文 | 147篇 |
免费 | 4篇 |
国内免费 | 31篇 |
专业分类
安全科学 | 1篇 |
废物处理 | 2篇 |
环保管理 | 18篇 |
综合类 | 65篇 |
基础理论 | 26篇 |
污染及防治 | 53篇 |
评价与监测 | 16篇 |
社会与环境 | 1篇 |
出版年
2023年 | 5篇 |
2022年 | 7篇 |
2021年 | 7篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 8篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2015年 | 4篇 |
2014年 | 2篇 |
2013年 | 6篇 |
2012年 | 9篇 |
2011年 | 10篇 |
2010年 | 9篇 |
2009年 | 10篇 |
2008年 | 19篇 |
2007年 | 14篇 |
2006年 | 13篇 |
2005年 | 8篇 |
2004年 | 2篇 |
2003年 | 4篇 |
2002年 | 4篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1996年 | 2篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
排序方式: 共有182条查询结果,搜索用时 15 毫秒
91.
Schaefer CE Fuller ME Condee CW Lowey JM Hatzinger PB 《Journal of contaminant hydrology》2007,89(3-4):231-250
Biological and abiotic approaches for treating co-mingled perchlorate, nitrate, and nitramine explosives in groundwater were compared in microcosm and column studies. In microcosms, microscale zero-valent iron (mZVI), nanoscale zero-valent iron (nZVI), and nickel catalyzed the reduction of RDX and HMX from initial concentrations of 9 and 1 mg/L, respectively, to below detection (0.02 mg/L), within 2 h. The mZVI and nZVI also degraded nitrate (3 mg/L) to below 0.4 mg/L, but none of the metal catalysts were observed to appreciably reduce perchlorate ( approximately 5 mg/L) in microcosms. Perchlorate losses were observed after approximately 2 months in columns of aquifer solids treated with mZVI, but this decline appears to be the result of biodegradation rather than abiotic reduction. An emulsified vegetable oil substrate was observed to effectively promote the biological reduction of nitrate, RDX and perchlorate in microcosms, and all four target contaminants in the flow-through columns. Nitrate and perchlorate were biodegraded most rapidly, followed by RDX and then HMX, although the rates of biological reduction for the nitramine explosives were appreciably slower than observed for mZVI or nickel. A model was developed to compare contaminant degradation mechanisms and rates between the biotic and abiotic treatments. 相似文献
92.
Monitoring, assessment and modelling using water quality data in the Saale River Basin, Germany 总被引:1,自引:0,他引:1
Bongartz K Steele TD Baborowski M Lindenschmidt KE 《Environmental monitoring and assessment》2007,135(1-3):227-240
The European Water Framework Directive (WFD) is the overall driver for this environmental study and currently requires the
identification of patterns and sources of pollution (monitoring) to support objective ecological sound decision making and
specific measures to enhance river water quality (modelling). The purpose of this paper is to demonstrate in a case study
the interrelationship between (1) hydrologic and water quality monitoring data for river basin characterization and (2) modelling
applications to assess resources management alternatives. The study deals with monitoring assessment and modelling of river
water quality data of the main stem Saale River and its principal tributaries. For a period of 6 years the data, which was
sampled by Environmental Agencies of the German states of Thuringia, Saxony and Saxony-Anhalt, was investigated to assess
sources and indicators of pollution. In addition to the assessment a modelling exercise of the routing of different pollutants
was carried out in the lower part of the test basin. The modelling is a tool to facilitate the evaluation of alternative measures
to reduce contaminant loadings and improve ecological status of a water body as required by WFD. The transport of suspended
solids, salts and heavy metals was modelled along a selected Saale reach under strong anthropogenic influence in terms of
contaminants and river morphology between the city of Halle and the confluence with the Elbe River. The simulations were carried
out with the model WASP5 which is a dynamic flood-routing and water quality model package developed by the US Environmental
Protection Agency. 相似文献
93.
Pujari PR Nanoti M Nitnaware VC Khare LA Thacker NP Kelkar PS 《Environmental monitoring and assessment》2007,134(1-3):271-278
On-site sanitation is increasingly adopted in urban cities in India. The adoption of On-site sanitation system puts the groundwater
resources in the vicinity of the system at a greater risk. Microbial contaminants as well as chemical contaminants like Chloride
and Nitrate are generated from human waste. These contaminants travel through the medium and ultimately get in contact with
the groundwater. Hence, the groundwater sources are vulnerable to nitrate contamination near the On-site sanitation systems.
The present study indicates significant Nitrate and Chloride contamination in samples collected close to On-site sanitation
systems. The recommended limit set by the Bureau of Indian standards (BIS) limit of 45 mg/l for Nitrate concentration is also
exceeded in few samples. The study indicates that Bacterial as well as Nitrate contamination is more in Monsoon as compared
to Summer. 相似文献
94.
Identification and quantification of a novel nitrate-reducing community in sediments of Suquía River basin along a nitrate gradient 总被引:1,自引:0,他引:1
Luciana Reyna 《Environmental pollution (Barking, Essex : 1987)》2010,158(5):1608-1614
We evaluated the molecular diversity of narG gene from Suquía River sediments to assess the impact of the nitrate concentration and water quality on the composition and structure of the nitrate-reducing bacterial community. To this aim, a library of one of the six monitoring stations corresponding to the highest nitrate concentration was constructed and 118 narG clones were screened. Nucleotide sequences were associated to narG gene from alpha-, beta-, delta-, gammaproteobacteria and Thermus thermophilus. Remarkably, 18% of clones contained narG genes with less than 69% similarity to narG sequences available in databases. Thus, indicating the presence of nitrate-reducing bacteria with novel narG genes, which were quantified by real-time PCR. Results show a variable number of narG copies, ranging from less than 1.0 × 102 to 5.0 × 104 copies per ng of DNA, which were associated with a decreased water quality index monitored along the basin at different times. 相似文献
95.
J.C. Rozemeijer Y. van der Velde F.C. van Geer M.F.P. Bierkens H.P. Broers 《Environmental pollution (Barking, Essex : 1987)》2010,158(12):3571-3579
Enhanced knowledge of water and solute pathways in catchments would improve the understanding of dynamics in water quality and would support the selection of appropriate water pollution mitigation options. For this study, we physically separated tile drain effluent and groundwater discharge from an agricultural field before it entered a 43.5-m ditch transect. Through continuous discharge measurements and weekly water quality sampling, we directly quantified the flow route contributions to surface water discharge and solute loading. Our multi-scale experimental approach allowed us to relate these measurements to field-scale NO3 concentration patterns in shallow groundwater and to continuous NO3 records at the catchment outlet. Our results show that the tile drains contributed 90-92% of the annual NO3 and heavy metal loads. Considering their crucial role in water and solute transport, enhanced monitoring and modeling of tile drainage are important for adequate water quality management. 相似文献
96.
Spatiotemporal variations of nitrate sources and dynamics in a typical agricultural riverine system under monsoon climate 总被引:1,自引:0,他引:1
Hao Jiang Wenjing Liu Jiangyi Zhang Li Zhou Xiaode Zhou Ke Pan Tong Zhao Yuchen Wang Zhifang Xu 《环境科学学报(英文版)》2020,32(7):98-108
Nitrogen pollution is a serious environmental issue in the Danjiangkou Reservoir region(DRR),the water source of the South-to-North Water Diversion Project of China.In this research,seasonal surveys and a bi-weekly time series survey were conducted in the Qihe River Basin,one of the most densely populated agricultural basins in the DRR.Hydrochemical compositions (NO3Cl),dual isotopes (δD-H2O,δ18O-H2O,δ15N-NO3-,and δ 相似文献
97.
98.
99.
Vulnerability and risk evaluation of agricultural nitrogen pollution for Hungary's main aquifer using DRASTIC and GLEAMS models 总被引:4,自引:1,他引:4
Leone A Ripa MN Uricchio V Deák J Vargay Z 《Journal of environmental management》2009,90(10):2969-2978
In recent years, the significant improvement in point source depuration technologies has highlighted problems regarding, in particular, phosphorus and nitrogen pollution of surface and groundwater caused by agricultural non-point (diffuse) sources (NPS). Therefore, there is an urgent need to determine the relationship between agriculture and chemical and ecological water quality.This is a worldwide problem, but it is particularly relevant in countries, such as Hungary, that have recently become members of the European Community. The Italian Foreign Ministry has financed the PECO (Eastern Europe Countries Project) projects, amongst which is the project that led to the present paper, aimed at agricultural sustainability in Hungary, from the point of view of NPS. Specifically, the aim of the present work has been to study nitrates in Hungary's main aquifer. This study compares a model showing aquifer intrinsic vulnerability to pollution (using the DRASTIC parameter method; Aller et al. [Aller, L., Truman, B., Leher, J.H., Petty, R.J., 1986. DRASTIC: A Standardized System for Evaluating Ground Water Pollution Potential Using Hydrogeologic Settings. US NTIS, Springfield, VA.]) with a field-scale model (GLEAMS; Knisel [Knisel, W.G. (Ed.), 1993. GLEAMS—Groudwater Leaching Effects of Agricultural Management Systems, Version 3.10. University of Georgia, Coastal Plain Experimental Station, Tifton, GA.]) developed to evaluate the effects of agricultural management systems within and through the plant root zone. Specifically, GLEAMS calculates nitrate nitrogen lost by runoff, sediment and leachate.Groundwater monitoring probes were constructed for the project to measure: (i) nitrate content in monitored wells; (ii) tritium (3H) hydrogen radioisotope, as a tool to estimate the recharge conditions of the shallow groundwater; (iii) nitrogen isotope ratio δ15N, since nitrogen of organic and inorganic origin can easily be distinguished.The results obtained are satisfactory, above all regarding the DRASTIC evaluation method, which is shown to satisfactorily explain both low and high aquifer vulnerability, and furthermore proves to be a good tool for zoning hydrogeological regions in terms of natural system susceptibility to pollution. The GLEAMS model, however, proves not to be immediately usable for predictions, above all due to the difficulty in finding sufficient data for the input parameters. It remains a good tool, but only after an accurate validation, for decision support systems, in the specific case to integrate intrinsic vulnerability, from DRASTIC (or similar methods), with land use nitrate loads from GLEAMS, or similar methods.The PECO project has proved a positive experience to highlight the fundamental points of a decision support system, aimed to mitigate the nitrate risk for groundwater coming from Hungarian agricultural areas. 相似文献
100.
Nitrate (NO3−) has been the dominant ion of secondary inorganic aerosols (SIAs) in PM2.5 in North China. Tracking the formation mechanisms and sources of particulate nitrate are vital to mitigate air pollution. In this study, PM2.5 samples in winter (January 2020) and in summer (June 2020) were collected in Jiaozuo, China, and water-soluble ions and (δ15N, δ18O)-NO3− were analyzed. The results showed that the increase of NO3− concentrations was the most remarkable with increasing PM2.5 pollution level. δ18O-NO3− values for winter samples (82.7‰ to 103.9‰) were close to calculated δ18O-HNO3 (103‰ ± 0.8‰) values by N2O5 pathway, while δ18O-NO3− values (67.8‰ to 85.7‰) for summer samples were close to calculated δ18O-HNO3 values (61‰ ± 0.8‰) by OH oxidation pathway, suggesting that PM2.5 nitrate is largely from N2O5 pathway in winter, while is largely from OH pathway in summer. Averaged fractional contributions of PN2O5+H2O were 70% and 39% in winter and summer sampling periods, respectively, those of POH were 30% and 61%, respectively. Higher δ15N-NO3− values for winter samples (3.0‰ to 14.4‰) than those for summer samples (-3.7‰ to 8.6‰) might be due to more contributions from coal combustion in winter. Coal combustion (31% ± 9%, 25% ± 9% in winter and summer, respectively) and biomass burning (30% ± 12%, 36% ± 12% in winter and summer, respectively) were the main sources using Bayesian mixing model. These results provided clear evidence of particulate nitrate formation and sources under different PM2.5 levels, and aided in reducing atmospheric nitrate in urban environments. 相似文献