H2O超声过程中H2O2生成动力学

采用50kHz超声清洗槽式声化学反应器,以纯水为空化液体,研究了超声过程中H2O2生成动力学．分别探讨了空化气体种类(Ar,O2)及组成与流量、空化液体体积与反应器形状对H2O2生成速率及产率的影响．结果表明,超声过程中H2O2的生成可采用零级反应动力学方程来进行描述．在此频率下和考察范围内,采用Ar作为空化气体比O2更有利于H2O2的生成．当混合气体组成为Ar:O2=70：30(V/V)时,H2O2的生成速率最快．随着空化气体流量的增加,H2O2产率增加,随后降低．增加空化液体的体积,H2O2的生成速率降低．与锥形瓶相比,圆底烧瓶中H2O2的产率明显降低．     

Possible Input of Nitrogen of Visitors’ Origin on a Protected Peatland

The Ozegahara peatland, in the Nikko-Oze National Park in Japan, is ecologically significant because of its oligotrophic environment; it is one of the most strictly preserved areas in the country. The isotope ratio of nitrogen (¹⁵N/¹⁴N) and carbon (¹³C/¹²C) and C/N ratio of peat moss (Sphagnum spp.) and sundew (Drosera rotundifolia) in the peatland were analyzed. The correlation of the isotope ratio with some parameters (sundew population density, number of trapped insects, water level, bog myrtle coverage, and visitor density) was investigated. The nitrogen isotope ratio of sundew showed the most significant covariation with visitor density, where sundew from lunch areas or along busy walkways showed a higher nitrogen isotope ratio. The nitrogen isotope ratio of peat moss covaried, not only with route traffic frequency but also with water level, bog myrtle coverage, and number of trapped insects by sundew, indicating that factors other than the visitor level influence the local nitrogen cycle. This study suggests that the nitrogen imported into the peatland by visitors is a principal factor to be monitored for the maintenance of the natural environment.     

Fused CFD-interpolation model for real-time prediction of hazardous gas dispersion in emergency rescue

Accidental releases of hazardous gases in chemical industries can pose great threats to public security. The computational fluid dynamics (CFD) model is commonly applied to predict gas dispersion in complex structured areas. It can provide good accuracy but it is too time-consuming to be used in emergency response. To reduce computation time while keep acceptable accuracy, this paper proposes several fused CFD-interpolation models which combine CFD model with different interpolation methods. Spline, linear and nearest interpolation methods are used. A CFD simulations database is created ahead of time which can be quickly recalled for emergency usage and unknown situations can be predicted instantly by interpolation methods instead of time-consuming CFD model. Fused models were applied to a case study involving a hypothetical propane release with varying conditions and validated against CFD model. The validation shows that prediction accuracy of these fusion models is acceptable. Among these models, CFD-Spline interpolation model performs best. It is faster than CFD model by a factor of 75 and is potentially a good method to be applied to real-time prediction.     

Dynamics of explosion venting in a compartment with methane-air mixtures

A series of experiments on explosion venting of methane-air mixtures are performed to scrutinize the pressure evolution as well as the flame dynamics and morphology at various vent conditions. Specifically, a premixed flame is ignited at the center of a polycarbonate cylindrical compartment, with three various vent areas considered (with negligible vent relief pressure). As expected, the highest maximum pressure is observed in the case of the smallest vent area. For all three cases, the pressure evolution experiences two major peaks, associated with the instants (i) when the maximum flame front surface area in the chamber is reached and (ii) when an external explosion occurs due to venting of unburned gases, respectively. For the fuel-rich mixtures, a flashback is observed subsequent to the external explosion, constituting the key outcome of the present work. The flame tip velocities show two general trends, namely, exponential acceleration towards the vent, while a flame propagates towards the blocked side of the compartment with no acceleration, which is important to know in the fire/explosion safety applications.     

演化博弈视角下小微企业内部安全知识共享研究

为探究小微企业组织内部安全知识共享机制,提高小微企业的安全氛围。本文运用演化博弈理论分析员工群体之间的安全知识共享博弈关系,选取系统动力学软件Vensim构建安全知识共享模型,对不同的影响因素进行了模拟分析。模拟结果表明:员工关系融洽系数、领导的重视程度对演化结果呈正相关关系;安全知识的分享成本则与演化结果呈负相关关系。并为促进安全知识共享提出对策措施。     

连云港埒子口海域潮动力特征及其变化

为研究连云港埒子口海域潮流动力特征及其对周边海岸工程的响应,以及为治理埒子口闸下淤积问题提供参考,建立了基于有限体积法离散二维浅水方程的数值模型。采用实测水文资料对模型率定和验证,应用模型分析埒子口潮流动力特征和建设徐圩港防波堤和灌河口导堤后埒子口海域潮流动力的变化。模拟结果表明,建设工程后潮流动力变化较大,埒子口海域涨急流和落急流方向改变,涨、落潮平均流速均减小,距离工程区域越近,流速变化越大。埒子口海域潮流动力减弱将会加重上游挡潮闸的闸下淤积问题,致使埒子口排水不畅,进而增加沂北地区的洪涝风险,所以,相关部门应及时采取措施,保证埒子口排涝畅通。     

基于行人占据区域的泰森多边形人员密度统计方法

行人动力学的研究一直是火灾下人员疏散研究的重要内容。研究者通过大量观测和可控实验,获得行人的运动行为特征,揭示人员运动规律,但是仍然缺乏足够的定量校准的实验数据。在总结了前人对于实验中全局密度与局部密度统计方法的基础上,基于泰森多边形方法,结合人际关系距离与视野的观念,提出了一种行人占据多边形的速度密度统计方法。通过对平均密度平均速度的比较发现,方法得到的结果比传统统计方法得到的结果波动更小且更接近于连续变化、在密度低时比泰森多边形方法的结果更符合实际情况;而对于个人的速度密度散点图,结果也比泰森多边形方法的结果更为集中,尤其是除去了密度小而速度低的不合理数据点。     

臭氧氧化法连续处理焦化废水生化出水

采用连续通入废水和臭氧的方式,利用臭氧氧化法深度处理焦化废水生化出水(COD为151~183 mg/L、pH约为8),并通过添加羟基自由基抑制剂叔丁醇探究了臭氧氧化的机理。在不调节废水pH、臭氧投加量12.15mg/L、废水流量2 mL/min的最佳条件下,COD去除率达54.5%,出水COD达到GB 16171—2012《炼焦化学工业污染物排放标准》。稳定运行时,降解1 kg COD需投加臭氧741.1 mg。臭氧氧化过程中,臭氧自身氧化和羟基自由基氧化同时存在,且以羟基自由基氧化为主。反应过程符合准一级动力学模型,反应速率常数为0.01 min~(-1)。     

石墨烯与抑癌基因p53 DNA片段相互作用的分子模拟与光谱学验证

石墨烯(graphene,G)及其衍生物由于具有独特的理化性质,被广泛应用于能源、生物医学等领域,但尚缺乏其对生物体和环境潜在危害的研究。采用分子动力学模拟并结合光谱学方法(紫外可见吸收光谱、紫外变温实验及荧光光谱),分析了石墨烯与抑癌基因p53启动子区DNA片段(p53-DNA)间的相互作用,并探讨了相关作用机制。石墨烯的部分芳香环与p53-DNA碱基的芳香环之间存在π-π堆积作用,两者可以通过嵌插作用进行结合,同时还通过沟槽作用进一步结合。光谱实验进一步证实,在石墨烯作用下,p53-DNA的熔点(Tm)值升高,EB-DNA体系发生静态荧光淬灭,说明石墨烯能与p53-DNA结合;同时,p53-DNA与石墨烯结合后在260 nm处的吸光度升高,说明石墨烯对p53-DNA的双螺旋结构具有一定的破坏作用。上述研究结果从分子水平上分析了石墨烯与p53-DNA间的相互作用机制,有助于进一步阐明石墨烯的毒性作用机理。     

土地城市化背景下武汉市资源环境承载力仿真研究

运用Vensim软件,通过构建"土地城市化-资源环境承载力"系统动力学模型对不同情景下武汉市资源环境承载力的发展趋势进行仿真,为土地城市化背景下武汉市未来发展方向提供参考。结果显示,协调发展型是最适合武汉市的发展模式,而现状延续型、政绩驱动型和生态环保型情景下武汉市资源环境承载力到2020年均将面临超载压力。武汉市在适当加速推进土地城市化的同时应注重增加耕地面积、加强基础设施建设、降低资源消耗和污染排放,确保资源环境承载系统平稳运行。