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In-situ bio-remediation is a viable cleanup alternative for aquifers contaminated by hydrocarbons such as BTEX. Transport models of varying complexity and capabilities are used to quantify their degradation. A model that has gained wide acceptance in applications is BIOPLUME II, which assumes that oxygen-limited biodegradation takes place as an instantaneous reaction. In this work we have employed theoretical analysis, using non-dimensional variables, and numerical modelling to establish a quantitative criterion demarcating the range of validity of the instantaneous reaction approximation against biodegradation kinetics. Oxygen was the limiting species and sorption was ignored. This criterion relates (o), the Dahmk?hler number at oxygen depletion, to O(o)*, the ratio of initial to input oxygen concentration, (o) > or = 0.7(O(o)*)(2) + 0.1O(o)* + 1.8. The derived (o) reflects the intrinsic characteristics of the physical transport and of the biochemical reaction, including the effect of biomass density. Relative availability of oxygen and hydrocarbons exerts a small influence on results. Theory, verified and refined via numerical simulations, showed that significant deviations of instantaneous reactions from kinetics are to be expected in the space-time region s相似文献
33.
The strategy of smoke control is of high importance for the design process of tunnels, especially for long and large cross-section tunnels. The South Hongmei Rd. Tunnel (SHT) located in Shanghai, China, is a 3.39 km long shield TBM (tunnel boring machine) tunnel with an external diameter of 14.5 m. The point smoke extraction system was proposed initially as the main ventilation strategy during a tunnel fire. To investigate the fire characteristics in the tunnel and develop appropriate smoke control strategies, a series of numerical 3D Computation Fluid Dynamics (CFD) simulations were conducted. Three fire scenarios, namely 5 MW, 20 MW and 50 MW, were modeled to evaluate the point extraction system. The gas temperatures, the stratification of the smoke, air temperature, minimum visibility etc., during the smoke spreading of a fire were analyzed. Based on the results of the simulation, the smoke extraction strategies according to fire scale and fire location were proposed for fire extinguishing. It was found that the three-point extraction opening strategy can control the smoke better than two-point extraction opening strategy under various fire scales, especially under serious fire scenario. From the results, damper openings ranged at closer intervals were found more efficient in two-point extraction system. Besides, placing the damper openings in the longitudinal direction can improve the efficiency of smoke extraction. It also results in reduction of the quantity of prefabricated members of duct slab and the process of assembly will be simplified during the construction. 相似文献
34.
Numerical evaluation of the effectiveness of NO2 and N2O5 generation during the NO ozonation process
Haiqiang Wang Zhuokai Zhuang Chenglang Sun Nan Zhao Yue Liu Zhongbiao Wu 《环境科学学报(英文版)》2016,28(3):51-58
Wet scrubbing combined with ozone oxidation has become a promising technology for simultaneous removal of SO2 and NOx in exhaust gas. In this paper, a new 20-species, 76-step detailed kinetic mechanism was proposed between O3 and NOx. The concentration of N2O5 was measured using an in-situ IR spectrometer. The numerical evaluation results kept good pace with both the public experiment results and our experiment results. Key reaction parameters for the generation of NO2 and N2O5 during the NO ozonation process were investigated by a numerical simulation method. The effect of temperature on producing NO2 was found to be negligible. To produce NO2, the optimal residence time was 1.25 sec and the molar ratio of O3/NO about 1. For the generation of N2O5, the residence time should be about 8 sec while the temperature of the exhaust gas should be strictly controlled and the molar ratio of O3/NO about 1.75. This study provided detailed investigations on the reaction parameters of ozonation of NOx by a numerical simulation method, and the results obtained should be helpful for the design and optimization of ozone oxidation combined with the wet flue gas desulfurization methods (WFGD) method for the removal of NOx. 相似文献
35.
对一维时变的层状云物理化学模式的化学过程作了研究,引入了较为细致的化学模式,并以类似化学反应方程式的方式处理了气液传输、碰并和云雨转化过程。在此基础上讨论了典型条件下的云雨酸化过程。模拟结果表明,高空云雨水组成随时间逐渐减小,地面雨水组成呈峰型分布。在降水后期pH值主要同O3和SO2有关;主要来自气溶胶,来自NH3,气体和气溶胶对的贡献大致相当,和Ca ̄(2+)的云下清除约占60%~80%;在降水前期H2O2时S(Ⅳ)的氧化超过O3,降水后期S(Ⅳ)的氧化主要通过O3。 相似文献
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环境风会改变排烟窗附近的烟气流向和速度,影响建筑内烟气流动,进而导致建筑自然排烟效率受到影响。采用数值模拟方法,对比研究了排烟窗开启角度和环境风对上、下悬窗阻风能力的影响,分析了不同开窗角度下,悬窗进风量和进风区域随开窗角度和风速的变化规律。结果表明:上、下悬窗相对进风量与开窗角度均成指数关系,但上悬窗阻风能力弱于下悬窗,上悬窗开窗角度大于45°后即失去阻风能力,而下悬窗开窗角度大于75°后才逐渐失去阻风能力,且开窗角度小于30°时,下悬窗至少能比上悬窗多减少50%空气进入室内。上悬窗开窗角度小于56°时,主要进风区域为近窗下侧水平区域;下悬窗开窗角度小于30°时,主要进风区域为窗体两侧及远窗下侧竖直区域,随着开窗角度增大,上、下悬窗主要进风区域均过渡到远窗下侧竖直区域。窗体用于日常通风时建议优选上悬窗。若要用于排烟,则应首选下悬窗,开窗角度15°即可满足阻风要求,若选用上悬窗,开窗角度不宜大于45°。 相似文献
38.
采用FDS软件对细水雾扑救汽车涂装车间喷漆室火灾的灭火效能进行数值模拟分析,着重探讨了喷漆室纵向通风、细水雾雾滴粒径、雾滴喷射速度、汽车障碍物等对扑灭油漆火的影响。模拟结果表明:在细水雾与油漆火的相互作用过程中,细水雾对火源的表面冷却和隔氧窒息作用显著;为了防止室内氧气得到补充,在开启细水雾灭火的同时应当联动控制关闭纵向通风系统;在模拟工况条件下雾滴粒径为100μm~300μm的细水雾灭火效果优于粒径为400μm、500μm的细水雾;雾滴在一定喷射速度范围内速度越大灭火效果越好,喷射速度为10m/s的雾滴灭火效果明显优于3m/s和5m/s的雾滴,但是为了防止火焰横向蔓延,喷射速度不宜过高;在汽车障碍物火灾中部分微小的细水雾雾滴受到火焰的卷吸作用,可以绕过障碍物进入火区发挥冷却作用,细水雾灭火系统能够有效控制障碍物火灾,可以应用于汽车涂装车间喷漆室。 相似文献
39.
结合某过江盾构隧道,基于三维流体动力学模拟仿真软件平台,建立三维仿真模型,研究火灾发生在隧道盾构段典型区段时,排烟开口在火源上下游不同的分布模式时烟气层的温度场分布。通过分析模拟结果可知:随着火源上游排烟开口逐步增加,火源上游烟气逆流长度和蔓延速度都相对稳定而后又逐步增长,火源下游的烟气蔓延长度先减小而后又基本趋于稳定,下游烟气沉降高度则有所升高;火源位置处正上方温度则随着上游排烟开口的个数逐步增加而逐渐升高。而从其他的排烟开口变化模式模拟结果可知:随着排烟开口面积或者开口间距的逐步增大,烟气蔓延的速度先增加而后又逐步减小,且开口间距为30m左右时烟气蔓延速度相对较慢;排烟开口宽高比对烟气蔓延影响较小。所获得的结论将有助于相关类型工程的设计和管理。 相似文献
40.
Numerical simulation for impacts of hydrodynamic conditions on algae growth in Chongqing Section of Jialing River, China 总被引:6,自引:0,他引:6
Hydrodynamic conditions are important factors for planktonic algae growth, through introducing two parameters which express the optimal velocity and the velocity range for planktonic algae growth, a new velocity factor was put forward for the formula of growth rate. Therefore, the two-dimensional unsteady ecological dynamic model for algae growth was established to analyze the effects of hydrodynamic conditions on algae growth in Chongqing Reach of Jialing River in China. The temporal and spatial distribution of Chlorophyll-a (Chl-a) concentration was simulated numerically for various water levels, under climate conditions in period of high frequency for algae blooms of Three Gorges Reservoir and nutrition status at present in the research reach. The corresponding locations and areas of likely algae blooms were analyzed and forecasted. The results showed that about 0.04 m s−1 was the optimal velocity for algae growth, and the occurrence of algae blooms in large scale is almost impossible because of relatively high water flow velocity for Jialing River. 相似文献