粉煤灰吸附处理炼油污水中石油类物质的应用研究

以炼油污水气浮后用于冲灰为目的,对粉煤灰吸附炼油污水中的石油类物质进行了初步研究,主要研究了水灰比、与油水的混合时间、静置沉淀时间等因素对粉煤灰吸附石油类效率的影响。研究表明,水灰比对粉煤灰吸附石油类效率的影响最显著。通过正交试验法,找出了粉煤灰处理炼油污水的最优工艺参数组合,为指导现场工作提供了理论依据。同时对粉煤灰吸附处理炼油污水中石油类的性能进行了研究,证实在常温状态下粉煤灰对石油类的吸附等温线符合Freundlich方程。     

Equilibrium study and kinetics of Cu removal from water by zeolite prepared from oil shale ash

Engineered zeolite was produced from oil shale ash by reaction with sodium hydroxide in a closed vessel reactor. This adsorbent was used for removal of copper ions from aqueous solution. The maximum adsorption capacity was 504.6 mg Cu²⁺/g zeolite. Kinetic studies showed that the rate of adsorption of copper is increased with increasing the solution pH and temperature, quantity of the zeolite and agitation speed. The kinetic data were fitted to homogeneous micropore model and found that the mass transfer coefficient and diffusivity of the Cu²⁺ are directly affected by the kinetic parameters. The increase in solution concentration will decrease the mass transfer coefficient while diffusivity is increased.     

Development of a new hydrocarbon index for oil-in-water

A new robust method for determination of hydrocarbons in water without use of Freon^™ or other halogenated solvents has been validated and subjected to an interlaboratory exercise. The method is based on extraction with a light hydrocarbon (boiling point in the 39–69°C range), followed by cleanup for removal of polar components and detection by gas chromatography (GC) with flame ionisation (FID) detection. The performance characteristics of the method are comparable with that of the previous Freon-IR method with recoveries in the 60–80% range and reproducibility (between laboratory variations) of about 30%.

A screening method for hydrocarbons in the range 5 ppm and above based on infrared spectroscopy (IR), and a promising method for detection of low levels based on solid phase extraction (SPE) has been tested and validated.     

油井酸化缓蚀剂述评

本文扼要介绍了国内外近年来在研究和应用油井酸化缓蚀剂方面的现状和发展，并列出了美国几家公司研制的缓蚀剂的性能试验数据。对目前我国的研究工作提出了看法和建议。     

Surfactant-based oil dispersant toxicity to developing nauplii of Artemia: effects on ATPase enzymatic system

The paper deals with the toxicity of a surfactant-based oil dispersant to the ATPase activities of two naupliar stages of Artemia (instar I & II). Both instars were exposed to sub-lethal and lethal concentrations derived from acute toxicity data. The chosen concentrations were near to LOECs and NOECs. An eightfold difference indicated between the instars was instar-exposure time dependent. The most prominent effects were the inhibition and the stimulation of Na⁺/K⁺-ATPase and Mg²⁺-ATPase activities, respectively. The cause of these effects was related to the dispersant components, the surfactants. The pattern stimulation/inhibition of Mg²⁺-ATPase and Na⁺/K⁺-ATPase activities could be used to indicate toxic stress by surfactant-based oil dispersants since previous studies with other contaminants have shown different ATPase activity patterns.     

大庆油田分布式防震减灾信息和辅助决策系统——系统框架研究

简要论述了国内外防震减灾信息和辅助决策系统的发展状况。以大庆油田防震减灾信息和辅助决策系统为基础，详细探讨了分布式防震减灾系统的框架研究，包括ArcIMS的应用、系统框架的二次开发、数据库的远程连接和调用和系统框架的集成等。同时阐述了分布式网络GIS已经成为防震减灾信息和辅助决策系统建设的一个重要发展方向和它的应用价值。     

Experimental design of the Svalbard shoreline field trials

Experimental oil spills on three mixed-sediment beaches in Svalbard, Norway, were designed to evaluate the effectiveness of in situ shoreline cleaning treatments to accelerate natural recovery. These were: sediment relocation (surf washing), mixing (tilling), bioremediation (fertilizer application), and bioremediation combined with mixing. Additionally, natural attenuation was studied as a treatment option. An intermediate fuel oil was applied to the sediment surface in the upper intertidal zone at three experimental sites, each of which had different sediment characteristics and wave-energy exposure. Over a 400-day period, the experiments quantified oil removal, documented changes in the physical character of the beach as well as oil fate and behaviour, assessed toxicity effects associated with treatment, and validated oil-mineral aggregate formation as a result of the selected treatment techniques. The three sites were chosen based on significant differences, and each treatment was quantitatively compared only with other treatments at that site.This paper describes the physical location and the experimental design of the field trials. Some of the key issues that were addressed in the design included: the methodology for application of oil, the application of treatment techniques, the realistic simulation of real-world conditions, and the sampling protocols to overcome sediment and oiling heterogeneity typical of mixed-sediment beaches in order to allow quantitative comparisons of the treatments.     

Estimating Time Windows for Burning Oil at Sea: Processes and Factors

This paper discusses processes and factors for estimating time period windows of in situ burning of spilled oil at sea. Time-periods of in situ burning of Alaska North Slope (ANS) crude oil are estimated using available data. Three crucial steps are identified. The First Step is to determine the time it takes for the evaporative loss to reach the known or established limitation for evaporation and compare this time-period with estimated time of ignition at the ambient wind and sea temperatures. The Second Step is to determine the water up-take of the spilled oil and compare it with the known or established limitation for water-in-oil content. The Third Step is to determine the necessary heat load from the igniter to bring the surface temperature of the spilled oil to its flash point temperature so that it will burn at the estimated time period for ignition of the slick.     

浅谈油气生产中的现场安全管理

油气生产中的各种不安全因素大多来源于现场作业。生产现场是安全管理的控制点。运用安全管理和安全系统工程的一些理论方法，可以提高生产中人的安全意识，减少现场作业中的事故隐患，达到预防事故的目的     

Development and verification of a screening model for surface spreading of petroleum

Overflows and leakage from aboveground storage tanks and pipelines carrying crude oil and petroleum products occur frequently. The spilled hydrocarbons pose environmental threats by contaminating the surrounding soil and the underlying ground water. Predicting the fate and transport of these chemicals is required for environmental risk assessment and for remedial measure design. The present paper discusses the formulation and application of the Oil Surface Flow Screening Model (OILSFSM) for predicting the surface flow of oil by taking into account infiltration and evaporation. Surface flow is simulated using a semi-analytical model based on the lubrication theory approximation of viscous flow. Infiltration is simulated using a version of the Green and Ampt infiltration model, which is modified to account for oil properties. Evaporation of volatile compounds is simulated using a compositional model that accounts for the changes in the fraction of each compound in the spilled oil. The coupling between surface flow, infiltration and evaporation is achieved by incorporating the infiltration and evaporation fluxes into the global continuity equation of the spilled oil. The model was verified against numerical models for infiltration and analytical models for surface flow. The verification study demonstrates the applicability of the model.