Potential of capillary electrophoresis mass spectrometry for the characterization and monitoring of amine-derivatized naphthenic acids from oil sands process-affected water

Capillary electrophoresis coupled to mass spectrometry(CE–MS) was used for the analysis of naphthenic acid fraction compounds(NAFCs) of oil sands process-affected water(OSPW). A standard mixture of amine-derivatized naphthenic acids is injected directly onto the CE column and analyzed by CE–MS in less than 15 min. Time of flight MS analysis(TOFMS), optimized for high molecular weight ions, showed NAFCs between 250 and 800 m/z. With a quadrupole mass analyzer, only low-molecular weight NAFCs(between 100 and 450 m/z) are visible under our experimental conditions. Derivatization of NAFCs consisted of two-step amidation reactions mediated by 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide(EDC), or mediated by a mixture of EDC and N-hydroxysuccinimide, in dimethyl sulfoxide, dichloromethane or ethyl acetate. The optimum background electrolyte composition was determined to be 30%(V/V) methanol in water and 2%(V/V) formic acid. NAFCs extracted from OSPW in the Athabasca oil sands region were used to demonstrate the feasibility of CE–MS for the analysis of NAFCs in environmental samples, showing that the labeled naphthenic acids are in the mass range of 350 to 1500 m/z.     

F2000-Ⅰ型红外光度测油仪的调试应用

应用吉林欧伊尔公司生产的F2000-Ⅰ型红外光度测油仪测量石油类,对红外分光光度法、非分光红外光度法、及餐饮油烟三个方面的精密度、准确度进行了测试,总结出在实验过程中的注意事项。     

基于VOCs浓度反演的地下水中含油物质泄漏原位在线监测方法的建立及应用

石油石化企业的含油物质泄漏进入地下水,会对生态环境造成负面影响。通过构建地下水井模型,比选不同原理的挥发性有机物(VOCs)检测传感器,建立了基于VOCs浓度反演的地下水中含油物质泄漏原位实时在线监测方法。研究发现,常规水质六参数传感器对含油物质泄漏的响应会产生滞后现象,在实时预警监测地下水井中含油物质时可不安装常规水质六参数传感器,节约企业污染防控监测成本。将该方法应用于企业现场进行原位实时监测,当实时监测值超过数据监控平台预警阈值时,系统会发出警报,实现了地下水井中含油物质泄漏实时预警监测。该监测方法具有响应速度快、准确性高、成本低、监测过程简单等优势,将帮助企业实时掌握地下水污染状况,提高地下水污染防控预警效率。     

Physiological and biochemical characteristic of Miscanthus × giganteus grown in heavy metal – oil sludge co-contaminated soil

The effect of oil sludge and zinc, present in soil both separately and as a mixture on the physiological and biochemical parameters of Miscanthus × giganteus plant was examined in a pot experiment. The opposite effect of pollutants on the accumulation of plant biomass was established: in comparison with uncontaminated control the oil sludge increased, and Zn reduced the root and shoot biomass. Oil sludge had an inhibitory effect on the plant photosynthetic apparatus, which intensified in the presence of Zn. The specific antioxidant response of M. × giganteus to the presence of both pollutants was a marked increase in the activity of superoxide dismutase (mostly owing to oil sludge) and glutathione-S-transferase (mostly owing to zinc) in the shoots. The participation of glutathione-S-transferase in the detoxification of both the organic and the inorganic pollutants was assumed. Zn inhibited the activity of laccase-like oxidase, whereas oil sludge promoted laccase and ascorbate oxidase activities. This finding suggests that these enzymes play a part in the oxidative detoxification of the organic pollutаnt. With both pollutants used jointly, Zn accumulation in the roots increased 6-fold, leading to increase in the efficiency of soil clean-up from the metal. In turn, Zn did not significantly affect the soil clean-up from oil sludge. This study shows for the first time the effect of co-contamination of soil with oil sludge and Zn on the physiological and biochemical characteristics of the bioenergetic plant M. × giganteus. The data obtained are important for understanding the mechanisms of phytoremediation with this plant.     

油气矿基于EPTMC模型实现建设项目环保三同时精细化管理建议探讨

环保三同时管理贯穿于油气田建设项目论证前期、施工期、运行期等整个过程,克服建设项目时间紧、任务重,快建快投等困难,同时要做好项目全过程环境保护管理,尤为重要。本文结合环境保护相关法律法规和建设项目三同时管理相关要求,结合气矿实际情况,为实现建设项目环保三同时精细化管理,通过实践验证,总结提出EPTMC管理模型建议。     

Performance evaluation method of oil and gas pipeline integrity management

The performance evaluation of integrity management has become the focus of attention because integrity management has become widely accepted by pipeline operators. This paper proposes a three-index system of pipeline integrity management performance evaluation (TISPIMPE), which includes system construction, implementation process, and pipeline health status, comprehensively evaluating the status, adequacy, and effectiveness of integrity management. It helps the pipeline operators to determine the weakness in each step. Based on the improved analytic hierarchy process (AHP), the different backgrounds of experts are fully considered, and experts' opinions are revised. The adjustment coefficient of performance evaluation is set up simultaneously, and the evaluation results are adjusted to make the results more reasonable. Taking the performance evaluation of pipeline integrity management of an oil and gas company as an example, it is shown that TISPIMPE has reasonable practicability and can accurately reflect the shortcomings of pipeline integrity management. TISPIMPE can effectively help pipeline managers comprehensively and systematically evaluate the performance of pipeline integrity management and gain an in-depth understanding of pipeline operation status.     

喷射诱导气浮用于废水脱油的动力学研究

喷射诱导气浮应用于污水脱油前景广阔。建立了数学模型，进行了单级间歇模拟实验，测定了脱油动力学常数及极限脱油浓度。验证了脱油动力学方程，利用实验结果，得到了用以计算多模型中参数的关联式。所提出的数学模型为建立设计计算和药剂评价方法提供了依据。