基于SVR的船舶溢油事故预测

船舶溢油事故的预测,是确定所需应急资源多少的重要依据;但船舶溢油事故具有小样本性,传统预测方法不再适用。针对船舶溢油事故的小样本性,该文选择SVR模型对其进行预测;SVR算法的关键是核函数的选择及自由参数的确定,针对上述问题该文分别采用交叉验证法、遗传算法;并在matlab软件上建立SVR模型,最后将该模型应用于上海港水域船舶溢油事故的预测。     

有冰条件下撇油器回收溢油速率试验研究＊

为评价一种进口多功能撇油器应对渤海冬季溢油的能力,试验分别对刷式、盘式、鼓式三种撇油头在无冰和有冰(冰密集度约5成)条件下进行收油速率测试。试验以100 L油品为基数,测出在各种组合条件下回收油品所需要的时间,并把鼓式撇油头在有冰条件下的泵速提高,再进行试验。结果发现三种撇油方式的回收速率不仅与撇油头类型有关,同时也取决于是否有冰;在有冰条件下,三种撇油头收油效果都受到影响,其中盘式撇油器受影响最大,无法回收溢油;在有冰条件下加大鼓式撇油头泵速会提高总回收速率,但含水率同时提高;对凝固原油,撇油器无能为力。试验结果对正确评估三种类型的撇油头在两种情况下的收油效果和相关单位应具备的清除溢油能力,以及今后引进设备提高应急能力将起到借鉴作用。     

Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis,emissions, and products

● Collaborative treatment of plastics and OS was established to improve oil quality. ● PE addition successfully improved OS pyrolysis process by deploying H/C_eff ratio. ● Higher H/C_eff ratio promoted cracking to obtain more gas and light oil fractions. ● The degradation of PE and OS was promoted each other under their temperature range. Pyrolysis is an effective method to treat oily sludge (OS) due to its balance between oil recovery and nonhazardous disposal. However, tank bottom OS contains a high content of heavy fractions, which creates obstacles for pyrolysis due to the high activation energy. The incomplete cracking of macromolecules and secondary polymerization decreases the oil quality and causes coking during the operation process. This study introduced polyethylene (PE) into OS to deploy the H/C_eff ratio of feedstocks for pyrolysis. A strong interaction between OS and PE during copyrolysis could be observed from the TG/DTG curves. PE tightly participated in OS degradation, while OS also promoted PE degradation at high temperature. Apparent pits were generated in solid residues from copyrolysis, which was attributed to the uniform and violent gas release. In addition to HCN, other nitrogenous and sulphurous pollutants were inhibited. Accordingly, more gas products were attained after PE addition with more value-added compositions of alkanes and alkenes. Although the oil yield decreased after PE addition, the oil products from copyrolysis possessed higher heating values and higher contents of light fractions with short chains as well as paraffins. Consequently, copyrolysis of OS and PE significantly improved the pyrolysis process and resulted in high oil quality.     

对壳牌石油公司HSE管理体系的几点认识

通过介绍壳牌石油公司建立 ＨＳＥ管理体系的背景和目标,对照我国行业标准 ＳＹ／Ｔ６２６７—１９９７,分析了该公司ＨＳＥ体系的技术特点,详细地讨论了危害和影响管理过程（ＨＥＭＰ）在ＨＳＥ管理体系中的地位和作用。指出,壳牌公司在废弃物管理中采用的分级政策和记帐政策颇具特色,值得借鉴。     

海上溢油应急物资调度双目标规划模型

为最大程度降低溢油事故造成的不利影响,提出充分考虑海上油膜漂移特性及溢油点和漂移点对救援物资需求不确定等特点,基于鲁棒优化思想,建立救援应急成本最小、应急时间最短的双目标规划模型,并基于NSGA-Ⅱ算法设计求解方法。结果表明:决策者可根据自身对溢油事故规模的判断,得到不同应急物资调度方案,为应急出救点的选择和物资调度提供合理决策依据。     

油松排放萜烯类化合物浓度的日变化及排放速率的研究

 采用封闭式采样和气相色谱法分析监测了北京主要树种油松排放的萜烯类化合物，其中包括α和β蒎烯、蒈烯、松油烯、柠檬烯和罗勒烯，以及少量异戊二烯。松油烯、B蒎烯、柠檬烯和蒈烯的排放量之和占油松排放碳氢总量的94％以上。萜烯和异戌二烯排放速率随日照和温度的升高而增加。萜烯等浓度的日变化表明在正午和午夜油松有两个排放高峰。在日均气温为18℃时油松的碳氢化合物平均总排放速率约为8.7μh/h.g。     

渤海溢油应急预报系统

本文建立的渤海溢油应急预报系统，采用目前比较成熟的环境动力和溢油行为模式，提供海面油膜的位置和覆盖面积，水体中油的浓度分布及溢油的比重，粘度，挥发量，残留量，平均厚度等物化参数的实时预报信息。适用于渤海海域的溢油应急报和环境风险评价。系统界面友好，操作简单，反应快捷，后处理功能完工具有可扩充性。     

辽河油田石油污染土壤的2阶段生物修复

建立了污染土壤预制床处理工程,对不同类型原油污染土壤分别进行堆腐处理,历时2个阶段,共运行210d.当稀油、稠油、特稠油和高凝油污染土壤中石油烃总量(TPH)为25.8～77.2g·kg^-1时,经过53d(为第1阶段)的运行,TPH去除率38.37%～56.74%.第2年(为第2阶段)继续处理156d,TPH降解率达到66.59%～80.96%.连续运行结果表明,污染土壤中易分解的石油烃污染物大部分在第1阶段得到降解,第二阶段降解率明显降低.     

高效原油降解菌处理油田采出水

利用油田采用废水中原有微生物种群分离驯化出的高效原油降解菌，通过单一菌种高效原油降解菌降解性能实验，高效混合菌正交实验，最佳组合菌株的连续生物处理油田采出水实验，都取得了处理低浓度含油废水的良好效果。这表明在常规物理，化学法处理油田采出水的基础上，利用生物再空度处理是可行的。