矿物超细颗粒的形成机制、结构特征及其环境行为和效应

矿物超细颗粒在自然环境中普遍存在,具有独特的环境行为和效应,对元素地球化学循环、污染物迁移转化和生态环境演变等有重要影响.矿物超细颗粒的环境行为和效应与其形成过程和结构特征密切相关.综述了物理、化学和生物过程驱动的矿物超细颗粒的形成机制,介绍了用于表征矿物超细颗粒结构特征的显微镜、光谱、质谱和同步辐射技术,分析了矿物超细颗粒在环境中的迁移转化及其与污染物的吸附、氧化还原和催化转化作用,总结了矿物超细颗粒的食物链积累、生物和生态毒性等环境效应,并对颗粒结晶路径、风险管控和微纳界面调控等重要研究方向进行了展望.超细颗粒是连接微观物质与宏观矿物晶体之间的桥梁,全面认识复杂基质中矿物颗粒的环境属性及其与污染物的微观作用机制,有助于指导矿物超细颗粒在环境污染修复中的应用,从而优化功能材料的设计,促进绿色低碳纳米技术的发展.     

中国交通运输碳排放强度时空交互特征及跃迁机制

采取多种空间分析的方法,对2002～2020年交通运输业碳排放强度的时空交互特征进行剖析,通过得到的时空跃迁类型与面板分位数模型进行嵌套来探究其跃迁机制,最后根据不同的跃迁机制引入地理探测器模型来考察影响交通运输业碳排放强度的不同因素之间的交互作用效应.结果表明: ①中国30个省区的交通运输业碳排放强度整体呈波动下降态势,在空间上的聚集水平也相对稳定.②ESTDA的时空交互特征表明,西北地区和周边邻接空间单位的关系不稳定,变化和波动较大.而东部沿海城市等经济发达地区已经形成了成熟的交通运输网络,因此局部空间格局也相对稳定,但仍有部分地区存在时空竞争性.③交通运输业碳排放强度时空跃迁可分为4类驱动或制约模式（人口-经济-城镇化制约模式;人口-经济-城镇化-设施制约模式;技术-消费-产业驱动模式和技术-产业-规制驱动模式）.大部分省份受低分位制约和高分位驱动两种模式的影响,仅有少部分省份受高分位制约和低分位驱动的作用影响,且绝大多数属于西北或西南地区.④根据得出的交通运输业碳排放强度跃迁机制进一步引入地理探测器模型,注重多因子的协调发展,加强区域间协同治理.     

植物篱对土壤养分流失的控制机理研究

植物篱是一种能有效减少地表径流、保土蓄水的水土保持措施,但其控制土壤养分流失相关机理的研究甚少。2001年在长江上游支流吒溪河的二级支流王家桥小流域设立的6个香根草(Vetiveriazizanioides)植物篱试验小区中进行地形测量及采样分析,拟通过局部地形变化、土壤颗粒和养分在小区内的空间分布变化来分析植物篱对紫色土区土壤养分流失的控制机理。坡型测量结果表明,植物篱带前出现泥沙堆积,说明植物篱能有效阻止侵蚀泥沙的向下搬运;机械组成分析结果表明,侵蚀影响下的土壤颗粒粒径在空间上出现分布差异,侵蚀剧烈的局部>0.2mm土壤颗粒明显富集,而植物篱对不同粒径的土壤颗粒的流失均有控制效果,但对粒径较大的颗粒的流失控制效果更明显;全量养分和速效养分含量空间分布的分析结果则表明,植物篱对土壤养分流失具有明显的控制作用。     

生物膜净化含苯废气的性能研究

在生物法净化废气装置中生物膜是设备的主体和关键．研究以净化含苯废气的生物滴滤塔为对象,采用静态反应器对塔内生物膜的净化性能进行研究,探索其过程机理,为生物滴滤器的优化提供技术支持．结果表明,在生物滴滤器中单位体积生物膜的呼吸速率和苯去除速率都沿气流方向逐渐减小,但单位质量生物膜的苯去除速率却是塔中部高两边低．研究发现,当生物膜经过3d的闲置后,苯的消除能力提高了70％左右,但闲置时间超过5d后,生物净化性能开始下降．综合实验结果,推测在生物膜中同时存在苯的生物降解过程和生物储备能源的合成过程,在苯浓度越高的地方储备能源的量也越多,储备能源的存在降低了生物膜的净化能力但增强了生物膜的稳定性．     

Response of bioaerosol cells to photocatalytic inactivation with ZnO and TiO2 impregnated onto Perlite and Poraver carriers

•ZnO/Perlite inactivated 72% of bioaerosols in continuous gas phase. •TiO₂ triggered the highest level of cytotoxicity with 95% dead cells onto Poraver. •Inactivation mechanism occurred by membrane damage, morphological changes and lysis. •ZnO/Poraver showed null inactivation of bioaerosols. •Catalysts losses at the outlet of the photoreactor for all systems were negligible. Bioaerosols are airborne microorganisms that cause infectious sickness, respiratory and chronic health issues. They have become a latent threat, particularly in indoor environment. Photocatalysis is a promising process to inactivate completely bioaerosols from air. However, in systems treating a continuous air flow, catalysts can be partially lost in the gaseous effluent. To avoid such phenomenon, supporting materials can be used to fix catalysts. In the present work, four photocatalytic systems using Perlite or Poraver glass beads impregnated with ZnO or TiO₂ were tested. The inactivation mechanism of bioaerosols and the cytotoxic effect of the catalysts to bioaerosols were studied. The plug flow photocatalytic reactor treated a bioaerosol flow of 460×1 0⁶ cells/m³_air with a residence time of 5.7 s. Flow Cytometry (FC) was used to quantify and characterize bioaerosols in terms of dead, injured and live cells. The most efficient system was ZnO/Perlite with 72% inactivation of bioaerosols, maintaining such inactivation during 7.5 h due to the higher water retention capacity of Perlite (2.8 mL/g_Perlite) in comparison with Poraver (1.5 mL/g_Perlite). However, a global balance showed that TiO₂/Poraver system triggered the highest level of cytotoxicity to bioaerosols retained on the support after 96 h with 95% of dead cells. SEM and FC analyses showed that the mechanism of inactivation with ZnO was based on membrane damage, morphological cell changes and cell lysis; whereas only membrane damage and cell lysis were involved with TiO₂. Overall, results highlighted that photocatalytic technologies can completely inactivate bioaerosols in indoor environments.     

Remediation of 2,4-dichlorophenol-contaminated groundwater using nano-sized CaO2 in a two-dimensional scale tank

• Nano CaO₂ is evaluated as a remediation agent for 2,4-DCP contaminated groundwater. • 2,4-DCP degradation mechanism by different Fe²⁺ concentration was proposed. • 2,4-DCP was not degraded in the system for solution pH>10. • The 2,4-DCP degradation area is inconsistent with the nano CaO₂ distribution area. This study evaluates the applicability of nano-sized calcium peroxide (CaO₂) as a source of H₂O₂ to remediate 2,4-dichlorophenol (2,4-DCP) contaminated groundwater via the advanced oxidation process (AOP). First, the effect and mechanism of 2,4-DCP degradation by CaO₂ at different Fe concentrations were studied (Fenton reaction). We found that at high Fe concentrations, 2,4-DCP almost completely degrades via primarily the oxidation of •OH within 5 h. At low Fe concentrations, the degradation rate of 2,4-DCP decreased rapidly. The main mechanism was the combined action of •OH and O₂^•−. Without Fe, the 2,4-DCP degradation reached 13.6% in 213 h, primarily via the heterogeneous reaction on the surface of CaO₂. Besides, 2,4-DCP degradation was significantly affected by solution pH. When the solution pH was>10, the degradation was almost completely inhibited. Thus, we adopted a two-dimensional water tank experiment to study the remediation efficiency CaO₂ on the water sample. We noticed that the degradation took place mainly in regions of pH<10 (i.e., CaO₂ distribution area), both upstream and downstream of the tank. After 28 days of treatment, the average 2,4-DCP degradation level was ≈36.5%. Given the inadequacy of the results, we recommend that groundwater remediation using nano CaO₂: (1) a buffer solution should be added to retard the rapid increase in pH, and (2) the nano CaO₂ should be injected copiously in batches to reduce CaO₂ deposition.     

当代中国环境治理的权利观

当代中国环境治理的权利观是指从权利的角度去考察、理解当代中国的环境治理,推进当代中国的生态文明建设事业。从这一角度来看,环境相关权利是当代中国环境治理的基本价值目标,也是重要的治理工具。所谓环境相关权利,是指环境治理有助于保障的环境权、生存权和发展权、生命权和健康权,以及在环境治理中可以运用到的知情、表达、参与、监督等权利。当代中国环境治理的权利观,在理论上符合生态文明建设的以人为本原则,符合国家治理体系和能力现代化的方针和取向,在实践上也能够揭示当代中国生态文明建设和环境治理的基本特征、精神实质和发展方向,既具有阐释性,也具有建构性。     

美缝剂TVOC释放量与释放规律的测试与分析

提出了环境舱法测试美缝剂总挥发性有机化合物(TVOC)释放量的方法,对市场常见的美缝剂产品的TVOC进行了测试,并研究了美缝剂的TVOC释放规律和主要污染物.同时对美缝剂的甲醛释放量进行了测试.通过对16种环氧树脂美缝剂产品的数据分析显示,美缝剂产品的甲醛释放量风险较低;75%的产品在第7天的TVOC释放量可达到500μg·m^-3以下.但个别产品在28 d时仍有明显的VOC释放,显示其具有长期缓慢释放的特点.美缝剂释放的主要污染物为苯甲醛与苯甲醇,个别产品检出有甲苯和邻苯二甲酸酯类物质.     

7.0 m采高综采面回采巷道变形破坏规律研究

针对神东矿区大柳塔煤矿采用7.0 m采高综采面回采5-2煤三盘区时回采巷道出现不同程度的变形破坏现象,采用现场实测的方法对52304及52303工作面回风顺槽之间的区段煤柱进行了巷道变形及应力变化规律的监测,并运用FLAC3D数值模拟软件对不同埋深条件下两工作面之间区段煤柱的应力分布规律进行了模拟,最后总结分析了回采巷道变形破坏的机理,并得出采空区段煤柱的失稳是造成回采巷道变形破坏的根本原因。从而为巷道的合理布置及相应控制对策的提出提供基础数据,以保证矿井安全高效的生产。     

大型铁路客运站大客流预警及应对方案设计 ——以北京西站为例

铁路客运站作为旅客集散地,出入站客流量会因为节假日、大规模列车晚点或停运等突发事件出现大规模聚集。当车站出现高密度客流时,若未能及时采取有效的应对措施,极易出现踩踏等事故。为应对车站大客流情况,首先制定了黄、橙、红三级预警机制。其中黄、橙预警用于应对车站高密度客流情况,而红色等级预警则用于应对短时间内车站需迅速疏散客流的紧急情形和大量客流长时间无法乘车离开的情形。最后重点研究了基于不同等级预警的应对方案。所提出的大型客运站大客流预警与应对方案实际应用于北京西站,经过多次春运和暑运检测,起到了良好的效果。