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41.
Eric Lichtfouse Valérie Sappin-Didier Laurence Denaix Giovanni Caria Laure Metzger Najat Amellal-Nassr Jens Schmidt 《Environmental Chemistry Letters》2005,3(3):140-144
We studied polycyclic aromatic hydrocarbons (PAHs) in crop soils amended with 1000 tonnes dry weight of sewage sludges per
10,000 m2 from 1974 to 1992, then after sludges addition from 1993 to 1999. The absence of variations of total PAHs levels of control
soils, averaging at 123 μg/Kg, shows the absence of horizontal contamination. During sludges addition, the total PAHs levels
in amended soils increased from 232 to 402 μg/Kg. Seven years after sludges addition, it decreased to 275 μg/Kg, which is
still more than twice –the levels of control soils. This finding shows that sludges PAHs are preserved in crop soils for long
periods of time, on a human scale. 相似文献
42.
Polycyclic aromatic hydrocarbons (PAHs) have long been recognised as potential carcinogens in animals in which biotransformation into reactive metabolites can lead to DNA damage. In animals PAHs metabolism mainly occurs in hepatic microsomes and is associated with the cytochrome p-450 mediated mixed functional oxidase (MFO) system. PAH metabolism in plants has been shown to occur via a similar enzyme system, but has received relatively little attention. This study is looking at how the plant species Plantago lanceolata metabolises benzo(a)pyrene (B(a)P), which is one of the PAHs whose metabolism has been studied extensively in animals. The aim of the work is to establish firstly that the B(a)P is taken up and secondly that it is biotransformed by the plant to products possibly similar to those found in animals. This work is achieved by using C-14-B(a)P along with whole body autoradiography, scintillation analysis and chromatography techniques to locate the B(a)P and its metabolites. 相似文献
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46.
The aim of this research work is to investigate the temporal and regional behaviour of the PAH in the Thessaloniki's area. During a period of six months, airborne particulate matter was collected twice a week and PAH were determined by HPLC. Profiles as well as concentrations of selected cancerogenic PAH differ in some cases from area to area and have characteristic, temporal changes of concentration. 相似文献
47.
运用Agilent(安捷伦)1200系列高效液相色谱和多环芳烃专用柱ZORBAX Eclipse PAH(4.6×250mm、5μm,P.N.959990-918,S.N.USPAB01066),对16种多环芳烃化合物混合溶液进行分析,根据具体实验条件优化EPA8310中色谱分离条件并得到了更节省时间、分离效率更好的流动相梯度变化程序。 相似文献
48.
Habitat function of agricultural soils as affected by heavy metals and polycyclic aromatic hydrocarbons contamination 总被引:20,自引:0,他引:20
Ecotoxic activity of soils polluted with polycyclic aromatic hydrocarbon (PAH) and heavy metals (HM) was evaluated in pot and laboratory experiments. Plants and soil microorganisms were chosen as test organisms and six different soil materials were used in the study. The applied levels of HM and PAH were aimed to reflect environmental conditions in the "worst case" situation. Zn(2+), Pb(2+) and Cd(2+) were introduced to the soils as an aqueous solution of the mixture of salts at the concentrations corresponding to 1000, 500 and 3 mg kg(-1), respectively. Mixture of four PAH compounds (flourene, anthracene, pyrene and chrysene) as a CH(2)Cl(2) solution was applied at levels of 10-100 mg summation operator 4PAH kg(-1). Population and activity of soil microflora was evaluated as measured of total bacteria counts, intensity of respiration and enzyme activity (dehydrogenases and phosphatases). Effect on plants was evaluated on the base of the growth (plant at an early stage of their development) and yield (mature plant) measurements. The results indicate that combined effect of PAH and heavy metals on soil microorganisms activity and on some plants at an early stage of their development can be stronger than in soils amended with HM or PAH separately. Reaction of tested organisms was related to soil properties, PAH concentration, time and plant species. Mature plants (maize) were insensitive to the applied levels of both group of contaminants. 相似文献
49.
Source identification of polycyclic aromatic hydrocarbons in environmental samples has advanced greatly in the last 20 years and continues to advance. To realize potential benefits and avoid possible pitfalls, however, great care is needed as one applies published diagnostic tools to data sets. This commentary reflects some recent observations, concerns, and recommendations. 相似文献
50.
A method involving high resolution gas chromatography combined with ion trap (HRGC-MS/MS) and negative chemical ionisation
(NCI) was developed for the determination of nitrated or oxygenated polycyclic aromatic hydrocarbons (nitro-PAHs, oxy-PAHs)
and other electrophilic substitutes in soil samples. Efficient clean-up was achieved by a combination of methods for the determination
of PAHs in soil and nitro-PAHs in aerosol using solid phase extraction (SPE) and semipreparative high performance liquid chromatography
(HPLC). In samples of surface soil from the city of Basle (Switzerland), nitro-PAHs (mainly 3-nitrofluoranthene and 1-nitropyrene)
were found in concentrations between 30 and 800 ng/kg dry weight. Oxy-PAHs and parent PAHs revealed 102-104-fold higher levels. Nitro-PAHs which are up to 105 times more mutagenic seem to be less persistent in soil than the parent forms, although their entire mutagenic potential
has to be estimated as being on the same order of magnitude. In urban air particulate matter, the amounts of nitro-PAHs (2–62
pg/m3) were 10–100 times lower than oxyPAHs and parent PAHs which were both found in a similar range. 3-nitrobenzanthrone, a recently
described suspected human carcinogen has not yet been detected. Using multivariate statistical analysis, it was possible to
elucidate similarities or special characteristics of substances in a given matrix reflecting their chemical properties or
specific emission sources. 相似文献