超声波萃取-高效液相色谱法测定总悬浮颗粒物中的多环芳烃

研究了一种用中流量采样器采样,超声波萃取,硅镁型吸附剂柱层析预分离.高效液谱测定总悬浮颗粒物的实验方法,在16分内可分高萘、蒽、芘、苯并(a)芘、苯并(ghi)苝等15种多环芳烃.已在大气环境的实际监测中得到应用.     

大连湾沉积物中PAHs的初步研究

对采集大连湾附近海域的沉积物中多环芳烃（PAHs)进行了定性和定量分析，并探讨了其在沉积物中的分布特征。大连湾表层沉积物中PAHs含量的变化范围为32．70－3558．88ng/g，平均值1152．08ng/g。大连湾表层沉积物中PAHs以油类污染为主。其含量分布，大连港附近海域最高，东北部靠近大连湾煤码头航道测站次之，由西北和东北向南逐步递减，呈现出明显的两点污染源特征。     

Sorption of pyrene on two paddy soils and their particle-size fractions

In the present study, the sorption of pyrene on two kinds of bulk paddy soils, Gleyic Stagnic Anthrosols, and Ferric accumulic Stagnic Anthrosols as well as their particle-size fractions was investigated. The sorption isotherms fitted well with Freundlich equation. For both soils, the clay fraction（ 〈 2μm） and coarse sand fraction（2000-250μm） had higher sorption capacity than fine sand fraction（250-20 μm） and silt fraction（20-2 μm）. The IogKoc values obtained of each soil and its particle-size fractions were similar, proving that SOM content was a key factor affecting pyrene sorption. The Kd values showed a significant correlation with contents of dithionite-extractable Fe in both paddy soils and a good relationship with CEC in Gleyic Stagnic Anthrosols, indicating possible effects of surface properties of particle-size fractions on the sorption of pyrene.     

唐山市大气中多环芳烃污染现状研究

通过污染源调查和采集样品分析得出唐山市大气中多环芳烃污染现状，与国内外一些城市相比较，了解目前唐山市大气中多环芳烃污染水平。     

吉林市大气中PM10和PAHs污染特征

研究了吉林市大气PM10的污染水平和其中优控PAHs总量的地区和季节分布特征。同时对PM10与PAHs的相关性进行了分析。研究表明，PAHs与大气PM10的地区分布大致成正相关，春季最重，夏季最轻：哈达湾最重，江南公园最轻。两者同时受到污染源排放和气象因素的影响。     

多环芳烃的分配系数与双区理论

以双区理论为基础,提出了多环芳烃的致癌性与其分配系数之间的定量关系方程,并利用该方程计算了77个多环芳烃的致癌性。计算值与实验值基本符合。     

多环芳烃的污染及其生物修复

多环芳烃(PAHs)是环境介质中普遍存在的难降解有机污染物，文中综述了目前国内外对PAHs的研究状况，重点阐述了它的来源分布、迁移转化、生物毒性、监测控制及其生物修复的研究进展等，从而为防治环境污染提供科学依据。     

商用垃圾流化床焚烧炉多环芳烃排放的环境评价

对流化床垃圾焚烧炉中PAHs的排放特性进行了研究 .结果表明 ,烟囱烟气为流化床垃圾焚烧炉PAHs排放的主要途径 ,日排放量要高于其它途径 1— 2个数量级 ,且以低分子量物质为主 .脱除剂的添加对烟气中PAHs有减少的作用 ,但却增加了循环出口水中PAHs含量 .不同工况时PAHs环境排放毒性有变化 ,垃圾与煤混烧大于全煤 ,添加脱除剂大于未添加工况 ,但少于垃圾比例高的工况 .垃圾比例越高 ,毒性越大     

广州市大气可吸入颗粒物(PM10)中多环芳烃的季节变化

采集广州五山、荔湾(2002-06-12～2003-06-31)2个采样点共112个PM10样品进行了GC/MS分析,结果表明2采样点全年多环芳烃浓度范围为8.11～106.26 ng·m-3,呈现出夏季低冬季高的特征.PAHs化合物的相对分布也呈明显的季节变化,5～6环PAHs的比重夏季比冬季高,而3～4环PAHs的比重冬季比夏季高.冬季PAHs可分为2种模式,不同模式之间PAHs的浓度和分布特征有明显的差异.统计结果表明,广州市多环芳烃浓度变化主要受气象条件的影响,风速(当温度＜20℃时)和温度(当温度＞20℃时)是影响多环芳烃浓度最主要的因素.此外,本研究还表明,汽车尾气排放是广州市大气颗粒物多环芳烃污染最主要的污染来源.     

Preliminary study on organic contaminants in the water of northwest part of the Lake Chao

The waterquality of the downstream of Nanfei River and the northwest area of Lake Chao is evaluated from organic analysis aspect. PAHs such as fluoranthene, pyrene are detected in the waters collected from downstream river and river mouth. More phenolic compounds are found in the river water. Some halogenated hydrocarbons are present in the river and lake waters. A great many of aliphatic hydrocarbons and benzene hydrocarbons found in all the water samples are about one third of the total organics detected. The hydrophobic components are found to be present not only in water but also in suspended sediment. The ratio of the amount existing is 0.4 in sediment and 1 in particle-free water. The quantity of humic materials existing in lake water is larger than that in river water. The proportion of the humic materials in lake water to that in river water is 1.9 to 1. In the lake water, some natural substances, such as dimethyl disulfide, alpha-pinene, azulene, and 6- methyl -2-heptanone are observed.