沸石用于去除废水中的氨氮

天然沸石及改性沸石对氨氮有很强的选择性吸附能力。介绍了沸石去除废水中氨氮的应用研究,包括在O/A生物处理系统、二级氧化塘处理系统、土地处理系统、湿地系统和堆肥系统等中的应用。分析了氨氮在沸石上发生吸附和离子交换的主要影响因素和规律。为开拓沸石在废水处理中的应用提供科学与技术基础。     

粮食基础设施震后恢复重建关键问题研究

在对汶川8.0级地震后绵阳市粮食基础设施破坏情况调研的基础上,提出恢复与发展并重、粮食基础设施节点与网络并行、推进行业整合和信息化的建设思路,规划了绵阳市灾后恢复重建的维修保障和重建发展项目,并对规划实施效果进行了经济和社会效益分析。     

Effects of long-term amendment of organic manure and nitrogen fertilizer on nitrous oxide emission in a sandy loam soil

To understand the effects of long-term amendment of organic manure and N fertilizer on N2O emission in the North China Plain, a laboratory incubation at different temperatures and soil moistures were carried out using soils treated with organic manure （OM）, half organic manure plus half fertilizer N （HOM）, fertilizer NPK （NPK）, fertilizer NP （NP）, fertilizer NK （NK）, fertilizer PK （NK） and control （CK） since 1989. Cumulative N2O emission in OM soil during the 17 d incubation period was slightly higher than in NPK soil under optimum nitrification conditions （25℃ and 60% water-filled pore space, WFPS）, but more than twice under the optimum denitrification conditions （35℃ and 90% WFPS）. N2O produced by denitrification was 2.1-2.3 times greater than that by nitrification in OM and HOM soils, but only 1.5 times greater in NPK and NP soils. These results implied that the long-term amendment of organic manure could significantly increase the N2O emission via denitrification in OM soil as compared to NPK soil. This is quite different from field measurement between OM soil and NPK soil. Substantial inhibition of the formation of anaerobic environment for denitrification in field might result in no marked difference in N2O emission between OM and NPK soils. This is due in part to more rapid oxygen diffusion in coarse textured soils than consumption by aerobic microbes until WFPS was 75% and to low easily decomposed organic C of organic manure. This finding suggested that addition of organic manure in the tested sandy loam might be a good management option since it seldom caused a burst of N2O emission but sequestered atmospheric C and maintained efficiently applied N in soil.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Imazaquin degradation and metabolism in a sandy loam soil amended with farm litters

Irnazaquin applied in legume crops has a long residual time in soil, which often impacts safety of the susceptible crops. To increase safety of imazaquin application, two composted litters, bovine manure （BM） and chicken manure （CM）, were used to determine their effects on imazaquin environmental behavior by incorporating each kind of manure into the tested sandy loam soil at 10% （w/w）. The degradation of imazaquin in BM- and CM-amended soil was about 2.4 and 1.5 times, respectively, faster than that in unamended soil. The half-lives of imazaquin in BM-amended soil varied between 6.7 and 15.4 d over the temperature range of 20 to 40℃, and the degradation rate constant （k） increased by a factor of about 1.5 for every 10℃ change. Higher mix ratio did not significantly increase the degradation, and the optimal active degradation of imazaquin was observed approximately at the mix ratio of 10：1 of soil to BM. The different moisture levels had negligible effect on imazaquin degradation. In both unamended and BM-amended treatments, two metabolites were observed at 5, 10 and 30 d after treatment. One metabolite at retention time （RT） of 8.4 rain was identified as 2-（4- hydroxyl-5-oxo-2-imidazolin-2-yl） quinoline acid, originating from the loss of isopropyl group and hydroxylation at the 4-position of imidazolinone ring. The other at RT of 12.9 rain was identified as quinoline-2,3-dicarboxylic anhydride, resulting from detachment of imidazolinone ring and the forming of dicarboxylic anhydride. This finding suggested that the addition of farm litters into soil might be a good management option since it can not only increase soil fertility but also contribute to increase safety of imazaquin application to the following susceptible crops.     

农地非农化代际配置与农地资源损失

合理的资源利用要求资源配置在代际上是有效率的。在资源代际最优配置原理的基础上,建立了一个衡量农地非农化是否符合代际配置效率的宏观决策模型,对我国20世纪90年代以来的农地非农化进行了检验。结果显示,若以1989-2003年为研究区间,1989-1996年阶段东、中、西部地区的过度非农化比例分别占各自实际非农化数量的6.58%、6.84%和7.85%,反映出1989-1996年期间的农地非农化存在一定的短期行为,造成农地的过度非农化。因此,未来一段时间的农地非农化政策应该进一步控制农地非农化的速度,来保证农地资源能够在未来得到更优的利用。     

西安市大气和水污染对人群健康损害的经济价值损失研究

环境污染对人群健康造成损害的经济价值评价一直是学术界讨论的热点．采用不同的价值评估方法-VPLL潜在寿命损失年法、VSL统计生命价值法、WTP支付意愿法对西安市1996—2003年的大气和水污染对人群健康造成的经济损失进行评价。结果表明：1996—2003年。西安市大气和水污染健康损失年平均为228792万-434237万元，占GDP的3．69％-7％。对居民健康有显着影响。     

Experimental investigation of a 250-kW turbine organic Rankine cycle system for low-grade waste heat recovery

An organic Rankine cycle (ORC) is generally used for converting low-grade heat into electricity. In this study, an extensive literature survey was conducted to identify current research gaps on experimental ORC systems. Specifically, there is limited experimental data and limited details on thermal and expander efficiencies of ORC systems. In order to address these gaps, the objective of this study included developing a turbine ORC with a power output exceeding 50 kW and thermal efficiency exceeding 8% for a heat source temperature < 120°C. The experimental results indicated that the system achieved a net power output of 242.5 kW and a thermal efficiency of 8.3% (the highest value for a turbine ORC system for the heat source temperature below 120°C). Thus, the study addressed the gaps identified in the research area of ORCs.     

农地整理项目农户耕地损失补偿额度的实证研究——基于耕地资源价值与农户受偿意愿

从耕地资源价值出发,测算农地整理项目农户耕地损失补偿额度,并基于湖北省孝感市和潜江市的农户调查数据分析农户的受偿意愿及其影响因素。研究表明:基于耕地资源价值体系,测算得到孝感市和潜江市农地整理项目农户耕地损失补偿额度分别为1 449 695.76、1 784 296.17元/hm~2;农户所期望得到的耕地损失补偿标准远低于耕地资源价值体系测算出来的理论值,两市农户对耕地损失的平均受偿意愿额度为336 197.95元/hm~2,可以农户受偿意愿为主、耕地农业生产价值和社会保障价值为辅,制定农地整理项目农户耕地损失补偿标准;受教育程度对补偿标准有显著负向影响,农户文化程度的提高有助于提高其对农地整理事业的认知程度,进而促进我国农地整理事业的发展;土地权属调整是解决农户耕地损失的一项重要措施,做好农地整理项目土地权属调整工作需充分尊重农户的意愿,并以农业现代化作为土地权属调整的目标。     

The food-print of Paris: long-term reconstruction of the nitrogen flows imported into the city from its rural hinterland

Between the tenth and twentieth century the population of Paris city increased from a few thousand to near 10 million inhabitants. In response to the growing urban demand during this period, the agrarian systems of the surrounding rural areas tremendously increased their potential for commercial export of agricultural products, made possible by a surplus of agricultural production over local consumption by humans and livestock in these areas. Expressed in terms of nitrogen, the potential for export increased from about 60 kg N/km2/year of rural territory in the Middle Ages, to more than 5,000 kg N/km2/year from modern agriculture. As a result of the balance between urban population growth and rural productivity, the rural area required to supply Paris (i.e. its food-print) did not change substantially for several centuries, remaining at the size of the Seine watershed surrounding the city (around 60,000 km2). The theoretical estimate of the size of the supplying hinterland at the end of the eighteenth century is confirmed by the figures deduced from the analysis of the historical city toll data (octroi). During the second half of the twentieth century, the ‘food-print’ of Paris reduced in size, owing to an unprecedented increase in the potential for commercial export associated with modern agricultural systems based on chemical N fertilization. We argue that analysing the capacity of territories to satisfy the demand for nitrogen-containing food products of local or distant urban population and markets might provide new and useful insights when assessing world food resource allocation in the context of increasing population and urbanization.