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101.
102.
Organochlorine pesticides in the ambient air of Chiapas, Mexico 总被引:1,自引:0,他引:1
Alegria H Bidleman TF Figueroa MS 《Environmental pollution (Barking, Essex : 1987)》2006,140(3):483-491
Organochlorine (OC) pesticides were measured in the ambient air of Chiapas, Mexico during 2000-2001. Concentrations of some OC pesticides (DDTs, chlordanes, toxaphene) were elevated compared with levels in the Great Lakes region, while those of other pesticides were not (hexachlorocyclohexanes, dieldrin). While this suggests southern Mexico as a source region for the former group of chemicals, comparably high levels have also been reported in parts of the southern United States, where their suspected sources are soil emissions (DDTs, toxaphene) and termiticide usage (chlordane). Ratios of p,p'-DDT/p,p'-DDE and trans-chlordane/cis-chlordane/trans-nonachlor (TC/CC/TN) in Chiapas suggest a mixture of fresh and weathered sources, while congener profiles of toxaphene suggest emission of old residues from soils. This is supported by air parcel back trajectory analysis, which indicated that air masses over Chiapas at the time of sampling had previously passed over areas of continuing or recent use of some OC pesticides as well as areas of past use. 相似文献
103.
Concentration and fate of persistent organochlorine pesticides in estuarine sediments using headspace solid-phase microextraction 总被引:4,自引:0,他引:4
The concentration and fate of persistent organochlorine pesticides (OCPs) in estuarine surface sediments in Erh-jen and Lan-yang rivers, Taiwan were investigated using headspace solid-phase microextraction (HSSPME) method to evaluate the possible pollution potential and guideline for OCP concentrations in Taiwan. The HSSPME method exhibits a good analytical performance with low detection limits for OCP determination in sediment. In addition, results obtained using the developed HSSPME method were in good agreement with those obtained using Soxhlet extraction in a certified sample. The developed analytical method was further applied to the determination of concentrations of OCP residues in surface sediments from the estuaries of the selected rivers in Taiwan. A total of 20 surface sediments from each river was collected from 10 sampling stations. The total OCP concentrations in sediments from Erh-jen River ranged from 0.17 to 5.04 ng/g-dw with the mean values of 0.25–1.24 ng/g-dw for HCHs, 0.10–0.89 ng/g-dw for cyclodienes and 0.16–0.64 ng/g-dw for DDTs. The concentrations of OCPs in sediments from Lan-yang River were in the range 0.37–0.9 ng/g-dw with an average of lower than 0.5 ng/g-dw. HCHs and DDTs were abundant in the estuarine sediments from the selected rivers. Results obtained in this study show that the origin of OCPs in the surface sediments from Erh-jen River is a combination of erosion of the weathered soils and long-range atmospheric transport, while the OCP concentrations found in Lan-yang River could be regarded as the background levels of OCPs in Taiwan. 相似文献
104.
Zhenyu Tian Haifeng Li Huiting Xie Chen Tang Ying Han Mengjing Wang Wenbin Liu 《环境科学学报(英文版)》2014,26(10):2041-2047
Concentrations of Polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs) and polychlorinated biphenyls(PCBs) in soil samples from Tibetan Plateau were determined. The average concentration of total 2,3,7,8-PCDD/Fs was(2.30 ± 1.02) pg/g, and World Health Organization Toxicity Equivalency(WHO-TEQ) average concentration was(0.013 ± 0.010)pg WHO-TEQ/g. The average concentration of ∑PCBs(7 indicator PCB and 12 dioxin like-PCB congeners) was(16.2 ± 9.25) pg/g, and WHO-TEQ average concentration was 0.043 ±0.049 pg WHO-TEQ/g. Comparing to previous studies in similar environmental conditions,PCDD/Fs and PCBs in this study showed a relatively lower concentration. The altitude dependences of PCDD/Fs and PCBs were also studied. Total organic carbon(TOC) normalized concentrations presented a quadratic relation with the altitudes, and an inflection could be found on the parabola of the total concentrations and some congeners of high concentration.The concentrations decreased with altitudes below about 4500 m above sea level(a.s.l.), while they increased with altitudes above it. These phenomena indicate that cold condensation of PCDD/Fs and PCBs would happen above 4500 m a.s.l, on the Tibetan Plateau. 相似文献
105.
106.
Yang Zhang Zheng Peng Zhaomin Dong Mujie Wang Chen Jiang 《Frontiers of Environmental Science & Engineering》2022,16(12):152
107.
108.
Gerhard Lammel Jana Klánová Roman Prokeš Andreas Stohl 《Environmental pollution (Barking, Essex : 1987)》2009,157(12):3264-3271
On Zugspitze (2670 m a.s.l.), Alps, higher concentrations were observed during a winter than during a summer measurement campaign of PAHs, chlorobenzenes (43.6 vs. 2.0 pg m−3) and DDTs (3.7 vs. 1.2 pg m−3), while hexachlorocyclohexanes and PCBs were found at similar levels. The PCB, HCH and DDT levels are among the lowest ever reported from outside the Arctic. Mostly lower levels were found in samples collected in summer than in winter despite a significant boundary layer air influence, but no such influence on samples collected during the winter campaign. Boundary layer influence was quantified by Lagrangian particle dispersion model retroplume analyses. Photochemical lifetimes corresponding to kOH < 1.5 × 10−12 cm3 molec−1 s−1 are found for p,p′-DDT, kOH < 0.75 × 10−12 cm3 molec−1 s−1 for p,p′-DDE and kOH < 1.0 × 10−12 cm3 molec−1 s−1 for p,p′-DDD. 相似文献
109.
Wang X Wu J Hao Y Zhu B Shi W Hu G Han X Giesy JP Yu H 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2720-2725
Reproductive toxicity of organic extracts of the surface water from the Tai section of the Yangtze River was assessed by in vitro cytotoxity assays and selected persistent organic pollutants including PCBs, OCPs and PAHs were quantified by instrumental analysis. Eleven of the US EPA priority PAHs were detected. Individual PAHs were found to range from 0.7 to 20 ng/L. Concentrations of BaP did not exceed the national drinking water source quality standard of China. However, a 286-fold concentrated organic extract induced significant reproductive toxicity in adult male rats. The morphology of cells, MTT assay and LDH release assay were all affected by exposure to the organic extracts of water. The results of the reproductive toxicity indicated that PAHs posed the greatest risk of the chemicals studied. The compounds present in the water could be bioconcentrated and result in adverse effects. 相似文献
110.
For decades, toxaphene had been used as a major chloropesticide. Degradation of the multicomponent mixture in the environment was mainly reported to be due to anaerobic dechlorination and hydrodechlorination. Little was known about oxidative transformation processes and the potential hydroxylated metabolites were not available as standard compounds. For this reason we synthesized hydroxylated polychlorobornanes by the UV-induced photochlorination of 2-endo-bornyl acetate with sulfuryl chloride followed by hydrolysis of the acetate moiety. The released polychlorinated 2-endo-hydroxybornanes were slightly higher chlorinated the longer the reaction was maintained. After 8 h, the main products were pentachlorinated hydroxybornanes followed by hexa- and heptachlorinated homologues. Traces of octachlorinated hydroxybornanes were also observed. The GC/ECNI-MS spectra of the products were characterized by the molecular ions and the [M-Cl]− fragment ions. The molecular ions of the polychlorinated hydroxybornanes are isobaric with those of polychlorinated biphenyls. E.g. hexachlorohydroxybornanes (C10H12Cl6O) and hexachlorobiphenyls (C12H4Cl6) show the molecular ion at m/z 358. Based on fractionation experiments on silica with the synthesis products it might be possible that OH-CTTs if present in samples will elute into a more polar fraction usually discarded or not collected. Both problems might explain why these compounds have not been more frequently described in the scientific literature. 相似文献