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191.
The level of concentrations of polycyclic aromatic hydrocarbons (PAHs) in surface soils from petroleum handling facilities
(kerosene tank, generating plant, petrol stations, mechanic workshops, leaking pipeline and air port fuel dump) from Calabar
metropolis southeastern Nigeria was determined by gas chromatography/ mass spectrometry. The results show that total polycyclic
aromatic hydrocarbons (PAHs) varied from 1.80 to 334.43 mg/kg with a mean of 50.31 mg/kg. The lowest value of 1.80 mg/kg was
obtained from petrol station while the highest value of 334.43 mg/kg was obtained from facility characterised by petrol stations
and mechanic workshops. The ratio of phenanthrene/anthracene and fluoranthene/pyrene, varied from 0.43 to 27.72 and from 0.14
to 17.76 respectively. These ratios indicate various sources for the PAH. The two to three ring PAHs are the most abundant.
Based on the PAH ratios and content alone it is not possible to distinguish between contribution from motor vehicle exhaust,
gasoline spillage, used engine oil or petroleum production. However, considering the area of the study, it is very likely
that the major source of soil contamination is originating from petroleum product. 相似文献
192.
Oil spills due to oil pipelines is a very frequent problem in Mexico. Petroleos Mexicanos (PEMEX), very concerned with the
environmental agenda, has been developing inspection and correction plans for zones around oil pipelines pumping stations
and pipeline right-of-way. These stations are located at regular intervals of kilometres along the pipelines. In this study,
two sections of an oil pipeline and two pipeline pumping stations zones are characterized in terms of the presence of Total
Petroleum Hydrocarbons (TPHs) and Polycyclic Aromatic Hydrocarbons (PAHs). The study comprehends sampling of the areas, delimitation
of contamination in the vertical and horizontal extension, analysis of the sampled soils regarding TPHs content and, in some
cases, the 16 PAHs considered as priority by USEPA, calculation of areas and volumes contaminated (according to Mexican legislation,
specifically NOM-EM-138-ECOL-2002) and, finally, a proposal for the best remediation techniques suitable for the contamination
levels and the localization of contaminants. 相似文献
193.
Spatial and temporal patterns of metal mobilisation from former water-powered, Pb working sites in a suburban area of Sheffield (UK) were investigated. Twelve time-integrated mass flux samplers were strategically deployed over two contrasting campaign periods (summer and winter). Suspended sediment samples were characterised magnetically and subjected to metal analysis. Metal levels in the upper River Sheaf showed a marked spatial and temporal variability. Pb concentrations in particular were relatively high (maximum 2132 mg kg(-1)). Their distribution tended to reflect the historical contamination of the valley by 17th to 19th century industry, especially during summer high discharge conditions. The mean suspended sediment Pb concentration (803 mg kg(-1)) exceeds contamination guidelines. It is unclear whether ground remediation of one of the seven floodplain sites in the catchment has been successful. The river is still affected by the legacy of at least two other Pb working sites. 相似文献
194.
Culbertson JB Valiela I Olsen YS Reddy CM 《Environmental pollution (Barking, Essex : 1987)》2008,154(2):312-319
In September 1969, the Florida barge spilled 700,000 L of No. 2 fuel oil into the salt marsh sediments of Wild Harbor, MA. Today a substantial amount, approximately 100 kg, of moderately degraded petroleum remains within the sediment and along eroding creek banks. The ribbed mussels, Geukensia demissa, which inhabit the salt marsh creek bank, are exposed to the spilled oil. Examination of short-term exposure was done with transplantation of G. demissa from a control site, Great Sippewissett marsh, into Wild Harbor. We also examined the effects of long-term exposure with transplantation of mussels from Wild Harbor into Great Sippewissett. Both the short- and long-term exposure transplants exhibited slower growth rates, shorter mean shell lengths, lower condition indices, and decreased filtration rates. The results add new knowledge about long-term consequences of spilled oil, a dimension that should be included when assessing oil-impacted areas and developing management plans designed to restore, rehabilitate, or replace impacted areas. 相似文献
195.
Jacobsen CS van der Keur P Iversen BV Rosenberg P Barlebo HC Torp S Vosgerau H Juhler RK Ernstsen V Rasmussen J Brinch UC Jacobsen OH 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):794-802
Pesticide mineralization and sorption were determined in 75 soil samples from 15 individually drilled holes through the vadose zone along a 28 km long transect of the Danish outwash plain. Mineralization of the phenoxyacetic acid herbicide MCPA was high both in topsoils and in most subsoils, while metribuzine and methyltriazine-amine was always low. Organic matter and soil pH was shown to be responsible for sorption of MCPA and metribuzine in the topsoils. The sorption of methyltriazine-amine in topsoil was positively correlated with clay and negatively correlated with the pH of the soil. Sorption of glyphosate was tested also high in the subsoils. One-dimensional MACRO modeling of the concentration of MCPA, metribuzine and methyltriazine-amine at 2 m depth calculated that the average concentration of MCPA and methyltriazine-amine in the groundwater was below the administrative limit of 0.1 μg/l in all tested profiles while metribuzine always exceeded the 0.1 μg/l threshold value. 相似文献
196.
主成分分析法在三江交汇处水质分析中的应用 总被引:1,自引:0,他引:1
本文应用主成分分析法,利用三江交汇处的三个断面从1984年到1998年的监测资料对交汇处的水质做分析,分析前先对量化数据标准化处理,处理后提取主成分,并且计算其贡献率和累计贡献率,再由相应的特征向量得到主成分的线性表达式。结果表明:五项影响因素中,三个断面桔水期均受亚硝酸盐氮的影响比较大,丰水期和平水期均受悬浮物和化学需氧量的影响比较大。交汇前,小南门断面的水质综合污染最严重,凉姜沟断面的水质综合污染最轻;交汇后,三江口断面的水质在两者的缓冲下,水质综合污染居中。则说明主成分分析法为河流的综合治理提供了科学依据。 相似文献
197.
198.
199.
P. G. Bradley 《Resources Policy》1987,13(4)
The petroleum industry has traditionally generated substantial revenues for governments. Where governmental power is divided, as in federations like Canada and Australia, a junior level of government normally collects royalties while the senior level levies a variety of imposts (income tax, export duties, excises on production). The combination of recent sharp reductions in prices, more price volatility and an era of freer markets has subjected existing tax and royalty systems to severe strain and has shifted attention to the design of fiscal systems that are more profit- sensitive. For the royalty element, interest focuses on net value royalties (NVRs). This paper deals with the nature and problems of NVRs. It proceeds by looking first at the application of resource rent royalties in Australia. It then focuses on recent megaproject royalty arrangements in Alberta and evaluates the degree to which Alberta's current royalty system is profit- sensitive. Problems associated with NVRs are discussed in the fourth section; concluding remarks are made in the last section. 相似文献
200.
人类活动对土壤环境的影响及对策 总被引:2,自引:0,他引:2
人类不合理的开发行为给土壤环境带来了沉重的负面影响,主要表现为土壤沙化、土壤侵蚀、土壤盐渍化、土壤污染等。本文以此为出发点展开讨论,分析各种现象的成因,并提出相应对策。 相似文献