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排序方式: 共有367条查询结果,搜索用时 31 毫秒
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Plant uptake and dissipation of PBDEs in the soils of electronic waste recycling sites 总被引:4,自引:0,他引:4
Honglin HuangShuzhen Zhang Peter Christie 《Environmental pollution (Barking, Essex : 1987)》2011,159(1):238-243
Plant uptake and dissipation of weathered PBDEs in the soils of e-waste recycling sites were investigated in a greenhouse study. Eighteen PBDE congeners (tri- through deca-) were detected in the plant tissues. The proportion of lower brominated PBDEs (mono- through hexa-) in plant roots was higher than that in the soils. A concentration gradient was observed of PBDEs in plants with the highest concentrations in the roots followed by the stems and lowest in the leaves. Reduction rates of the total PBDEs in the soils ranged from 13.3 to 21.7% after plant harvest and lower brominated PBDEs were associated with a higher tendency to dissipate than the higher brominated PBDEs. This study provides the first evidence for plant uptake of weathered PBDEs in the soils of e-waste recycling sites and planting contributes to the removal of PBDEs in e-waste contaminated soils. 相似文献
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A hydroponic experiment was conducted to investigate the debrominated, hydroxylated and methoxylated metabolism of polybrominated diphenyl ethers (PBDEs, BDE-15, -28 and -47) in maize. A total of six debrominated metabolites (de-PBDEs), seven hydroxylated PBDEs (OH-PBDEs, including two unidentified OH-di-PBDEs and one unidentified OH-tri-PBDE) and four methoxylated PBDEs (MeO-PBDEs) were determined in the exposed plants. The metabolic products were detected in maize only after 12 h of exposure to the PBDEs. However, the concentration of each type of the metabolites (de-PBDEs, OH-PBDEs or MeO-PBDEs) decreased at the later exposure time, possibly due to further metabolism. The removal of a bromine atom or the introduction of a hydroxyl/methoxy group was easier at the ortho-positions on the biphenyl structure than at the para-positions. Concentration ratios of the total debrominated, hydroxylated or methoxylated metabolites to the parent congener (BDE-28 or -47) generally followed the order of leaves > stems ? roots, and MeO-PBDEs > de-PBDEs ? OH-PBDEs. These results suggest that metabolism occurred preferentially in leaves and stems than in roots. Less transformation and shorter elimination half-life of OH-PBDEs would contribute to the lower concentrations of OH-PBDEs than of de-PBDEs or MeO-PBDEs in maize. 相似文献
366.
株洲市区农业土壤中多环芳烃的分布特征研究 总被引:3,自引:1,他引:2
采集株洲市区农业土壤表层样品185个,用高效液相色谱法对16种多环芳烃(PAHs)进行检测结果表明,除萘外,其余15种PAHs均有不同程度的检出,以苯并[b]萤蒽、萤蒽和苯并菲等3或4环PAHs为主, ~5521μg/kg之间,平均280μg/kg.地域上,石峰区、芦淞区>天元区>荷塘区;从土地利用类型看,旱地>水田>林地.按Maliszewska-Kordybach土壤污染程度分级标准,株洲市区农业土壤总体上受到PAHs轻度污染,这些PAHs主要来源于工业生产、交通运输等过程中化石燃料的燃烧. 相似文献
367.
快速溶剂萃取-气相色谱/串联质谱法测定农作物中的有机氯农药 总被引:3,自引:0,他引:3
建立快速溶剂萃取,固相萃取柱净化,气相色谱/串联四极杆质谱检测分析农作物中23种有机氯农药残留的方法。以油菜为样品,加标浓度为5、10、25、50μg/kg时,平均回收率在72%~101%之间,相对标准偏差3%~14%(n=5)。8种农作物(莴笋、黄瓜、蒜苗、辣椒、油菜、茄子、玉米和水稻)加标浓度为25μg/kg时的平均回收率在71%~113%之间,相对标准偏差3%~16%(n=5)。方法检出限0.75~1.76μg/kg之间。 相似文献