The copper cycles of European countries

A comprehensive technological copper cycle treating a series of life stages (mining and processing, fabrication, utilization, and end of life) has been constructed for sixteen countries on the European continent for the year 1994. In this paper we draw on that information to present country-level copper cycles for a sampling of the countries. We then compare the countries on the basis of their relative and absolute copper production, import/export, usage, recycling, and losses to the environment, and go on to produce per capita assessments of flow and stock changes. Among the results of particular interest are: (1) country-level copper budgets possess features often different from the continental budgets of which they are a part. For example, Europe extracted only slightly more copper from mines than it deposited in landfills, while the mine to landfill flow ratio was about 11:1 in Poland and near zero in the United Kingdom; (2) Germany led all other countries in the group of sixteen in the absolute magnitude of every major copper flow (production, import, export, consumption, and waste generation, and in per capita flows of copper entering use and waste management), while the Benelux countries led all others in per capita flows for all other categories; (3) citizens of essentially all the countries discarded 1–3 kg Cu/year, mostly in obsolete electronics and end-of-life vehicles.     

Why recycle? A comparison of recycling motivations in four communities

Four Illinois communities with different sociode-mographic compositions and at various stages of planning for solid waste management were surveyed to determine the influence of sociodemographic variables and planning stages on the factors that motivate recycling behavior. A factor analysis of importance ratings of reasons for recycling and for not recycling yielded five factors interpreted as altruism, personal inconvenience, social influences, economic incentives, and household storage. The four communities were shown to be significantly different in multivariate analyses of the five motivational factors. However, attempts to explain these community differences with regression analyses, which predicted the motivational factors with dummy codes for planning stages, a measure of self-reported recycling behavior, and sociodemographic measures were unsatisfactory. Contrary to expectation, the solid waste management planning stages of the cities (curbside pickup, recycling dropoff center, and planning in progress) contributed only very slightly to the prediction of motivational factors for recycling. Community differences were better explained by different underlying motivational structures among the four communities. Altruistic reasons for recycling (e.g., conserving resources) composed the only factor which was similar across the four communities. This factor was also perceived to be the most important reason for recycling by respondents from all four communities. The results of the study supported the notion that convenient, voluntary recycling programs that rely on environmental concern and conscience for motivation are useful approaches to reducing waste.     

End-of-life vehicle recycling and automobile shredder residue management in Japan

The Japanese Government introduced the Law on Recycling of End-of-Life Vehicles (ELV Recycling Law) in 2002. This law requires manufacturers to retrieve chlorofluorocarbons (CFCs), airbags, and automobile shredder residue (ASR) from ELVs and to properly recycle the remaining materials. This framework is compared with European ELV directives. Pilot-scale incineration plant testing has revealed a greater formation of by-product persistent organic pollutants (POPs) during the primary combustion of ASR compared to normal municipal solid waste. This may be attributed to the abundance of chlorine, Cu, and Fe in ASR, as Cu and Fe have been found to catalyze the formation of POPs under certain conditions. However, most by-product POPs were destroyed by the secondary combustion, and almost all were removed after flue gas treatment. The direct melting system is a shaft-type gasification and melting technology that has proved effective in many municipal solid waste applications. This system can be applied to ASR recycling for effective decomposition of brominated flame retardants and polybrominated dioxins.     

Waste minimization study in a solvent-based paint manufacturing plant

Solvent-based paint manufacturing plants produce significant quantities of hazardous waste, which must be properly treated before it can be disposed. Since the cost for treating this waste is high, reducing the quantity of waste has become a crucial issue in this industry.Waste minimization options are beneficial for the owner of the plant as well as for the environment. The quantity of hazardous waste can be minimized by changing the plant's technology or by substituting hazardous substances, which are used in the paint manufacturing process, with environmentally friendly ones. Furthermore, separating the various waste streams makes it easier to recover raw materials and enhances the possibility of their reuse within the production process. This will decrease operational costs for the plant.This paper presents a case study of waste minimization in a solvent-based paint manufacturing plant. Source reduction, recovery, and recycling methods are taken into consideration. Its aim is to develop an understanding of the facility's waste generating processes, to suggest ways to reduce the waste production, and finally to select an appropriate waste minimization option to suggest to the plant. Some of the suggested methods are currently being practiced while others are at initial stage of development.     

Air emissions from pavement layers composed of varying rates of reclaimed asphalt

An experimental study of road building and recycling of used pavement has been conducted within the framework of a Life Cycle Analysis. Four equivalent asphalt concretes made with different recycling rates have been investigated during road construction. Airborne emissions, pollutant release over time and odor production related to asphalt laying have all been determined and compared among the various recycling rates. All of the results (VOC, PAH and odors), expressed in terms of concentrations and fluxes, exhibit quite monotonic variations with respect to the recycling rate. These results, however, did not reveal the same trend as a function of the recycling rate (increases or decreases), depending on the selected target parameter (VOC or PAH). Indicators have been proposed for a discussion of results that take into account: (i) raw material emissions with respect to the reference defined in the case of pavement without reclaimed asphalt; and (ii) emissions in each case from all material production sources.     

Exergy losses during recycling and the resource efficiency of product systems

Recycling materials have always some degree of contamination. The presence of contaminations in the recycling streams causes a shift in the original composition of the materials to recycle. As a consequence, their quality may decrease with each recycling step. Additionally, lower quality resources are produced from resource streams that had initially a higher quality. These quality losses cannot be measured by mass balances, as the quality degradation cannot be translated by mass measures alone. To account all losses caused by recycling contaminations, all downstream recycling processes required to bring the materials back to the resource cycles must be included. This article describes a method to calculate the exergy content and exergy losses of metal solutions during recovery and recycling. The losses attributed to recycling, namely the material losses, the contamination losses with other metals, and the consequent need for dilution can be used as indicators of the quality loss of materials and of the efficiency of resource use in product systems. Therefore, exergy is proposed here as a measure of the efficiency of resources use.     

Electrochemical reduction in vat dyeing: greener chemistry replaces traditional processes

In application of vat dyes the substitution of non-regenerable reducing agents such as Na₂S₂O₄ by cathodically regenerable reducing agents offers great ecological advantages. In a demonstration project a 45 A multi-cathode electrolyser successfully was coupled to a dyeing apparatus for package dyeing with a capacity of 1–10 kg material. Iron-complexes with triethanolamine and Na-d-gluconate were used as cathodically regenerable reducing agents. Dyebath regeneration was performed by ultrafiltration. Substantial reduction in chemical consumption and reduction in wastewater volume, released from the dyeing process could be demonstrated. Quality of dyeings was assessed with regard to levelness and iron content analysed in the dyed samples.     

An illicit economy: scavenging and recycling of medical waste

This paper discusses a significant illicit economy, including black and grey aspects, associated with medical waste scavenging and recycling in a megacity, considering hazards to the specific group involved in scavenging as well as hazards to the general population of city dwellers. Data were collected in Dhaka, Bangladesh, using a variety of techniques based on formal representative sampling for fixed populations (such as recycling operatives) and adaptive sampling for roaming populations (such as scavengers). Extremely hazardous items (including date expired medicines, used syringes, knives, blades and saline bags) were scavenged, repackaged and resold to the community. Some HCE employees were also observed to sell hazardous items directly to scavengers, and both employees and scavengers were observed to supply contaminated items to an informal plastics recycling industry. This trade was made possible by the absence of segregation, secure storage and proper disposal of medical waste. Corruption, a lack of accountability and individual responsibility were also found to be contributors. In most cases the individuals involved with these activities did not understand the risks. Although motivation was often for personal gain or in support of substance abuse, participants sometimes felt that they were providing a useful service to the community.     

Reuse of ornamental rock-cutting waste in aluminous porcelain

Large amounts of solid wastes are discarded in the ornamental rocks industry. This work investigates the incorporation of ornamental rock-cutting waste as a raw material into an aluminous porcelain body, replacing natural feldspar material by up to 35 wt.%. Formulations containing rock-cutting waste were pressed and sintered at 1350 °C. The porcelain pieces were tested to determine their properties (linear shrinkage, water absorption, apparent density, mechanical strength, and electrical resistivity). Development of the microstructure was followed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses. The results showed that ornamental rock-cutting waste could be used in aluminous porcelains, in the range up to 10 wt.%, as a partial replacement for traditional flux material, resulting in a valid route for management of this abundant waste.     

Global anthropogenic tellurium cycles for 1940–2010

Tellurium is increasingly used in solar photovoltaics in the form of cadmium–telluride (CdTe) thin films. There are concerns regarding whether tellurium availability could be a constraint on large-scale deployment of CdTe photovoltaics. The present work brings a new perspective to the discussion of tellurium availability by providing the first extant global tellurium cycles constructed with material flow analysis principles. The tellurium cycles, for 1940–2010, present information on the production, fabrication and manufacturing, use, and resource management stages during this period. The results of the analysis show that during 1940–2010 approximately 11 Gg of refined tellurium was produced. This represents about 4.5% of the tellurium that was extracted from the ground during copper mining. Almost 80% of the refined tellurium, 8.5 Gg, was dissipated into end-uses such as metallurgical additives to iron, steel, and nonferrous metals, and thereby lost to potential reuse. As of 2010, the in-use tellurium stock is estimated at 1.1 Gg, which mainly accumulated after 1990s with the increasing tellurium use in electronics, specifically photovoltaic and thermoelectric devices. Because tellurium is a byproduct of copper ores, its supply can be enhanced by more attention to recovery during processing of the copper parent. Tellurium can also, in principle, be recovered from end-of-life electronics; the increasing in-use stock indicates the potential for significant end-of-life recycling in the coming decades.