A quantitative estimate of potential aluminium recovery from incineration bottom ashes

The recovery of ferrous and non ferrous metals from the bottom ashes is a common practice in the most part of Europe, both for the environmental advantages of their recycle and to avoid problems of swelling and expansion that metals can cause when bottom ashes are reused in concrete production or in road construction. This paper focuses on metal recovery from bottom ashes produced in Municipal Solid Waste (MSW) incinerators, with a particular focus on aluminium. A forecasting model was developed in order to evaluate the quantity of aluminium scraps recoverable from the bottom ashes. The model was applied to the Italian situation but its validity can be extended to other countries. Focusing on Italy, by applying conventional technologies for the separation of non-ferrous metals, the amount of aluminium potentially recoverable from bottom ashes is estimated in the range from 16,500 to 21,000 tonnes at the year 2015, and from 19,000 to 28,500 tonnes at 2020.     

Overview of non-hazardous solid waste in the small island state of Mauritius

In Mauritius, solid waste disposal has been a cause for concern since the 1980s. Currently, there is no segregation of waste and some 1200 tonnes of solid waste are generated daily by the 1.24 million inhabitants of the island. As processes such as recycling and composting are still in their infancy stage, most of the waste generated have to be disposed of at the sole landfill. The solid waste management practices of 1980s and early 1990s are no longer compatible with the changing composition and quantity of wastes now generated. As a result, there is an urgency to review the whole waste management system and come forward with sustainable solutions.This paper presents an overview of the disposal of non-hazardous solid waste in Mauritius and provides recommendations for improving the current disposal system.     

The influence of collection facility attributes on household collection rates of electronic waste: The case of televisions and computer monitors

In the US, household electronic waste collected for recycling is primarily by voluntary drop-off at designated collection facilities. This study examines the influence of specific collection facility attributes (recycling fees charged, number of days open, and driving distance) on the household collection rate of e-waste in the US state of Maine. Data were collected for household computer monitor and television collection for 92 municipal waste transfer facilities representing 30% of the state's population for one year. Results suggest that recycling fees are negatively correlated with the number of televisions and computer monitors collected; furthermore, the more frequently facilities were open, the more televisions and computer monitors were collected per capita. The distance from the facility had no correlation, which prompted an analysis of whether the existence of a curbside collection system in the municipality was influential. Results show a negative correlation between computer monitor and television collection and a municipality having recycling (but not e-waste) curbside collection. Based on the results of this study, policymakers may be able to increase the collection rate of household e-waste by eliminating or lowering recycling fees, expanding collection days and hours to increase convenience, and/or considering curbside collection of e-waste.     

A mechanical pre-treatment process for the valorization of useful fractions from spent batteries

In this paper the authors propose a full-scale plant aimed to pre-treat spent batteries in order to obtain cleaned useful fractions (magnetic and non-magnetic metals, paper, plastic, a fine-sized material made of a metal-carbon mixture). The treating process was designed after having analyzed and tested a representative sample coming from the whole amount of spent batteries collected in 1 month by the public service in and around Turin. The analyses performed on the sample allowed the authors to determine its in-percentage composition in term of type of batteries: 60-70% b.w. (by weight) alkaline, 25-30% b.w. Zn-C and 5-10% b.w. other types. For each type, the composition in term of size (AAA or LR03; AA or LR6; C or LR14; D or LR20; 9 V or 6F22A; 4.5 V or 3R12A) has also been determined.The treatment for the recovery of secondary raw materials foresees the following phases:

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separation of useful types/sizes of exhaust batteries to undergo further treatments by means of a first sieving process;

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liberation of the single components taking advantage of a crushing operation;

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separation of a fine-sized material (to subject to pyro or hydro metallurgic recovery) from a coarse-sized material (to send to secondary smelt foundries and incinerators) by means of a second sieving phase.

On the basis of the results obtained from the crushing/sieving laboratory tests and the chemical characterization, a full-scale plant able to treat about 76,000 t/y of spent batteries has been designed. The cost analysis performed on the proposed treatment plant has given back a unit pre-treatment cost equal to 3€ per ton of processed spent batteries.     

Building partnerships — the Ohio Materials Exchange

This paper discusses a method by which individuals working in government, private business, not-for-profit and educational organizations developed a collaborative statewide program involving the exchange of materials from manufacturers, commercial business and not-for-profit organizations in Ohio.     

A rationale for recycling

The decision as to whether to recycle discarded objects or not has traditionally been made on a simple financial basis. However, over the last few years a popular movement has sprung up which regards recycling as a good in itself, and this movement finds itself at odds with the present financial basis for recycling. In this paper a rationale for recycling is worked out in an attempt to resolve this conflict. It is concluded that the normal market signals do not provide a proper basis for recycling decisions and that this market failure must be corrected by government intervention. However, this intervention should not take the form of uncritical support for recycling. Rather the societal objectives of individual recycling proposals should be identified and the proposal should then be evaluated in terms of whether it would achieve these objectives more effectively than some alternative action.     

Cadmium—Towards a rational use of a toxic element

Because of its toxicity, cadmium creates an environmental problem as well as a health hazard for exposed workers. Most cadmium emissions arise from the intentional use of the element. It is therefore mandatory to reduce cadmium consumption to the lowest possible level. Cadmium pigments, mainly used in plastic processing, can be replaced in all applications where the processing temperature does not exceed 300°C. Newly developed polyvinyl chloride stabilizers promise to be an excellent substitute for cadmium stabilizers in even the most demanding applications. Cadmium plating, still extensively used in the United States and the West Germany, has been virtually abandoned in Japan. Improved lead acid batteries are replacing vented nickel cadmium batteries because of their cost effectiveness. While in these applications cadmium use is declining, more and more cadmium is needed for the manufacturing of sealed nickel cadmium batteries. These relatively small electrochemical cells are used mainly by individual consumers. Here cadmium can only be replaced in some marginal applications. The high cadmium content of these batteries (up to 22%) makes them a good candidate for recycling of the heavy metal.     

循环经济视野下过度包装的立法思考

通过对国外包装立法的考察比较,提出限制过度包装必须由非理性的利益冲动行为回归到理智的法治轨道上来.应以促进循环经济发展,加快建设资源节约型和环境友好型社会,实现可持续发展为立法的终极价值目标.     

Effects of organic-waste compost addition on sesame growth, yield and chemical composition

The agronomic aspects of some organic waste compost applications to sesame plants grown on sandy soil were investigated. Different rates and combinations from biosolids (BS), municipal solid waste (MSW) and water hyacinth (W) compost, incorporated with or without shale deposits (tafla) at 8%, were used to treat the sandy soil. Dry matter accumulation was used as an indicator of the effectiveness of such treatments on plant growth. In addition, the contents of nitrogen-phosphorus-potassium, chlorophyll, total protein, oil and carbohydrates were determined in plant tissue as physiological parameters. Heavy metal contents (Fe, Mn, Zn, Cu, Co, Ni, Cd, Pb) in seeds samples were determined. Results indicated that all compost treatments stimulated sesame growth and enhanced its pigment, carbohydrate and mineral contents. While the chemical constituents of sesame seeds (oil, carbohydrate and total protein) showed no variation when expressed as relative data (%), the absolute results expressed as gram per plant exhibited significant increases. The maximum levels (μg g⁻¹) of tested metals in seeds did not exceed 226 Fe, 12.5 Mn, 81. 7 Zn, 23.7 Cu, 3.8 Co, 24.6 Ni, 5.4 Pb and 1.72 Cd, which are below the reported concentrations at which phytotoxicity could occur.     

鞍山市电厂燃煤锅炉灰渣的资源化利用途径

在简要介绍机电厂产生灰渣的机理、旋风锅炉除尘固硫工艺流程以及国内锅炉灰渣的利用现状的基础上，以鞍山热电新材股份有限公司灰渣利用现状为例介绍河分析了燃煤锅炉灰渣的资源化利用情况。按该厂炉渣产生量3．5t/a估算循环利用年均获利可达62．5万元，其经济效益显著。