某城市湖泊中磷的循环特征及富营养化发生潜势

通过对浙江省临海市东湖水体磷元素的输入与输出途径与通量、磷元素在湖泊环境中的循环特征以及磷循环对水温上升的响应分析,并基于对该水体从2000年开始隔年进行各参数的观测,表明2000年以来磷输入年平均增量为0.007～0.009mg/L,水中叶绿素a平均年增0.14～0.56μg/L,透明度年平均下降0.38～0.49m,溶解氧年平均下降0.21～0.71mg/L.并依此建立了反映湖泊富营养化发生潜势的这些主要代表性参数与湖水中总磷含量之间的相关关系,揭示了可以通过从磷物质单因子的变化预测所引起的其它因子变化之间的关系来综合判断湖泊的营养状态,从而为减少湖泊富营养化的发生、提高湖泊水质提供科学依据.     

Denitrification and the controlling factors in Yunnan Plateau Lakes (China): Exploring the role of enhanced internal nitrogen cycling by algal blooms

Denitrification plays an important role in nitrogen(N) removal in freshwater ecosystems.This internal process regulates the fluctuations of N concentration, especially for lakes with high nutrients concentrations and long residence time. Lakes in Yunnan plateau(southwestern China) provide typical cases, while studies in this region have been rare.Therefore, we studied denitrification of two lakes(Lake Dianchi in hypereutrophic state and Lake Erhai in mesotrophic) in this region. We used acetylene inhibition technique to quantify potential denitrification rate(PDR) of these lakes in April and August, 2015 and 2016. PDR of the sediments ranged 0–1.21 μmol/(N·m~2·hr), and that of overlying water ranged 0–0.24 μmol/(N·L·hr). Then, we used Least Angle Regression to determine the controlling factors for denitrification. Nutrients controlled PDR from two aspects: providing essential nitrogen sources; and affecting the richness and metabolism of denitrifying bacteria. In April, both aspects limited PDR; while only nitrogen sources limited PDR in August, due to depleted nitrate and enhanced denitrifying bacteria activity. Ammonia was most significant to denitrification, indicating that nitrate from nitrification transported to the bottom of wellmixed lake provide major N source by denitrification. The high PDR and low nitrate concentrate in August were evidence of an enhanced internal N cycling by algal blooms.     

伊乐藻和氮循环菌技术对太湖氮素吸收和反硝化的影响

从太湖梅梁湾采集无扰动泥芯样,分别添加固定化氮循环细菌、水生植物伊乐藻建立室内微宇宙,模拟生态修复,探讨不同修复处理下,硝氮的去除机制.采用15N标记结合同位素配对技术测定了各生态模拟柱中的反硝化速率和植物吸收速率.结果表明,不同处理的实验柱反硝化速率差异明显,同时添加了水生植物和固定化氮循环细菌的实验柱反硝化速率最高,为99.35μmol·(m2·h)-1,植物氮吸收速率为36.55μg·(m2·h)-1.沉水植物伊乐藻在自身吸收氮素的同时也提高了耦合硝化反硝化的作用.与植物吸收相比,反硝化过程是主要的氮去除途径.沉水植物与固定化氮循环菌组合生态修复技术促进了湖泊水体氮素的脱除,起到了净化作用.     

森林生态系统在碳循环中的作用

描述了森林生态系统的碳循环及其在全球碳循环中的作用，说明了森林生态系统在碳循环中的作用主要取决于森林生态系统的生物量、林产品、植物枯枝落叶和根系碎屑以及森林土壤。最后，阐明了中国森林生态系统碳循环的研究现状和趋势。     

Investigation of adsorption/desorption behavior of Cr(VI) at the presence of inorganic and organic substance in membrane capacitive deionization (MCDI)

The adsorption and desorption behavior of Cr(VI) in membrane capacitive deionization (MCDI) was investigated systematically in the presence of bovine serum albumin (BSA) and KCl with different concentrations, respectively. Results revealed that Cr(VI) absorption was enhanced and the adsorption amount for Cr(VI) increased from 155.7 to 190.8?mg/g when KCl concentration increased from 100 to 200?mg/L in the adsorption process, which was attributed to the stronger driving force. However, the adsorption amount sharply decreased to 90.2?mg/g when KCl concentration reached up to 1000?mg/L suggesting the negative effect for Cr(VI) removal that high KCl concentration had. As for the effect of BSA on ion adsorption, the amount for Cr (VI) significantly declined to 78.3?mg/g and pH was found to be an important factor contributing to this significant reduction. Then, the desorption performance was also conducted and it was obtained that the presence of KCl had negligible effect on Cr(VI) desorption, while promoted by the addition of BSA. The incomplete desorption was obtained and the residual chromium ions onto the electrode after desorption was detected via energy-dispersive X-ray spectroscopy (EDS). Based on above analysis, the enhanced removal mechanism for Cr(VI) in MCDI was found to be consisted of ion adsorption onto electrode surface, the redox reaction of Cr(VI) into Cr(III) and precipitation, which was demonstrated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM).     

Experimental study and steady-state simulation of biogeochemical processes in laboratory columns with aquifer material

Packed bed laboratory column experiments were performed to simulate the biogeochemical processes resulting from microbially catalyzed oxidation of organic matter. These included aerobic respiration, denitrification, and Mn(IV), Fe(III) and SO(4) reduction processes. The effects of these reactions on the aqueous- and solid-phase geochemistry of the aquifer material were closely examined. The data were used to model the development of alkalinity and pH along the column. To study the independent development of Fe(III)- and SO(4)-reducing environments, two columns were used. One of the columns (column 1) contained small enough concentrations of SO(4) in the influent to render the reduction of this species unimportant to the geochemical processes in the column.The rate of microbially catalyzed reduction of Mn(IV) changed with time as evidenced by the variations in the initial rate of Mn(II) production at the head of the column. The concentration of Mn in both columns was controlled by the solubility of rhodochrosite (MnCO(3(S))).In the column where significant SO(4) reduction took place (column 2), the concentration of dissolved Fe(II) was controlled by the solubility of FeS. In column 1, where SO(4) reduction was not important, maximum dissolved Fe(II) concentrations were controlled by the solubility of siderite (FeCO(3(S))). Comparison of solid-phase and aqueous-phase data suggests that nearly 20% of the produced Fe(II) precipitates as siderite in column 1. The solid-phase analysis also indicates that during the course of experiment, approximately 20% of the total Fe(III) hydroxides and more than 70% of the amorphous Fe(III) hydroxides were reduced by dissimilatory iron reduction.The most important sink for dissolved S(-II) produced by the enzymatic reduction of SO(4) was its direct reaction with solid-phase Fe(III) hydroxides leading initially to the formation of FeS. Compared to this pathway, precipitation as FeS did not constitute an important sink for S(-II) in column 2. In this column, the total reacted S(-II) estimated from the concentration of dissolved sulfur species was in good agreement with the produced Cr(II)-reducible sulfur in the solid phase. Solid-phase analysis of the sulfur species indicated that up to half of the originally produced FeS may have possibly transformed to FeS(2).     

氧化还原修复重金属污染土壤的文献计量学分析

基于Web of Science和中国知网(CNKI)的数据源,选择对应数据库、设定年限,检索相关文献和专利,运用文献计量学方法,并借助Origin、Excel等绘图制表工具对数据结果进行了统计、分析和对比,比较直观地展现出重金属污染土壤氧化还原修复技术的总体情况、国内外发展现状和趋势、国内外发展差距,并从关键词的发展演替角度分析研究热点与方向,为氧化还原修复技术相关学科发展与研究等提供决策参考。     

RESEARCH: Issues Related to Greenhouse Effect,Productivity Modeling,and Nutrient Cycling: A Case Study of Indian Wetlands

/ Models available in the literature on nutrient uptake, lightavailability, and chlorophyll growth have been suitably modified andintegrated through the computer program CHLORF (written in "C"language), which has the advantage of being amenable to simulation undervarious combinations of input variables. The model has been used forsensitivity analysis in order to identify the most sensitive set ofparameters whose control can form an appropriate basis for evolving pragmaticmanagement strategies. In addition, greenhouse mitigation potential has beencomputed in terms of assimilation of carbon dioxide for a case study ofIndian wetlands.KEY WORDS: Wetland; Nutrient cycling; Modeling; Greenhouse effect     

内循环三相流化床流体动力学性质的初步研究

研究了内循环三相流化床流体动力学的一些性质，认为随着进气流量的增大，氧的体积传递系数、气含率增加，混合时间与循环时间则减小。而随着载体的加入量增大，气含率、氧传递系数、循环时间和混合时间均有减小的趋势。根据实验结果确定载体投加量为6％，相应的进气量控制在0．75－1Nm^3/h之间。     

Nutrient cycling characteristics of Quercus acutissima and Pinus massoniana mixed forest in the Three-Gorge Reservoir area, China

The cycling characteristics of nitrogen(N), phosphorus(P) and potassium(K) of the Quercus acutissima and Pinus massoniana mixed forest, which is the most common forest type in the Three Gorge Reservoir areas in China, were systematically analyzed. The results showed that N, P and K accumulated in the plant pool and in the litter pool, while total N, P, and K were deficient in the soil pool and in the forest systems. Contents of N in the soil of depth 20-40 cm were the key factor limiting growth of trees. The biological outside cycling coefficients were 8.78, 72.5 and 11.7 times of inside cycling coefficients of N, P and K, respectively. 33.92, 10.26 and 15.88 kg of N, P and K return to the litter pool from branches, leaves and throughfall per year, but, 14.31, 1.32 and 10.48 kg of N, P and K return to the soil from litter pool per year respectively. It is clear that 58% of N, 87% of P, and 34% of K are lost by surface runoff per year. 5.49%, 1.30%, and 8.34% of N, P and K withdraw from leaves to branches, 4.99%, 1.99% and 7.30% of N, P and K withdraw from branches to trunks per year,respectively.