青岛市区春夏季大气能见度与颗粒物的关系

利用青岛市灰霾综合观测站2012年3月2日-2012年6月7日期间的监测数据,分析了青岛市区大气能见度与不同粒径颗粒物质量浓度的日变化特征,比较了各级别大气能见度下不同粒径颗粒物质量浓度及所占比例的相关性,研究了相对湿度对大气能见度和颗粒物质量浓度相关性的影响.结果表明,监测时段大气能见度与颗粒物质量浓度呈现较好的负相关,每天大气能见度最低值出现在早晨07:00--09:00;剔除相对湿度高于90％的前提下,PM2.5是影响大气能见度的主要因子,随着其在PM1o中所占比例上升,大气能见度级别不断下降,相关系数为-0.84;不同相对湿度区间下,PM2.5对大气能见度的影响最明显,其中,相对湿度为60％ ～ 70％,大气能见度与颗粒物质量浓度之间的相关性最好.     

加轴压卸围压下含瓦斯煤岩损伤变形的能量演化机制

采动影响下含瓦斯煤岩的损伤变形是一个极其复杂的非线性过程,单纯依靠传统经典弹塑性力学无法准确分析其破坏机理。针对此情况,通过试验研究了不同初始围压条件下含瓦斯煤岩的损伤变形特征,并分析了损伤变形与能量演化规律之间的内在联系。研究表明:初始围压越高,煤样破坏时强度越大,脆性破坏特征越明显,瓦斯流量急剧增加幅度越大,煤样破坏时积累的总能量和弹性应变能越多,且初始围压与弹性能之间满足对数函数关系。采用累积耗散能定义了煤岩损伤变量,并分析了不同阶段损伤与渗透率之间的演化关系。     

几种腐殖填料生物滤池COD去除效能比较研究

分别采用腐殖垃圾、泥炭、煤炭等腐殖填料及河沙构筑生物滤池,处理模拟废水,比较研究其COD去除效能及降解特征,为工艺填料改性提供理论依据。几种填料的扫描电镜分析图显示腐殖垃圾及泥炭以团聚体三维空间结构为主;煤炭与河沙表面粗糙程度较小,且主要由颗粒状物质构成。稀释平板涂布法分离出各生物滤池中发挥主要作用的微生物共3种,各系统菌落数量有差异,但种类相同。3种腐殖填料生物滤池在进水有机物浓度为500 mg/L及1000 mg/L时均有较理想的有机物去除效率。3种腐殖填料生物滤池中泥炭构筑的腐殖填料生物滤池有机物比降解速率最小,因而微生物比增长速率最小,微生物增长和自身氧化最易趋向于动态平衡,对应的饱和水力渗透系数最大,滤池最不易发生堵塞,最有利于腐殖填料生物滤池长期稳定运行,证明泥炭是一种优良的生物介质。     

Comparing the sensitivity of soil invertebrates to pesticides with that of Eisenia fetida

The sole routine testing of the standard earthworm Eisenia fetida for the terrestrial risk assessment of pesticides has been under much debate since other soil invertebrates may be more sensitive than this standard test species. However, the very low availability of laboratory toxicity data for taxa other than E. fetida has greatly hampered sensitivity comparisons. In the present study, the relative tolerance (T_rel) approach was used to enable comparing toxicity thresholds obtained from the US-EPA ECOTOX database, for main terrestrial taxonomic groups and pesticidal types of action (insecticides, fungicides, herbicides, and other) separately. Analyses confirmed previously reported lower and higher sensitivity of collembolans to fungicides and insecticides, respectively. However, various other discrepancies in susceptibility relative to E. fetida were encountered as indicated by species sensitivity distributions and/or calculated 95% confidence intervals of T_rel values. Arachnids and isopods were found to be more sensitive to insecticides, and nematodes to fungicides, as compared to E. fetida. Implications of study findings for the terrestrial risk assessment of pesticides are discussed.     

Polymer Barrier Films

Many polymers such as polyolefins (polyethylene, polypropylene), poly(vinyl chloride), aliphatic polyamides, poly(ethylene terephthalate), polycarbonate, and others are used as protective barrier films against the mass transport of small molecules of gases, vapors, and liquids (known as diffusates, permeants) in different applications. The barrier properties depend on the polymer characteristics such as solubility, diffusion, permeability, and others, the nature of the fluid, temperature, and other factors. Mainly polymer barrier film application in packaging, construction, and agriculture are discussed.     

Correlation of indoor radon concentration to commonly available geologic data

Over the last several years, the inhalation of decay products coming from radon-222 has become a national health concern. It is estimated that somewhere between 16,000 and 20,000 people die annually in the United States from lung cancer due to exposure to these decay products. Nationwide, 95% of all homes have not been tested for radon, and so it would seem that any methodology that could give a general idea of indoor radon concentrations (without actually testing the house itself) might be useful. While not intended to replace a radon test, which is both simple and inexpensive, our project attempts to predict indoor radon concentrations based on easily obtainable information from Soil Conservation Service county soil surveys and US Geological Survey surficial geology maps. We have chosen four parameters: soil permeability, surficial geology, soil shrink-swell potential, and distance to the nearest geologic fault. Of these four variables, surficial geology and distance to fault correlated well to winter indoor radon concentrations as measured by short-term (48-h) tests. While it is understood that there are limits to this methodology, primarily because of map scale problems, the correlations mentioned above were very strong and suggest further study would be useful.     

Application of Multiattribute Decision-Making Methods for the Determination of Relative Significance Factor of Impact Categories

A relative significance factor (f _i ) of an impact category is the external weight of the impact category. The objective of this study is to propose a systematic and easy-to-use method for the determination of f _i . Multiattribute decision-making (MADM) methods including the analytical hierarchy process (AHP), the rank-order centroid method, and the fuzzy method were evaluated for this purpose. The results and practical aspects of using the three methods are compared. Each method shows the same trend, with minor differences in the value of f _i . Thus, all three methods can be applied to the determination of f _i . The rank order centroid method reduces the number of pairwise comparisons by placing the alternatives in order, although it has inherent weakness over the fuzzy method in expressing the degree of vagueness associated with assigning weights to criteria and alternatives. The rank order centroid method is considered a practical method for the determination of f _i because it is easier and simpler to use compared to the AHP and the fuzzy method.     

“两带”渗透率分布模型应用及渗透率规律研究*

为了研究覆岩破坏后形成“两带”的渗透率分布规律,根据理论推导应力-应变曲线以及采空区材料力学参数公式,建立“两带”渗透率分布模型,采用COMSOL软件分别对垮落带的渗透率分布和断裂带渗透率分布进行数值模拟。研究结果表明:垮落带渗透率呈“椭圆”分布,渗透率最大可达到1.07×10-6 m2,最小可达到1.5×10-8 m2;随着高度的增加,采空区两侧的渗透率变化幅度增加,中部的渗透率变化值较小。断裂带渗透率呈“铲状”分布,靠近工作面区域渗透率最大,断裂带的渗透率在上下隅角处最大可达到1.8×10-10 m2,垂直方向上随着高度的增加渗透率减小。研究结果可为西部典型浅埋煤层安全高效开采提供现场指导作用。     

Wall losses of oxygenated volatile organic compounds from oxidation of toluene: Effects of chamber volume and relative humidity

Vapor wall losses can affect the yields of secondary organic aerosol. The effects of surface-to-volume (S/V) ratio and relative humidity (RH) on the vapor-wall interactions were investigated in this study. The oxygenated volatile organic compounds (OVOCs) were generated from toluene-H₂O₂ irradiations. The average gas to wall loss rate constant (k_gw) of OVOCs in a 400 L reactor (S/V = 7.5 m⁻¹) is 2.47 (2.41 under humid conditions) times higher than that in a 5000 L reactor (S/V = 3.6 m⁻¹) under dry conditions. In contrast, the average desorption rate constant (k_wg) of OVOCs in 400 L reactor is only 1.37 (1.20 under humid conditions) times higher than that in 5000 L reactor under dry conditions. It shows that increasing the S/V ratio can promote the wall losses of OVOCs. By contrast, the RH effect on k_gw is not prominent. The average k_gw value under humid conditions is almost the same as under dry conditions in the 400 L (5000 L) reactor. However, increasing RH can decrease the desorption rates. The average k_wg value under dry conditions is 1.45 (1.27) times higher than that under humid conditions in the 400 L (5000 L) reactor. The high RH can increase the partitioning equilibrium timescales and enhance the wall losses of OVOCs.     

“固化赤泥-人工膜”复合防渗材料研究

赤泥本身具有良好的防渗性能,加入石灰作为激发剂,更可提高其防渗性。根据《土工合成材料测试手册》和GB/T 50123—1999《土工试验方法标准》进行渗透试验,结果表明:室内试验在赤泥中加入8%石灰,并夹一层人工防渗膜形成的复合防渗材料,在固化28 d后,其渗透系数可达(7.3～7.4)×10-9 cm/s。在工业试验中,夹入不同厚度和质地的人工防渗膜的石灰(8%)固化赤泥,渗透系数可达到6.32×10-9～1.89×10-7 cm/s。研究成果在中原某铝厂赤泥堆场防渗工程中得到了应用。