全文获取类型
收费全文 | 651篇 |
免费 | 91篇 |
国内免费 | 276篇 |
专业分类
安全科学 | 96篇 |
废物处理 | 6篇 |
环保管理 | 60篇 |
综合类 | 398篇 |
基础理论 | 206篇 |
污染及防治 | 161篇 |
评价与监测 | 50篇 |
社会与环境 | 29篇 |
灾害及防治 | 12篇 |
出版年
2024年 | 6篇 |
2023年 | 23篇 |
2022年 | 34篇 |
2021年 | 29篇 |
2020年 | 35篇 |
2019年 | 39篇 |
2018年 | 45篇 |
2017年 | 59篇 |
2016年 | 47篇 |
2015年 | 55篇 |
2014年 | 36篇 |
2013年 | 122篇 |
2012年 | 68篇 |
2011年 | 81篇 |
2010年 | 35篇 |
2009年 | 45篇 |
2008年 | 32篇 |
2007年 | 40篇 |
2006年 | 34篇 |
2005年 | 27篇 |
2004年 | 15篇 |
2003年 | 20篇 |
2002年 | 16篇 |
2001年 | 14篇 |
2000年 | 9篇 |
1999年 | 10篇 |
1998年 | 9篇 |
1997年 | 8篇 |
1996年 | 4篇 |
1995年 | 8篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1988年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有1018条查询结果,搜索用时 31 毫秒
31.
Focardi S Corsi I Mazzuoli S Vignoli L Loiselle SA Focardi S 《Environmental monitoring and assessment》2006,122(1-3):275-287
Aquatic ecosystems around the world, lake, estuaries and coastal areas are increasingly impacted by anthropogenic pollutants through different sources such as agricultural, industrial and urban discharges, atmospheric deposition and terrestrial drainage. Lake Victoria is the second largest lake in the world and the largest tropical lake. Bordered by Tanzania, Uganda, and Kenya, it provides a livelihood for millions of Africans in the region. However, the lake is under threat from eutrophication, a huge decline in the number of native fish species caused by several factors including loss of biodiversity, over fishing and pollution has been recently documented. Increasing usage of pesticides and insecticides in the adjacent agricultural areas as well as mercury contamination from processing of gold ore on the southern shores are currently considered among the most emergent phenomena of chemical contamination in the lake. By the application of globally consistent and comprehensive geospatial data-sets based on remote sensing integrated with information on heavy metals accumulation and insecticides exposure in native and alien fish populations, the present study aims at assessing the environmental risk associated to the contamination of the Lake Victoria water body on fish health, land cover distribution, biodiversity and the agricultural area surrounding the lake. By the elaboration of Landsat 7 TM data of November 2002 and Landsat 7 TM 1986 we have calculated the agriculture area which borders the Lake Victoria bay, which is an upland plain. This process has greatly enhanced nutrient loading to the soil, which is subsequently transported to the lake by rain or as dry fall. All the data has been insert in the Geographical information System (ARCGIS) to be upgraded and consulted. Heavy metals in fish fillets showed concentrations rather low except for mercury being higher than others as already described in previous investigations. In the same tissue, cholinesterases activity (ChE) as an indicator of insecticides exposure showed significant differences among fish species in both activity and sensitivity of selected inhibitor insecticides. This integrated approach aims at identifying and quantifying selected aquatic environmental issues which integrated with monitoring techniques such as contaminant concentrations and biological responses to insecticides exposure in fish populations will provide a scientific basis for aquatic zones management and assist in policy formulations at the national and international levels. 相似文献
32.
Weyer PJ Smith BJ Feng ZF Kantamneni JR Riley DG 《Environmental monitoring and assessment》2006,116(1-3):81-90
Nitrate contamination of water sources is a concern where large amounts of nitrogen fertilizers are regularly applied to soils.
Ingested nitrate from dietary sources and drinking water can be converted to nitrite and ultimately to N-nitroso compounds,
many of which are known carcinogens. Epidemiologic studies of drinking water nitrate and cancer report mixed findings; a criticism
is the use of nitrate concentrations from retrospective drinking water data to assign exposure levels. Residential point-of-use
nitrate data are scarce; gaps in historical data for municipal supply finished water hamper exposure classification efforts.
We used generalized linear regression models to estimate and compare historical raw water and finished water nitrate levels
(1960s--1990s) in single source Iowa municipal supplies to determine whether raw water monitoring data could supplement finished
water data to improve exposure assessment. Comparison of raw water and finished water samples (same sampling date) showed
a significant difference in nitrate levels in municipalities using rivers; municipalities using other surface water or alluvial
groundwater had no difference in nitrate levels. A regional aggregation of alluvial groundwater municipalities was constructed
based on results from a previous study showing regional differences in nitrate contamination of private wells; results from
this analysis were mixed, dependent upon region and decade. These analyses demonstrate using historical raw water nitrate
monitoring data to supplement finished water data for exposure assessment is appropriate for individual Iowa municipal supplies
using alluvial groundwater, lakes or reservoirs. Using alluvial raw water data on a regional basis is dependent on region
and decade. 相似文献
33.
Karimoun M. Illyassou Rabani Adamou Bruno Schiffers 《Journal of environmental science and health. Part. B》2019,54(3):176-186
The use of pesticides in horticultural sector in Niger has become an integral part of modern agriculture. Nevertheless, their inappropriate use can generate negative health effects to operators. A study was carried out among Kongou farmers in order to assess their potential dermal exposure (PDE). The UK-POEM model was used to quantify the PDE during mixing/loading and application according to the local practices. In order to determine which parts of the operator body are subject to most contamination during spraying and to validate the theoretical model used, a patch method was used with a tartrazine dye. The deposits of the tartrazine on patches were measured by colorimetry thanks to the absorbance value determined after their extraction in water and a calibration curve. A total of ten spraying trials (five trials with the hand-held sprayer and five others with the backpack sprayer) were performed by different producers at 0.5 and 1 m height for each trial. The survey shows that 92% of the farmers are illiterate and the most common active substances identified are organophosphate or pyrethroids insecticides. Seventy percent of operators do not use any personal protective equipment (PPE) during mixing/loading or spraying. The predictive systemic exposure levels vary from 0.0027?mg kg?1 bw per day to 0.7692?mg kg?1 bw per day for backpack sprayer and from 0.0261?mg kg?1 bw per day to 0.9788?mg kg?1 bw per day for hand-held sprayer, several times higher the Acceptable Operator Exposure Level (AOEL) for some actives substances. Theoretical modeling indicates more exposure of operator by a hand-held sprayer than a backpack sprayer. The patch method results show that the deposits of dye increase when the position of sprayer nozzle increases from 0.5 to 1 m for the two sprayers. All parts of the operator body are contaminated but lower body parts and chest are the most exposed. The patch method results also show that hand spraying contaminates operator more than backpack spraying, confirming the results of the theoretical model. 相似文献
34.
研究了盐度为5条件下,ClO2和碳水化合物水平对中国明对虾(Fenneropenaeus chinensis)存活和生长的影响,共两个实验:实验1研究了ClO2(0、1、4、7、10、13、16、19和22 mg/L)对中国明对虾存活的影响,发现随ClO2浓度的升高,对虾存活率呈下降趋势;在24、48、72和96 h,LC50分别为21.04、13.32、10.91和8.26 mg/L,安全浓度为1.60 mg/L.实验2研究了ClO2(0.0、0.2、0.4和0.6 mg/L)和饲料中碳水化合物水平(13.89和41.76%)对中国明对虾存活和生长的影响,发现在两个碳水化合物水平,随ClO2浓度的升高,对虾存活率、特定生长率、摄食量和吸收效率均呈下降趋势,而饲料系数呈上升趋势;在四个ClO2水平,摄食13.89%碳水化合物对虾的特定生长率、摄食量和吸收效率均高于摄食41.76%碳水化合物的对虾,而摄食13.89%碳水化合物对虾的饲料系数低于摄食41.76%碳水化合物的对虾. 相似文献
35.
YIN Da-qiang HU Shuang-qing GU Ying WEI Li LIU Shu-shen ZHANG Ai-qian 《环境科学学报(英文版)》2007,19(2):232-237
Bisphenol A (BPA) is the monomer component of polycarbonate plastics and classified as an endocrine disrupting chemical (EDC). The reproductive toxicity of BPA has been extensively studied in mammals; however, relatively little information is available on the immunotoxic responses of fish to BPA. In this study, we investigated the effects of BPA on the immune functions of lymphocytes and macrophages in Carassius auratus. The effects of BPA were compared with those of two natural steroid hormones, estradiol and hydrocortisone. Proliferation of the two types of cells in response to PHA was measured using colorimetric MTT assay. Macrophage respiratory burst stimulated by Con A was measured using chemiluminescence assay. Results showed that BPA (0.054-5.4 mg/L), estradiol (0.0002-2.0 mg/L) and hydrocortisone (5-50 mg/L) significantly induced Carassius auratus lymphocyte proliferation while higher doses of hydrocortisone (500-5000 mg/L) appeared to be inhibitory. BPA (0.005-50 mg/L), estradiol (0.005-800 mg/L) and hydrocortisone (0.005-500 mg/L) markedly enhanced macrophage proliferation, whereas higher doses of BPA (500-1000 mg/L) appeared to inhibit cell proliferation. Furthermore, higher dosage of BPA (50 mg/L) and hydrocortisone (50 and 500 mg/L) suppressed the macrophages respiratory burst while estradiol is stimulative all the doses tested (0.05-500 mg/L). In conclusion, BPA could have immunotoxicity to Carassius auratus and functional changes of lymphocyte and macrophage in Carassius auratus may be different between low and high dosages. 相似文献
36.
37.
Damjana Drobne ?iva Pipan Tkalec 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1157-1164
A single-species laboratory test with terrestrial invertebrates was used to identify the hazard of nanosized TiO2. Feeding parameters, weight change, mortality, and the activities of catalase and glutathione-S-transferase were evaluated after 3 or 14 days of dietary exposure. The effects of nano-TiO2 were dependent on exposure concentration and duration, total consumed quantity, size and pre-treatment of particles. The intensity of a response was ruled by duration of exposure and not by consumed quantity of nano-TiO2 or exposure concentration as expected. The response to nano-TiO2 is described as threshold-like. The exposure concentrations 10-1000 μg TiO2/g dry food (1.35-1025 μg of total consumed quantity of TiO2/g animal wet wt.) were identified as safe for tested species after tested exposure period. We conclude that the response to nanoparticles is different from that of soluble chemicals therefore these two types of data should be interpreted and processed differently. 相似文献
38.
Norbert Gonzalez-Flesca Matthew S. Bates Veronique Delmas Vincenzo Cocheo 《Environmental monitoring and assessment》2000,65(1-2):59-67
Many VOC represent hazards to human health through chronic exposure. Recent European and world-wide legislation proposes limit values for ambient concentrations of these compounds. However, very little experimental data exists for true population exposure. In 1996, the European MACBETH initiative set out to measure population exposure to benzene in six European cities. This study details the French contribution to this program. Six campaigns were carried out, each comprising measurements at 100 outdoor sites and the participation of 50 non-smoking volunteers who wore personal samplers and had passive monitors installed in their homes. Iso-concentration maps were drawn for each campaign and the results showed that outdoor concentrations were significantly lower than indoors. Almost 75% of the volunteers were exposed to mean concentrations higher than the limit value of 5µgm3. It is demonstrated that personal exposure levels cannot be deduced simply by combining indoor and outdoor background concentrations. It is also shown that there is need for better knowledge of the contributions to overall exposure of outdoor microenvironments and the authors hope that future European directives will take this into account. 相似文献
39.
A.J. Wheeler I. Williams R.A. Beaumont R.S. Hamilton 《Environmental monitoring and assessment》2000,65(1-2):69-77
The personal exposure of children aged 9 – 11 years to particulate matter (PM10 and PM2.5) was carried out between January and September 1997 in the London Borough of Barnet. Personal sampling along with home, garden and classroom microenvironmental monitoring was completed for all ten children. Each child was monitored for five days during winter, spring and summer. All children completed daily time activity diaries to provide information on any potential activities that could influence their exposure to particulate matter. Each evening a household activity questionnaire was also completed by the parents. Personal Environmental Monitors were used to sample personal exposure to PM10 and PM2.5. Harvard Impactors were used for the microenvironmental sampling of both size fractions. The children's mean personal exposure concentrations for PM10 during winter, spring and summer were 72, 54 and 35 µg/m3 respectively and for PM2.5 22, 17 and 18 µg/m3 respectively. In order to determine the potential sources of particulate matter, analysis of the Teflon filters has been undertaken. The physical characteristics of the particles have been identified using Scanning Electron Microscopy. The relationships between personal exposure concentrations and the different microenvironments will be discussed. 相似文献
40.
Diapouli E Chaloulakou A Mihalopoulos N Spyrellis N 《Environmental monitoring and assessment》2008,136(1-3):13-20
Simultaneous indoor and outdoor PM10 and PM2.5 concentration measurements were conducted in seven primary schools in the Athens area. Both gravimetric samplers and continuous
monitors were used. Filters were subsequently analyzed for anion species. Moreover ultrafine particles number concentration
was monitored continuously indoors and outdoors. Mean 8-hr PM10 concentration was measured equal to 229 ± 182 μg/m3 indoors and 166 ± 133 μg/m3 outdoors. The respective PM2.5 concentrations were 82 ± 56 μg/m3 indoors and 56 ± 26 μg/m3 outdoors. Ultrafine particles 8-h mean number concentration was measured equal to 24,000 ± 17,900 particles/cm3 indoors and 32,000 ± 14,200 particles/cm3 outdoors. PM10 outdoor concentrations exhibited a greater spatial variability than the corresponding PM2.5 ones. I/O ratios were close or above 1.00 for PM10 and PM2.5 and smaller than 1.00 for ultrafine particles. Very high I/O ratios were observed when intense activities took place. The
initial results of the chemical analysis showed that accounts for the 6.6 ± 3.5% of the PM10 and for the 3.1 ± 1.4%.The corresponding results for PM2.5 are 12.0 ± 7.7% for and 3.1 ± 1.9% for . PM2.5
indoor concentrations were highly correlated with outdoor ones and the regression line had the largest slope and a very low
intercept, indicative of no indoor sources of fine particulate . The results of the statistical analysis of indoor and outdoor concentration data support the use of as a proper surrogate for indoor PM of outdoor origin. 相似文献