Oxidation of inorganic contaminants by ferrates (VI, V, and IV)--kinetics and mechanisms: a review

Inorganic contaminants are found in water, wastewaters, and industrial effluents and their oxidation using iron based oxidants is of great interest because such oxidants possess multi-functional properties and are environmentally benign. This review makes a critical assessment of the kinetics and mechanisms of oxidation reactions by ferrates (Fe(VI)O(4)(2-), Fe(V)O(4)(3-), and Fe(IV)). The rate constants (k, M(-1) s(-1)) for a series of inorganic compounds by ferrates are correlated with thermodynamic oxidation potentials. Correlations agree with the mechanisms of oxidation involving both one-electron and two-electron transfer processes to yield intermediates and products of the reactions. Case studies are presented which demonstrate that inorganic contaminants can be degraded in seconds to minutes by ferrate(VI) with the formation of non-toxic products.     

Emergy evaluation of an integrated livestock wastewater treatment system

Wastewater treatment practices should pay more attention to their environmental performances due to their resources consumption and emissions’ impact. While reclaimed water reuse seems to have become a promising practice, is it always feasible in any condition? To address this issue, this study carried out an extended emergy evaluation of a holistic wastewater treatment system. On one hand, this method was extended to include the emissions’ impact. On the other hand, this study integrated a wastewater treatment plant, its excess sludge disposal system and treated water disposal system into an integrated wastewater treatment system (IWTS), so as to evaluate its performances more completely. And then several indicators, including cost per unit pollutant eliminated (CUPE), ratio of positive output (RPO), environmental load ratio (ELR), and sustainability index (SI), were proposed for evaluating the performances of an IWTS. Two scenarios (scenario A: wastewater treatment + sludge landfilling + treated water discharges; scenario B: wastewater treatment + sludge landfilling + reclaimed water reuse) for a livestock wastewater treatment plant in Sichuan Agricultural University located in Ya’an City in Southwest China, as cases, were researched. The results show that scenario B has lower positive output efficiency and greater environmental load than scenario A. Meanwhile, the reclaimed water reuse raises cost per unit pollutant eliminated compared with the treated water being discharged directly; emissions’ impact enhances the environmental load of the two scenarios to different degree; emissions’ impact has decisive effect on the sustainability of the two scenarios. These results mean that the reclaimed water reuse should not be advocated in this case. This study provides some policy implications: (1) wastewater treatment process should be comprehensively evaluated from its resources consumption and impact of emissions; (2) reclaimed water reuse should be carefully evaluated from its pros and cons simultaneously; (3) the local conditions should be considered when implementing reclaimed water reuse, such as local water body conditions, market demands, the related laws and regulations, corporations’ economic conditions, etc.     

Utilization of solar energy in sewage sludge composting: Fertilizer effect and application

Three reactors, ordinary, greenhouse, and solar, were constructed and tested to compare their impacts on the composting of municipal sewage sludge. Greenhouse and solar reactors were designed to evaluate the use of solar energy in sludge composting, including their effects on temperature and compost quality. After 40 days of composting, it was found that the solar reactor could provide more stable heat for the composting process. The average temperature of the solar reactor was higher than that of the other two systems, and only the solar reactor could maintain the temperature above 55 °C for more than 3 days. Composting with the solar reactor resulted in 31.3% decrease in the total organic carbon, increased the germination index to 91%, decreased the total nitrogen loss, and produced a good effect on pot experiments.     

Influence of influent on anaerobic ammonium oxidation in an Expanded Granular Sludge Bed-Biological Aerated Filter integrated system

Shortcut nitrification-denitrification, anaerobic ammonium oxidation (ANAMMOX), and methanogenesis have been successfully coupled in an Expanded Granular Sludge Bed-Biological Aerated Filter (EGSB-BAF) integrated system. As fed different synthetic wastewater with chemical oxygen demand (COD) of 300–1200 mg·L^-1 and NH4+-N of 30–120 mg·L^-1 at the outer recycle ratio of 200%, the influence of influent on ANAMMOX in the integrated system was investigated in this paper. The experimental results showed that higher COD concentration caused an increase in denitrification and methanogenesis but a decrease in ANAMMOX; however, when an influent with the low concentration of COD was used, the opposite changes could be observed. Higher influent NH4+-N concentration favored ANAMMOX when the COD concentration of influent was fixed. Therefore, low COD/NH4+-N ratio would decrease competition for nitrite between ANAMMOX and denitrification, which was favorable for reducing the negative effect of organic COD on ANAMMOX. The good performance of the integrated system indicated that the bacterial community of denitrification, ANAMMOX, and methanogenesis could be dynamically maintained in the sludge of EGSB reactor for a certain range of influent.     

城市下水道污水水质模型的开发与应用

建立了下水道水质转化概念模型,以ASM3(活性污泥3号模型)为基础开发了下水道污水水质数学模型,通过模拟试验,运用遗传算法和曲线拟合技术进行了模型率定与参数估值.模型经现场试验验证可较好地模拟下水道中的ρ(DO)与ρ(TOC)的变化.应用该模型进行数值模拟,探讨了初始ρ(DO)和水力停留时间(HRT)等可控因素对下水道中微生物作用及有机质降解的影响.结果表明,在下水道中设置曝气点,可提高污水的ρ(DO),能有效地提高微生物增殖速率,强化有机物的生化降解能力.      

Fate and risk assessment of emerging contaminants in reclaimed water production processes

• PPCPs had the highest removal efficiency in A²O combined with MBR process (86.8%). • ARGs and OPFRs were challenging to remove (6.50% and 31.0%, respectively). • Octocrylene and tris(2-ethylhexyl) phosphate posed high risks to aquatic organisms. • Meta-analysis was used to compare the ECs removal in wastewater treatment. • Membrane treatment technology is the most promising treatment for ECs removal. Reclaimed water has been widely applied in irrigation and industrial production. Revealing the behavior of emerging contaminants in the production process of reclaimed water is the first prerequisite for developing relevant water quality standards. This study investigated 43 emerging contaminants, including 22 pharmaceuticals and personal care products (PPCPs), 11 organophosphorus flame retardants (OPFRs), and 10 antibiotic resistance genes (ARGs) in 3 reclaimed wastewater treatment plants (RWTPs) in Beijing. The composition profiles and removal efficiencies of these contaminants in RWTPs were determined. The results indicated that the distribution characteristics of the different types of contaminants in the three RWTPs were similar. Caffeine, sul2 and tris(1-chloro-2-propyl) phosphate were the dominant substances in the wastewater, and their highest concentrations were 27104 ng/L, 1.4 × 10⁷ copies/mL and 262 ng/L, respectively. Ofloxacin and sul2 were observed to be the dominant substances in the sludge, and their highest concentrations were 5419 ng/g and 3.7 × 10⁸ copies/g, respectively. Anaerobic/anoxic/oxic system combined with the membrane bioreactor process achieved a relatively high aqueous removal of PPCPs (87%). ARGs and OPFRs were challenging to remove, with average removal rates of 6.5% and 31%, respectively. Quantitative meta-analysis indicated that tertiary treatment processes performed better in emerging contaminant removal than secondary processes. Diethyltoluamide exhibited the highest mass load discharge, with 33.5 mg/d per 1000 inhabitants. Octocrylene and tris(2-ethylhexyl) phosphate posed high risks (risk quotient>1.0) to aquatic organisms. This study provides essential evidence to screen high priority pollutants and develop corresponding standard in RWTPs.     

Aggravation of membrane fouling and methane leakage by a three-phase separator in an external anaerobic ceramic membrane bioreactor

The existence of three-phase separator did not affect COD removal in the EAnCMBR. The existence of three-phase separator aggravated methane leakage of EAnCMBR. The existence of three-phase separator aggravated membrane fouling rate of EAnCMBR. Start-up of EAnCMBR equipped three-phase separator was slightly delayed. The three-phase separator is a critical component of high-rate anaerobic bioreactors due to its significant contribution in separation of biomass, wastewater, and biogas. However, its role in an anaerobic membrane bioreactor is still not clear. In this study, the distinction between an external anaerobic ceramic membrane bioreactor (EAnCMBR) unequipped (R1) and equipped (R2) with a three-phase separator was investigated in terms of treatment performance, membrane fouling, extracellular polymers of sludge, and microbial community structure. The results indicate that the COD removal efficiencies of R1 and R2 were 98.2%±0.4% and 98.1%±0.4%, respectively, but the start-up period of R2 was slightly delayed. Moreover, the membrane fouling rate of R2 (0.4 kPa/d) was higher than that of R1 (0.2 kPa/d). Interestingly, the methane leakage from R2 (0.1 L/d) was 20 times higher than that from R1 (0.005 L/d). The results demonstrate that the three-phase separator aggravated the membrane fouling rate and methane leakage in the EAnCMBR. Therefore, this study provides a novel perspective on the effects of a three-phase separator in an EAnCMBR.     

Treatment of sludge containing nitro-aromatic compounds in reed-bed mesocosms - Water, BOD, carbon and nutrient removal

Since the mid-1970s, Sweden has been depositing 1 million ton d.w sludge/year, produced at waste water treatment plants. Due to recent legislation this practice is no longer a viable method of waste management. It is necessary to improve existing and develop new sludge management techniques and one promising alternative is the dewatering and treatment of sludge in constructed wetlands. The aim of this study was to follow reduction of organic carbon, BOD and nutrients in an industrial sludge containing nitro-aromatic compounds passing through constructed small-scale wetlands, and to investigate any toxic effect such as growth inhibition of the common reed Phragmites australis. The result showed high reduction of all tested parameters in all the outgoing water samples, which shows that constructed wetlands are suitable for carbon and nutrient removal. The results also showed that P. australis is tolerant to xenobiotics and did not appear to be affected by the toxic compounds in the sludge. The sludge residual on the top of the beds contained low levels of organic carbon and is considered non-organic and could therefore be landfilled. Using this type of secondary treatment method, the amount of sludge could be reduced by 50-70%, mainly by dewatering and biodegradation of organic compounds.     

城市污泥的处理技术及资源化展望

本文讨论了国内外污泥处理的现状，并对目前各种污泥处理方法进行了比较，在此基础上提出污泥资源化的一些途径，认为污泥资源化将是我国污泥处理的主要发展方向。     

丝状菌在工业废水处理中的控制与有效利用

任何活性污泥系统中都存在着丝状菌,在丝状菌与菌胶团细菌平衡生长时,不会发生膨胀污泥问题,只有当丝状菌生长超过菌胶团细菌时,就会出现污泥膨胀问题。丝状菌在工业废水中的有效控制与利用尤为重要。