全文获取类型
收费全文 | 1764篇 |
免费 | 50篇 |
国内免费 | 262篇 |
专业分类
安全科学 | 35篇 |
废物处理 | 26篇 |
环保管理 | 246篇 |
综合类 | 646篇 |
基础理论 | 292篇 |
污染及防治 | 504篇 |
评价与监测 | 249篇 |
社会与环境 | 63篇 |
灾害及防治 | 15篇 |
出版年
2024年 | 3篇 |
2023年 | 15篇 |
2022年 | 26篇 |
2021年 | 36篇 |
2020年 | 60篇 |
2019年 | 36篇 |
2018年 | 48篇 |
2017年 | 38篇 |
2016年 | 57篇 |
2015年 | 70篇 |
2014年 | 77篇 |
2013年 | 141篇 |
2012年 | 105篇 |
2011年 | 206篇 |
2010年 | 114篇 |
2009年 | 197篇 |
2008年 | 170篇 |
2007年 | 143篇 |
2006年 | 83篇 |
2005年 | 49篇 |
2004年 | 40篇 |
2003年 | 52篇 |
2002年 | 40篇 |
2001年 | 32篇 |
2000年 | 41篇 |
1999年 | 22篇 |
1998年 | 17篇 |
1997年 | 18篇 |
1996年 | 22篇 |
1995年 | 12篇 |
1994年 | 14篇 |
1993年 | 30篇 |
1992年 | 21篇 |
1991年 | 3篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有2076条查询结果,搜索用时 375 毫秒
801.
Xue Bai Chang Li Lingyu Ma Pei Xin Fengjie Li Zhenjia Xu 《Frontiers of Environmental Science & Engineering》2022,16(8):107
802.
Rui Yue Zhikang Chen Liujun Liu Lipu Yin Yicheng Qiu Xianhui Wang Zhicheng Wang Xuhui Mao 《Frontiers of Environmental Science & Engineering》2022,16(11):147
803.
Zhang C Wu L Luo Y Zhang H Christie P 《Environmental pollution (Barking, Essex : 1987)》2008,151(3):470-476
Principal components analysis (PCA) and correlation analysis were used to estimate the contribution of four components related to pollutant sources on the total variation in concentrations of Cu, Zn, Pb, Cd, As, Se, Hg, Fe and Mn in surface soil samples from a valley in east China with numerous copper and zinc smelters. Results indicate that when carrying out source identification of inorganic pollutants their tendency to migrate in soils may result in differences between the pollutant composition of the source and the receptor soil, potentially leading to errors in the characterization of pollutants using multivariate statistics. The stability and potential migration or movement of pollutants in soils must therefore be taken into account. Soil physicochemical properties may offer additional useful information. Two different mechanisms have been hypothesized for correlations between soil heavy metal concentrations and soil organic matter content and these may be helpful in interpreting the statistical analysis. 相似文献
804.
Enhanced multi-metal extraction with EDDS of deficient and excess dosages under the influence of dissolved and soil organic matter 总被引:2,自引:0,他引:2
This study investigated the influence of dissolved and soil organic matter on metal extraction from an artificially contaminated soil. With high concentration of DOM, the extraction of Cu, Zn and Pb was enhanced by forming additional metal-EDDS complexes under EDDS deficiency. However, the enhancement of metal extraction under EDDS excess was probably due to the soil structure being disrupted owing to humic acid enhanced Al and Fe dissolution, which induced more metals dissolving from the soils. Fulvic acid was found to enhance metal extraction to a greater extent compared with humic acid because of its high content of the carboxylic functional group. Cu extraction from the soil with high organic matter content using EDDS was the lowest due to the high binding affinity of Cu to SOM, whereas Zn extraction became the highest because of a preference for EDDS to extract Zn due to the high stability constant of ZnEDDS. 相似文献
805.
An environment-friendly and cost-effective extraction method has been studied for the removal of arsenic from contaminated soil. A yellow-brown forest soil was contaminated with arsenic(V) and used as a model soil. Among various potassium and sodium salts, potassium phosphate was most effective in extracting arsenic, attaining more than 40% extraction in the pH range of 6–8 with minimum damage to the soil properties. Exchange mechanism is proposed for the extraction of arsenic from soil by phosphate. Sequential extraction shows that phosphate is effective in extracting arsenic of Al- and Fe-bound forms. Arsenic of residual form was not extracted. Arsenic was efficiently extracted by phosphate solution of pH 6.0 at 300 mM phosphate concentration and at 40°C. 相似文献
806.
Assessing the chemical and biological accessibility of the herbicide isoproturon in soil amended with biochar 总被引:2,自引:0,他引:2
Decamethylcyclopentasiloxane (D5) is a cyclic volatile methyl siloxane (cVMS) commonly found in commercially available products. D5 is expected to enter the terrestrial environment through the deposit of biosolids from sewage treatment plants onto agricultural fields for nutrient enrichment. Little to no information currently exists as to the risks of D5 to the terrestrial environment. In order to evaluate the potential risk to terrestrial organisms, the toxicity of a D5 contaminated biosolid in an agricultural soil was assessed with a battery of standardized soil toxicity tests.D5 was spiked into a surrogate biosolid and then mixed with a sandy loam soil to create test concentrations ranging from 0 to 4074 mg kg−1. Plant (Hordeum vulgare (barley) and Trifolium pratense (red clover)) and soil invertebrates (Eisenia andrei (earthworm) and Folsomia candida (springtail)) toxicity tests were completed to assess for lethal and sub-lethal effects. Plant testing evaluated the effects on seedling emergence, shoot and root length, and shoot and root dry mass. Invertebrate test endpoints included adult lethality, juvenile production, and individual juvenile dry mass (earthworms only). Soil samples were collected over time to confirm test concentrations and evaluate the loss of chemical over the duration of a test. The toxicity of the D5 was species and endpoint dependent, such that no significant adverse effects were observed for T. pratense or E. andrei test endpoints, however, toxicity was observed for H. vulgare plant growth and F. candida survival and reproduction. Chemical losses of up to 50% were observed throughout the tests, most significantly at high concentrations. 相似文献
807.
A review of biochars' potential role in the remediation, revegetation and restoration of contaminated soils 总被引:30,自引:0,他引:30
Beesley L Moreno-Jiménez E Gomez-Eyles JL Harris E Robinson B Sizmur T 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3269-3282
Biochars are biological residues combusted under low oxygen conditions, resulting in a porous, low density carbon rich material. Their large surface areas and cation exchange capacities, determined to a large extent by source materials and pyrolysis temperatures, enables enhanced sorption of both organic and inorganic contaminants to their surfaces, reducing pollutant mobility when amending contaminated soils. Liming effects or release of carbon into soil solution may increase arsenic mobility, whilst low capital but enhanced retention of plant nutrients can restrict revegetation on degraded soils amended only with biochars; the combination of composts, manures and other amendments with biochars could be their most effective deployment to soils requiring stabilisation by revegetation. Specific mechanisms of contaminant-biochar retention and release over time and the environmental impact of biochar amendments on soil organisms remain somewhat unclear but must be investigated to ensure that the management of environmental pollution coincides with ecological sustainability. 相似文献
808.
Remediation of metal polluted mine soil with compost: co-composting versus incorporation 总被引:10,自引:0,他引:10
Tandy S Healey JR Nason MA Williamson JC Jones DL 《Environmental pollution (Barking, Essex : 1987)》2009,157(2):690-697
Trace element contamination of post-industrial sites represents a major environmental problem and sustainable management options for remediating them are required. This study compared two strategies for immobilizing trace elements (Cu, Pb, Zn, and As) in mine spoil: (1) co-composting contaminated soil with organic wastes and (2) conventional incorporation of mature compost into contaminated soil. Sequential chemical extraction of the soil was performed to determine temporal changes in trace element fractionation and bioavailability during composting and plant growth. We show that mine spoil can be co-composted successfully and this action causes significant shifts in metal availability. However, co-composting did not lead to significant differences in metal partitioning in soil or in plant metal uptake compared with simply mixing mine spoil with mature compost. Both treatments promoted plant growth and reduced metal accumulation in plants. We conclude that co-composting provides little additional benefit for remediating trace-element-polluted soil compared with incorporation of compost. 相似文献
809.
Laboratory and field studies were conducted in order to determine the leaching potential of eight pesticides commonly used during pepper cultivation by use of disturbed soil columns and field lysimeters, respectively. Two soils with different organic matter content (soils A and B) were used. Additionally, soil B was amended with compost (sheep manure). The tested compounds were cypermethrin, chlorpyrifos-methyl, bifenthrin, chlorpyrifos, cyfluthrin, endosulfan, malathion and tolclofos-methyl. In soil B (lower organic matter content), only endosulfan sulphate, malathion and tolclofos-methyl were found in leachates. For the soil A (higher organic matter content) and amended soil B, pesticide residues were not found in the leachates. In addition, this paper reports on the use of common agronomic practices (solarization and biosolarization) to enhance degradation of these pesticides from polluted soil A. The results showed that both solarization and biosolarization enhanced the degradation rates of endosulfan, bifenthrin and tolclofos-methyl compared with the control. Most of the studied pesticides showed similar behavior under solarization and biosolarization conditions. However, chlorpyrifos was degraded to a greater extent in the solarization than in biosolarization treatment. The results obtained point to the interest in the use of organic amendment in reducing the pollution of groundwater by pesticide drainage and in the use of solarization and biosolarization in reducing the persistence of pesticides in soil. 相似文献
810.
The study of operating variables in soil washing with EDTA 总被引:7,自引:0,他引:7
Zou Z Qiu R Zhang W Dong H Zhao Z Zhang T Wei X Cai X 《Environmental pollution (Barking, Essex : 1987)》2009,157(1):229-236
This study discusses the operating variables for removal of metals from soils using EDTA, including the type of EDTA, reaction time, solution pH, dose, temperature, agitation, ultrasound and number of extractions. For As, Cd, Cu, Pb and Zn, the removal efficiency order was: H4-EDTA > Na2EDTA > (NH4)2EDTA. At low EDTA concentrations the removal increased progressively with increasing dose while above 0.4 mmol/g only small increases in extraction efficiency were observed. EDTA induced a two-step process including a rapid desorption within the first hour, and a gradual release in the following hours. The extraction efficiency of metals decreased with increasing pH in the range of 2-10. Consecutive extractions using low concentrations were more effective than a single extraction with concentrated EDTA if the same dose of EDTA was used. 相似文献