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An attempt was made to judge the environmental compatibility, the governing leaching mechanism, and mobility patterns in a
waste–cement solidified/stabilized matrix after 21 days of curing. The mixed sludge from a steel pickling facility was stabilized
by ordinary Portland cement. Iron was the major leachable metal, along with Pb, Zn, and Mn. To characterize the leaching behavior,
the mobility and mechanism of leaching were determined by diffusion leaching tests. In the solidified/stabilized matrix, the
mobility of all the elements studied was reduced, and average to low mobility was observed. Values for the negative log of
the effective diffusion coefficient of more than 12.5 were obtained for the metals. The dominant leaching mechanisms were
surface wash off in the initial stage, followed by diffusion. The environmental performance of the solidified/stabilized product
when considered in terms of mass leached over 64 days was found to be satisfactory for consideration for the safe disposal
and reuse of waste. 相似文献
22.
石灰、粉煤灰处理铅镉污染土壤的试验研究 总被引:3,自引:0,他引:3
试验模拟了Cd,Pb污染土壤,加入石灰、粉煤灰等浸出毒性,试验结果表明,加入质量分数为5%的石灰后,浸出液中的Cd,Pb浸出浓度最低,比模拟污土样品分别降低85.5%,45.2%,其它处理样品的浸出浓度和浸出率都较高,处理效果不理想。Cd,Pb污染土壤进入生活垃圾填埋场之前,添加少量石灰做预处理,是一种较好的方法。另外,浸提刺pH值对Cd,Pb的浸出影响很大。在浸提剂1#(pH值为4.93±0.05)和浸提刺2#(pH值为2.64±0.05)2种浸提剂下,Cd浸出浓度相差约30~40倍,Pb的浸出浓度相差约10~20倍。 相似文献
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采用镁基稳定剂协同硅酸盐固化/稳定化处置重金属污染土壤,以铅浸出浓度和药剂处理成本为综合指标确定稳定剂和固化剂的最优配比,并对处置机制及影响因素等探讨,为后期同类型的重金属污染土壤修复提供技术支持。研究结果表明,按照稳定剂添加比例2.5%与固化剂添加比例3%的最优配比处置后,土体重金属铅降低99.8%,可达到铅浸出修复目标值50μg/L的要求。 相似文献
25.
Rachana?Malviya Rubina?ChaudharyEmail author 《Journal of Material Cycles and Waste Management》2004,6(2):147-152
The sludge from a steel processing unit bearing zinc, lead, iron, and manganese was solidified with ordinary Portland cement. The waste was stabilized in the specimens with a waste/binder ratio range of 0.16–4.0. On the basis of the available leaching and unconfined compressive strength, the performance of the solidified/stabilized waste was compared for different numbers of curing days. It was found that curing up to 28 days resulted in a performance improvement, as shown by less leaching of heavy metals and the increased unconfined compressive strength of the specimen. The treatment effectiveness of the solidification/stabilization process was assessed for the metals Pb, Zn, Fe, and Mn, and was found to be 89%, 95%, 74%, and 90%, respectively, for an optimum ratio of 4.0 after 28 days of curing. 相似文献
26.
电镀重金属污泥的水泥固化/稳定化处理 总被引:12,自引:0,他引:12
电镀重金属污泥经425号水泥固化后;其中混凝土:污泥为40:1或50:1样本的强度(28d)可达275号水泥的标准,且对Zn、Cu、Ni、Cr离子的固化效果好;在体系中添加粉煤灰及水玻璃,其早期的固化效果或产物强度低;混凝土:铁氧体污泥(湿法合成,FeSO_4·7H_2O:污泥=4:1)为30:1体系中,固化效果与稳定性均好,且产物强度可达325号水泥标准。 相似文献
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造纸黑液固化技术及有机复合肥肥效试验研究 总被引:3,自引:0,他引:3
研究包括两项发明:黑液固化工艺和黑液固化物生产有机NPK复合肥。黑液固化采用交联技术,在常温常压下,向黑液中投加一定量的胶凝剂和交联剂,经搅拌、使黑液在短时间内由液变为固态;通过对固化物成份的分析,以黑液固化物为原料生产有机NPK复合肥,并与一般NPK复混肥进行水稻、花生的肥效对比试验,得出了以黑液固化物生产的有机NPK复合肥肥效优于一般NPK复混肥的结论。 相似文献
29.
Optimization for solidification of low-level-radioactive resin using Taguchi analysis 总被引:3,自引:0,他引:3
Solidification of low-level-radioactive (LLW) resin was optimized using Taguchi analytical methodology. The ingredients in LLW mortar which caused the solidification of cement were evaluated through consecutive measurements of the effects of various concentrations of ingredients. Samples selected according to Taguchi's method were separated into 18 different categories and measured at the 7th, 21st, and 28th day after fabrication on developing effects. Evaluations of the various samples focused on whether the compressive and bending strength fulfilled the special criteria of the Taiwan Power Company (TPC). Similar results indicated that both furnace slag and fly ash were the dominant material resulting from the solidification of LLW mortar. The superior combination was obtained as furnace slag 24 wt.%, fly ash 24 wt.%, and cement 8 wt.% to mix 24 wt.% of resin with 20 wt.% of water, to fulfill the contemporary requirements of TPC. 相似文献
30.
土壤重金属污染的工程危害及修复方法 总被引:5,自引:2,他引:3
分析了重金属污染对地基土和地下结构物的危害,比较了电动修复、土壤冲刷、原位土壤淋洗、化学固化修复土壤的优缺点,重点介绍固化/稳定化技术在修复重金属污染土壤中的应用。 相似文献