仿生植物附着微生物膜对污染水体氮素迁移转化效能分析

通过室外及室内控制试验,研究5种常见填料作为原材料制成的仿生植物对污染水体氮素的去除性能,结果表明,仿生植物原材料的差异将直接影响其附着生物膜特性,其附着生物膜量、硝化强度、反硝化强度以及硝化细菌、反硝化细菌均表现为：软性填料﹥组合填料﹥悬浮填料﹥立体弹性填料﹥半软性填料。水深对仿生植物附着生物膜亦有不同程度的影响,其中生物膜量随水深的增加并未表现出明显的分层效应,而生物膜硝化作用强度、硝化细菌随水深的增加逐渐降低,但生物膜反硝化作用强度、反硝化细菌则随水深的增加则呈现出逐渐增加的趋势。5种不同材质的仿生植物对水体TN、NH4＋-N、NO3--N具有较好的去除效果,去除率表现为：软性填料﹥组合填料﹥悬浮填料﹥立体弹性填料﹥半软性填料﹥对照系统。同时,仿生植物种植密度也影响其对水体氮素的去除效果,表现为CK〈7株·m-3〈13株·m-3〈20株·m-3,研究结果将为仿生植物的野外实际应用及我国城市重污染河道水质原位修复提供技术支持。     

亚硝酸盐氮胁迫对罗非鱼（GIFTOreoohromisniloticus）血清非特异性免疫酶活性的影响

试验设置了不同浓度亚硝酸盐氮（空白对照、0．75mg·L-1、1．50mg-L-1、3．00mg·L-1和5．00mg·L-1）,研究了亚硝酸盐氮胁迫对罗非鱼（GIFTOreochromisniloticus）血清非特异性免疫酶（溶菌酶、碱性磷酸酶、补体c3）活性的影响。结果表明：罗非鱼血清碱性磷酸酶、溶菌酶、补体C3活性均呈现出随亚硝酸盐氮浓度升高而降低的趋势,且当亚硝酸盐氮浓度小于1．50mg·L-1时,罗非鱼血清碱性磷酸酶、溶菌酶、补体C3活性与对照组相比差异不显著（P〉0．05）,说明低于1．50mg·L-1的亚硝酸盐氮不会对罗非鱼机体免疫力产生显著影响;而高于3．00mg·L-1的亚硝酸盐氮胁迫能够显著（P〈O．05）降低罗非鱼血清碱性磷酸酶、溶菌酶、补体C3活性,最大下降率分别达到31．75％、27．40％、14．43％,从而显示出高浓度亚硝酸盐氮（〉3．00mg·L-1）能够对罗非鱼机体产生强烈的氧化胁迫和免疫损伤,导致机体免疫力下降,增加罗非鱼对致病菌的易感性。本研究认为,3．00mg·L-1可能是亚硝酸盐氮胁迫引起罗非鱼机体免疫力显著降低的阈值。     

三江平原农田源头排水沟渠截留排水中氮素动态

通过小尺度野外原位试验,研究排水沟渠水体、底泥和植物中氮含量的变化规律.结果表明,随水体停留时间增加,沟渠对水体氮素的净化能力增强,认为停留8d左右较适宜.沟渠对NH4-N的截留率大于TN和NO3--N.渠水停留11d时,4条试验沟渠[氮浓度高、磷浓度低(NHPL),氮浓度高、磷浓度高(NHPH),氮浓度低、磷浓度低(NLPL),氮浓度低、磷浓度高(NLPH)]对NH4+-N的截留率均达100％,对NO3--N的截留率分别为84.63％、84.35％、75.67％和76.14％,对TN的截留率分别为88.02％、89.89％、90.88％和88.53％.试验结束时沟渠表层(0～15 cm)底泥氮含量降低,植物氮累积量远大于进水TN总量,说明植物生长同时吸收了水体、土壤和底泥中的氮,建议在秋季适时收割植物,以避免植物分解导致二次污染.     

啤酒废水同步脱氮除磷工艺启动研究

为了将短程硝化反硝化与A/O法除磷同时应用于SBR工艺处理啤酒废水,通过改变序批式反应器(SBR)工艺运行方式,使活性污泥依次经历厌氧、好氧、缺氧3个阶段,控制ρ(MLSS)=4 700 mg/L、pH=7.5～8.0、DO=0.3～0.5 mg/L(好氧阶段)。反应器内短程硝化反硝化同步除磷效果明显,氨氮去除率大于90%,亚硝酸盐积累率大于85%,磷去除率大于98%。试验结果表明短程硝化反硝化与A/O法除磷可同时应用于SBR工艺处理啤酒废水。     

我国电解锰行业氨氮污染分析与控制

我国"十二五"期间将氨氮纳入总量控制指标,电解锰行业氨氮污染控制变得非常紧迫。介绍了电解锰氨氮污染的现状,分析了电解锰氨氮污染的产生途径以及电解锰生产中的氨氮平衡,依据"源头消减、过程控制、末端循环"的清洁生产理念,提出了电解锰氨氮污染的控制措施。     

Validation of liquid nitrogen vaporisation rate by small scale experiments and analysis of the conductive heat flux from the concrete

The vaporisation of a liquid nitrogen pool spilled on concrete ground was investigated in small scale field experiments. The pool vaporisation rate and the heat transfer from the concrete ground were measured using a balance and a set of embedded heat flux sensors and thermocouples. The ability to predict the concrete's thermal properties based on these measurements was investigated. This work showed that a simple, one-dimensional theoretical model, assuming heat conduction through a semi-infinite ground with ideal contact between the cryogenic liquid and the ground, commonly used to describe the heat transfer from a ground to the LNG, can be used to match the observed vaporisation rate. Though estimated parameters, thermal conductivity and thermal diffusivity, do not necessary represent real values. Although the observed vaporization rate follows a linear trend, and thus can be well represented by the model, the overall model prediction seems to be overestimated. The temperature profile inside the concrete is slightly over-predicted at the beginning and under-predicted at later stage of the spill. This might be an effect of the dependence of the concrete's thermal properties on the temperature or may indicate an incorrect modelling and a varying temperature of the ground surface.     

Nitrogen budget and its environmental loading in an urban ecosystem with the rapid urbanisation of China

A detailed nitrogen (N) budget has been developed for an urban ecosystem based on the method of material flow analysis. How increased human activity and urbanisation influences N cycling have also been analysed. Total N input and output in the urban ecosystem of Zhengzhou City (ZUE) was calculated at 304.8?Gg was 275.3?Gg year^?1, resulting in an N accumulation of 29.5?Gg year^?1. Industry and human life activities, which respectively accounted for 43.8% and 34.2% of total N inputs and 52.6% and 29.1% of total N outputs, were the core of N flow in the urban ecosystem. Humans activities mediated more than 98% N inputs into the ZUE, 73.2% of N was released into the atmosphere and 11.7% into hydrosphere. This very large volume of released N could contribute to regional problems. High energy consumption, insufficient wastewater treatment facility practices, and low N use efficiency are the primary causes of pollution. The major challenge ahead for the urban ecosystem is how to manage high-intensity N pollutant inputs to the urban ecosystems coupled with incomplete N cycling and removal. Based on the analysis of the N budget and loading, this study also proposes an N management strategy for the ZUE.     

Effects of different mowing frequencies on soil carbon and nitrogen changes in leymus chinensis steppe of Hulun Buir北大核心CSCD

Mowing is the main management of Hulun Buir grasslands in Inner Mongolia; therefore, understanding the changes of soil organic carbon (SOC), total nitrogen (TN), and carbon sequestration under different mowing frequencies will provide an important scientific basis for grassland carbon sink management in Inner Mongolia. Three treatment plots were devised in the study area, including enclosed sample (Y), mowing every other year (2G), and mowing once a year (1G), where SOC, TN content and storage were investigated. The results showed that with increased mowing frequency, the SOC and TN content showed a decreasing trend in the 0-30 cm depth soil layer. The SOC and TN content were different in each soil layer, which decreased gradually with increasing soil depth in Y and 2G plots, whereas increased gradually in 1G plots. The soil carbon storage was significantly correlated with the soil nitrogen storage, and both showed a significant linear decrease with increased mowing frequency, which showed as carbon and nitrogen loss. In 2G plots, the soil carbon storage decreased by 17.1% and soil nitrogen storage decreased by 20.8%. In 1G plots, the soil carbon storage decreased by 21.6% and soil nitrogen storage decreased by 29.3%. The results showed that the change of soil carbon and nitrogen was sensitive to mowing frequency for the Hulun Buir grassland. It is possible to reduce the loss of carbon and nitrogen by reasonably controlling mowing frequency, and the sustainable use of grassland could be achieved with appropriate fertilization. Keywords. © 2018 Science Press. All rights reserved.     

吸收液对中空纤维膜接触器回收尿液中氨氮的影响

采用中空纤维膜接触器（Hollow Fiber Membrane Contactor, HFMC）回收尿液中的氨氮,系统研究了吸收液类型（H₃PO₄、H₂SO₄和HNO₃）对氨回收效能、水蒸气的跨膜通量和所获液体肥料的影响.结果表明,使用H₂SO₄作为吸收液时氨氮回收效能最优,其次是H₃PO₄和HNO₃.当采用H₂SO₄为吸收液时,氨氮回收率、氨跨膜通量和传质系数分别为84.49%±0.01%、22.92 g·m^-2·h^-1和2.37×10^-6 m·s^-1.HNO₃的挥发性使其从吸收液侧反向跨膜至料液侧,导致氨跨膜传质驱动力变小;此外,NH₃和HNO₃会在膜孔中反应并生成NH₄NO₃气溶胶,增加氨在膜孔中的传质阻力,导致氨氮的回收效能降低.对采用不同吸收液时膜两侧的水的活度差和理论水通量进行了计算,结果表明,随着氨氮的不断跨膜吸收,膜两侧的活度差和水通量逐渐增大,实验结束时水通量分别为7.44×10^-2 kg·m^-2·h^-1（H₃PO₄）、9.06×10^-2 kg·m^-2·h^-1（H₂SO₄）和2.00×10^-2 kg·m^-2·h^-1（HNO₃）.肥料组分分析表明,以H₂SO₄和HNO₃为吸收液可以获得仅含N素的单一液体肥料,以H₃PO₄作吸收液可获得N-P复合肥,（NH₄）₂HPO₄和NH₄H₂PO₄所占的比例分别为88.33%和11.67%.     

潮白河再生水生态补给河道区浅层地下水氮转化

再生水与天然地下水水质存在差异,利用再生水生态补给河道区可能会带来环境风险.引温济潮工程已运行10余年,为研究再生水长期河道入渗下不同位置地下水氮组分的演化特征与机制,收集近11年的地表水与地下水监测资料.采用聚类分析将地表水划分为不同区域后选择典型地下水监测点分析氮组分的演化差异,并利用Cl-计算混合比得出地下水中目标成分的计算浓度,初步推测地表水入渗后发生的氮转化,并选取DO、TOC、底泥、水文地质条件等环境指标分析证明.结果表明:①地表水明显分为3组,包括减河、土坝以北潮白河段、土坝以南潮白河段,各组间指标存在显著差异,影响水质差异的主要因素为再生水的氮、磷含量及水体流态.②再生水入渗过程中,包气带或黏土层较厚有利于氮的去除,减河和土坝以北潮白河段地表水中的NO₃--N流经包气带时通过反硝化与同化作用衰减,NH₄+-N通过吸附与硝化作用得以去除,入渗后未引起地下水中的氮浓度明显增加.③而土坝以南潮白河段,河道补水后翌年地下水位抬升并趋于稳定,长期地表水入渗使底泥的氮和有机质含量升高,使得该断面于2013年后达到适宜的碳氮比而发生有机氮矿化作用,由于包气带较薄,生成的NH₄+-N较少吸附于土壤介质中,易随水流入渗而引起地下水中ρ（NH₄+-N）升高.研究显示,再生水入渗过程中,包气带或黏土层较厚可有效去除氮组分,但部分地区包气带较薄且发生有机氮矿化作用会增加地下水的氮污染风险.