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681.
The critical load concept is nowwidely used as a tool for developing emissioncontrol policies in Europe. As a signatorycountry of the Convention of Long-RangeTransboundary Air Pollution, critical loads foracidity, nutrient nitrogen, nitrogen and sulphurhave been calculated for the Flemish and Walloonregions in Belgium. This paper describes themethodology used for estimating critical loadsfor forest soils in the Walloon region accordingto the Steady-State Mass Balance equations. As anexample the methodology was applied to thecatchment `Waroneu', situated in a sensitive areaof the Haute Ardenne. Main input parameters tothe equations were derived from precipitation andrunoff data of the catchment study. Improvedestimates of nitrogen uptake (Nu) and base cationuptake (BCu) were obtained by intensive samplingof Picea abies and Quercus roburtrees. Nutrient contents (Ca, Mg, K, N) andnutrient to nitrogen ratios of Picea abiesreflected the poor soil quality at a site withhigh N deposition. Quercus robur nutrientcontents increased from stem to higher orderbranches with a high proportion of nutrientslocated in the bark. However the simulation ofstem only harvesting had a minor effect oncritical loads. Measured wood densities werelower than reported literature values with a maineffect on Nu and BCu estimates. The use ofrecommended default values and/or data derivedfrom the experimental site resulted in a widerange of critical loads, some of which werelargely overestimated. Results demonstrated theimportance of site specific data for criticalload calculations. 相似文献
682.
In the 1999 Gothenburg protocol to the UN/ECE LRTAP Convention andin the negotiations for an EU acidification strategy the area withexceedances of critical loads has been the preferred measure forenvironmental impacts. The aim of this study has been to assessthe influence of the uncertainty and spatial variation of both thecritical loads and deposition values on the calculated area withexceedances of critical loads. This has been done on a nationalscale for Denmark and on the European scale based on the dataincluded in the RAINS model. It is demonstrated that includinguncertainty and spatial variation in exceedance calculations, ingeneral gives larger exceeded area for the critical load ofacidity, CL(A). The picture for the critical load of nutrientnitrogen, CLnut(N), is more mixed because of the higherproportion of exceeded areas. A further point of interest is thepossibility of validating relationships between critical loadexceedances and observable damage based on large scale monitoringand model data. It is demonstrated that it will probably not bepossible to use exceedance calculations on European scale as basisfor validation exercises, linking exceedances to observable damage. 相似文献
683.
Reduction of sulphur deposition causesrecovery of acidified surface waters. Processes in thecatchment delay recovery. The acidification model MAGICwas applied to the Vikedal and Tovdal rivers in southernNorway. Response in water chemsitry is delayed by 10–20 yr. The delay is due to release of old sulphate atVikedal and cation exchange at Tovdal. Assuming that theGothenburg protocol is fully implemented by the year2010, much of the predicted increase of ANC will occur inthe next 10 yr with a levelling off by about 2040. Ifnitrogen leaching increases in the future, however,recovery of ANC will not be as rapid, nor as complete.Critical load for acidity calculated by steady-statemodels is confirmed by the MAGIC predictions. Futurerequirement for mitigation measures such as liming willdecrease in the future as acid deposition decreases. Bythe year 2046 the liming requirement will be reduced byabout 45% at Vikedal and 65% at Tovdal. One of the mainpurposes of the Norwegian national monitoring programmeis to provide documentation of changes in environmentalquality due to long-range transported air pollutants.Modelling applications such as this clearly show that thedata fill this purpose. 相似文献
684.
Waste plastics recycling by an entrained-flow gasifier 总被引:1,自引:0,他引:1
Takatoshi Shoji Kenjiro Shindoh Hironori Ozaki Atsushi Sodeyama 《Journal of Material Cycles and Waste Management》2001,3(2):75-81
We studied an entrained-flow gasification process which efficiently converts waste plastics to energy at a high energy recovery
rate. Waste plastics, after being shredded to <8 mm or <14 mm, were fed into an entrained-flow gasifier with air and oxygen.
In the gasifier, organic substances were pyrolyzed, partially combusted, and then converted into synthetic gas (CO, H2) at a high temperature (over 1600 K). The clarified gasification characteristics were that the lower heat value (LHV) of
the product gas was over 4.2 MJ/Nm3 and the cold gas efficiency was approximately 60%. Other inert substances in the wastes such as ashes and metals were melted
into slag and condensed on bag filters. The bag filters and a water scrubber removed impurities such as dusts, heavy metals,
and hydrogen halides from the product gases. Solid hydrocarbons, which include char and soot, were removed at a hot cyclone
and on the bag filters.
Received: July 19, 2000 / Accepted: October 3, 2000 相似文献
685.
Beier C. Rasmussen L. Pilegaard K. Ambus P. Mikkelsen T. Jensen N. O. Kjøller A. Priemé A. Ladekarl U. L. 《Water, Air, & Soil Pollution: Focus》2001,1(1-2):187-195
The fluxes of the major nitrogen compounds havebeen investigated in many ecosystem studies over the world.However, only in few studies has attention been drawn to theimportance of the fluxes of minor gaseous nitrogen compoundsto complete the nitrogen cycle. In Denmark a detailed study onthe nitrogen cycle in an old beech forest has been implementedin 1997 at Gyrstinge near Sorø, Zealand. The study includesthe fluxes of the gases NO, N2O and water mediatedtransport of NO3
- and NH4
+. Measurementsof the fluxes of the gaseous compounds are performed withmicro-meteorological methods (eddy-correlation and gradient)and with chambers. Water mediated fluxes encompass rain,throughfall, stem-flow and leaching from the root zone. Thehydrological model is verified by TDR measurements. The findings show that the total water mediated N input tothe forest floor with throughfall and stemflow was 25.6 kg Nha-1 yr -1, and open field wet deposition withprecipitation was 19.0 kg N ha-1 yr -1. The internalcycling of N in the ecosystem measured as turnover oflitterfall and plant uptake was 100 kg N ha-1 yr -1and 14 kg N ha-1 yr -1, respectively. The fluxes ofthe gaseous N compounds NO and N2O were of minorimportance for the total N turnover in the forest, NOxemission being <1 kg N ha-1 yr -1 and N2Oemission from the soil being 0.5 kg N ha-1 yr -1 withno significant difference between wet and dry soils.Concentrations of NO3
- and NH4
+ in thesoil solution beneath the rooting zone are very small andconsequently the N leaching is almost negligible. It isconcluded that the nitrogen mass balance of this old beechforest ecosystem mainly is controlled by the input by dry andwet deposition and a large internal N cycle with a fast litterturnover. The nitrogen input tothe forest ecosystem which currently exceeds the critical loadby 5 kg N ha-1 yr -1is mainly accumulated in the soil and no significant nitrateleaching is occurring. 相似文献
686.
This paper describes an application of the long termdynamic model, MAGIC, on a monthly timestep, enablingincorporation of the seasonal dynamics associated with abroad understanding of the ecosystem N cycle. The modelhas been applied to the Dargall Lane catchment in theGalloway region of Scotland where marked seasonal Ndynamics are apparent. Mean monthly proportions ofrainfall, runoff, deposition fluxes and net retention ofN are utilised to drive the model on a monthly timestep.Calibration of the model has successfully reproduced thepresent day observed seasonal variation in streamNO3 and ANC. Prediction of recovery at the siteunder the second sulphur protocol indicates that,although mean annual ANC increases, mean monthly ANC doesnot rise above zero for all months of the year until2010. 相似文献
687.
688.
针对高锰酸盐指数(CODMn)和氨氮(NH3-N)标准溶液(以下简称液标)制造商、浓度水平和使用情况进行调研,根据调研结果选择常用的7个品牌CODMn液标和9个常用NH3-N液标品牌开展量值比对和质量评价研究,匿名采购129支液标经盲样编码后采用《地表水环境质量标准》(GB 3838—2002)推荐标准进行分析测定,计算和评定测定结果的不确定度,以En法进行量值比对评价。研究表明,NH3-N液标量值均满意,CODMn测试中的加盖操作会使测定结果偏高,按照证书要求操作时CODMn液标量值合格,未按照液标证书中要求进行液标样品前处理测定会造成测定结果的偏离,影响评价结果。建议监测人员合理选用和规范使用环境用液标,加强环境用液标的选购和管理,确保检测过程得到有效控制。 相似文献
689.
Gregory M. Clark David K. Mueller M. Alisa Mast 《Journal of the American Water Resources Association》2000,36(4):849-860
ABSTRACT: Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flow‐weighted concentrations during 1990–1995 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow‐weighted concentration of nitrate exceeded 0.6 mg/L in only three basins. Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8.1, 26, 86, 2.8, and 8.5 kilograms per square kilometer, respectively. Concentrations and yields of nitrate tended to be highest in northeastern and mid‐Atlantic coastal states and correlated well with areas of high atmospheric nitrogen deposition. Concentrations and yields of total nitrogen were highest in the southeastern part of the nation and in parts of the upper Midwest. In the northeast, nitrate was generally the predominant form of nitrogen, and in the southeast and parts of the upper Midwest, organic nitrogen was the dominant form. Concentrations of total phosphorus were generally highest in the Rocky Mountain and Central Plain states. 相似文献
690.