水中总碱度测定的不确定度评定

以水中总碱度为例,分析了测试过程中不确定度的来源,对各不确定度分量进行评定及合成,并计算得出合成不确定度和扩展不确定度。结果表明,对本测试方法影响较大的不确定度分量是标准物质配制、溶液体积引入和标定过程中的随机因素。在样品重复测定的条件下,测定结果的不确定度仅与溶液中的质量浓度有关。     

常州市老城区水体有机污染分布特征及原因初探

为了老城区河道的合理整治,采用总有机碳（TOC）分析仪对常州市老城区3条河流及区域内浅层地下水的14个采样点水样进行3个月的总有机碳含量检测。老城区水环境受到不同程度的有机污染,某些地下水的TOC含量高于地表水,原因为地表水补给地下水,且老城区水体污染源主要来源于周边地区的生活污水,并受到关河、雨水等的影响,这为常州市老城区水污染治理提供了依据。     

海水中总氮的测定方法比较研究

通过标准曲线、检出限和测定范围、方法精密度、方法准确度、实际海水样品测定结果、加标回收率、分析效率和物料消耗这几方面比较了过硫酸钾氧化法、流动注射分析法和高温氧化-化学发光检测法这3种测定海水中总氮(TN)方法的优缺点。结果表明,流动注射分析法和高温氧化-化学发光检测法的测定范围更宽,精密度、准确度更好,3种样品的加标回收率达到96.2%~101%;高温氧化-化学发光检测法分析效率高、物料消耗少、节能环保,适用于一般海水样品的批量分析,且由于测定范围大,该法也适用于TN浓度较高的海水样品的批量分析,流动注射分析法因其较低的检出限更适用于TN浓度较低的海水样品的批量分析。     

Relationship between metabolic enzyme activities and bioaccumulation kinetics of PAHs in zebrafish (Danio rerio)

Many studies have investigated bioaccumulation and metabolism of polycyclic aromatic hydrocarbons (PAHs) in aquatic organisms. However, lack of studies investigated both processes simultaneously, and the interaction between these two processes is less understood so far. This study investigated the bioaccumulation kinetics of PAHs and metabolic enzyme activities, including total cytochrome P450 (CYPs) and total superoxide dismutase (T-SOD), in zebrafish. Mature zebrafish was exposed to the mixture of phenanthrene and anthracene under constant concentration maintained by passive dosing systems for 16 days. The results showed that PAH concentrations in zebrafish experienced a peak value after exposure for 1.5 days, and then decreased gradually. The bioaccumulation equilibrium was achieved after exposure for 12 days. Both of the uptake rate constants (k_u) and the elimination rate constants (k_e) decreased after the peak value. The variation of PAH concentrations and metabolic enzyme activities in zebrafish had an interactive relationship. CYPs and T-SOD activities increased initially with the increase of PAH concentrations, but decreased to the lowest state when PAH concentrations reached the peak value. When the bioaccumulation equilibrium of PAHs was achieved, CYPs and T-SOD activities also reached the steady state. In general, CYPs and T-SOD activities were activated after exposure to PAHs. The decrease of PAH concentrations in zebrafish after the peak value may be attributed to the great drop of k_u and the variation of CYPs activities. This study suggests that an interactive relationship exists between bioaccumulation kinetics of PAHs and metabolic enzyme activities in aquatic organisms.     

污染物排放总量控制工作的若干思考和建议

分析了目前污染物排放总量控制工作中存在的问题。给出了总量控制目标确定的依据和方法。提出了总量控制计划分配的原则和分配步骤。分别从现有污染源总量控制、新建项目总量控制．区域总量控制等方面提出了监督管理的要求。且对考核总量控制计划完成情况提出了具体要求。对总量控制工作中应注意的问题提出了若干建设性的想法。     

Analysis and fate of acephate and its metabolite,methamidophos, in pepper and cucumber

Abstract

Levels of acephate (Orthene^R) and its principle metabolite, methamidophos, in/on greenhouse‐grown pepper and cucumber fruits and leaves in relation to the applied methamidophos were monitored. Dislodgeable and total residues of acephate and methamidophos were determined by gas‐liquid chromatography equipped with a flame ionization detector (GC‐FID) and were confirmed by nitrogen phosphorus detector (GC‐NPD). The dissipation curves of the residues followed first‐order kinetics (R²> 0.96). Initial residues of acephate on fruits varied between pepper (15.12 ppm) and cucumber (2.16 ppm) . Total residues in fruits and leaves determined at intervals following application revealed the greater persistence of acephate on pepper fruits (half‐life [t_1/2] of 6 d) than on cucumber fruits (t_1/2 was 3.7 d) . T_1/2 values for the applied methamidophos were 4.7 and 5.3 d on pepper and cucumber fruits, respectively. Deacety‐lation of acephate (formation of its metabolite) was detectable 1 d following acephate treatment and reached a maximum of 2.05% of initial acephate residues 3 d after application on pepper fruits. On cucumber fruits, acephate metabolite reached a maximum of 2.12% one wk following application. No acephate residues were detected above the limit of detection of 0.001 ppm in pepper fruits 50 d following acephate application while its metabolite was detectable at that time (detectability limit was 0.0001 ppm).     

Experimental study on the impact of temperature on the dissipation process of supersaturated total dissolved gas

Water temperature not only affects the solubility of gas in water but can also be an important factor in the dissipation process of supersaturated total dissolved gas （TDG）. The quantitative relationship between the dissipation process and temperature has not been previously described. This relationship affects the accurate evaluation of the dissipation process and the subsequent biological effects. This article experimentally investigates the impact of temperature on supersaturated TDG dissipation in static and turbulent conditions. The results show that the supersaturated TDG dissipation coefficient increases with the temperature and turbulence intensity. The quantitative relationship was verified by straight flume experiments. This study enhances our understanding of the dissipation of supersaturated TDG. Furthermore, it provides a scientific foundation for the accurate prediction of the dissipation process of supersaturated TDG in the downstream area and the negative imp）acts of high dam projects on aquatic ecosystems.     

均匀设计优化试验条件-原子荧光法测定污泥中总砷

通过对试验条件进行优化,建立了一种改进的氢化物发生-原子荧光光谱法测定污泥中总砷的方法。采用了均匀设计〔U10*(108)〕与单因子试验相结合以研究和优化分析参数和条件。在优化的试验条件下进行总砷含量的测定,方法检出限为0.21 mg kg-1,线性范围为0.24-100μg L-1,加标回收率在91.0%-94.5%之间。测定11份有证土壤样品(浓度值10.7±0.8 mg kg-1)的相对标准偏差(RSD,n=5)为1.6%。该方法经标准样品验证后,成功用于污泥实际样品的测定,并取得满意的结果。     

A forecast analysis on world population and urbanization process

The continuous growth of world population and the intensification of urbanization process create a challenge to environment quality and sustainable development around the world. In this paper I tried to conduct a forecast analysis of near-future urbanization related population growth worldwide, based on recent demographic trends. Such an analysis can provide important insights into the prospects for changes in the size and composition of world population and in urbanization process. Optimal polynomial functions were used to fit historical trajectories of population dynamics, and the detailed forecasts of the population mainly over the period 2010–2030 were conducted and analyzed. If the past pattern continues, world total population would increase to 7.94–8.33 billion in 2030 and the annual growth is expected to continually decline in the forecast period. Global total population would stop increasing during the period 2050–2060 and would not exceed 9.5 billion in the future. The total population of Africa, Asia, Oceania, South America, North & Central America would separately increase to 1.35–1.41, 4.86–5.65, 0.04–0.05, 0.44–0.45, and 0.71–0.72 billion in 2030. Europe’s total population is forecast to decline to 0.64–0.67 billion in 2030. World’s rural population is expected to grow to the maximum during the period 2015–2020 and would greatly decline after that period. Global rural population would reach 3.12–3.41 billion in 2030. Rural population in Asia and Africa is estimated to increase and achieve the maximum around 2025 and decline thereafter. For other regions, the rural population would continually decline in the forecast period. Urban population in the world would continually grow and reach 4.72–5.00 billion in 2030, an increase of 48.6–57.8%. However the annual growth of urban population is expected to increase to the maximum (6.86 million/year) during the period 2020–2025 and then decline in the following years. Urban population is projected to continually grow in all regions excepting Europe. Europe’s urban population is expected to decline in the period 2010–2030. Urbanization process worldwide, represented by the ratio urban population versus total population (RUT) and the ratio rural population versus urban population, is expected to continue during the period 2010–2030. The RUT of the world is projected to reach 0.5 before 2010 and would continue to increase in the forecast period. Global RUT is estimated to reach 0.56 in 2030. However, the regional patterns of urbanization process would be diverse. Europe’s RUT is estimated to continually decline in the forecast period and reach 0.68 in 2030. The RUT for Africa and Caribbean would continually increase before 2030, while the RUTs for Asia and South America are estimated to achieve their maximums around 2025 and decline in the following years. Oceania and North & Central America would thoroughly realize urbanization (≈1) during the periods 2020–2025 and 2025–2030. The expansion of world population and urbanization will continually exert a stronger stress to environment quality and sustainable development in a near future. However we may expect this situation would start to change from mid-21st century after total population has achieved its maximum. Readers should send their comments on this paper to BhaskarNath@aol.com within 3 months of publication of this issue.     

以“零污染”为目标加强清洁生产的全面质量管理

通过对江苏油田清洁生产试点单位环保工作的全面总结，提出了当前油田清洁生产必须走管理与科技结合的道路，加强清生产的全面质量管理，并针对清洁生产过程如何消除污油，污水，尾气，套管气对环境的污染均提出了自己的思路。