Adsorption kinetics and isotherms of pesticides onto activated carbon-cloth

Adsorption of pesticides ametryn, aldicarb, dinoseb and diuron from aqueous solution onto high specific area activated carbon-cloth was studied. Kinetics of adsorption was followed by in situ UV-spectroscopy and the data were treated according to various rate models. The extent of adsorption was determined at the end of 125 min adsorption period. Rate constants and the extent of adsorption for the four pesticides were found to follow the order: dinoseb > ametryn > diuron > aldicarb. Adsorption isotherms were derived at 25 °C on the basis of batch analysis. Isotherm data were treated according to Langmuir and Freundlich models. The fits of experimental data to these equations were examined. The types of interactions between the surface and pesticide molecules were discussed.     

液液萃取-气相色谱/串联质谱法测定水中五氯酚及其钠盐

采用液液萃取处理水样,用气相色谱-串联质谱法测定样品中五氯酚及其钠盐,通过优化测定条件,使方法在1.00μg/L～500μg/L范围内线性良好.检出限和定量限分别为1.00μg/L和5.00μg/L,空白水样五氯酚钠3个质量浓度水平的加标回收率为89.8％～98.4％,5次平行试验测定结果的RSD为5.5％～10.7％...     

江苏省太湖流域水生态健康评估的初步实践及展望

阐述了水生态健康的内涵与意义,从江苏省率先在太湖流域开展水生态环境功能分区管理的顶层设计,构建以水生态健康指标为核心的水生态健康评估技术体系,地方对照水生态环境功能区划的水生态分级管控目标开展的应用与实践结果等3个方面,回顾了江苏省太湖流域水生态健康评估工作的主要进展,提出了完善水生态健康评估技术体系和推进流域水生态健康评估工作的建议。     

Water sharing agreements sustainable to reduced flows

By signing a water sharing agreement (WSA), countries agree to release an amount of river water in exchange for a negotiated compensation. We examine the vulnerability of such agreements to reduced water flows. Among all WSAs that are acceptable to riparian countries, we find out the one which is self-enforced under the most severe drought scenarios. The so-called upstream incremental WSA assigns to each country its marginal contribution to its followers in the river. Its mirror image, the downstream incremental WSA, is not sustainable to reduced flow at the source. Self-enforcement problems can be solved by setting water releases and compensations contingent to water flow. We apply our analysis to the Aral Sea Basin. We compute the upstream incremental compensations for the Bishkek agreement and asses its vulnerability with historical flows.     

河湖水环境问题及管理和治理模式

本文首先介绍了我国当前的河湖水环境现状,分析了我国水资源存在的一系列问题,主要问题包括水体污染和富营养化;河湖面积严重萎缩,河湖水的功能逐渐退化;难以降解的有机污染物污染量加大。有针对性地提出了改善我国河湖水环境的管理以及治理模式,进一步落实了保护河湖水环境工作,加强水资源周围生态环境的文明建设,实现河湖水环境的可持续发展。     

探究城市污水处理项目的环境影响评价

水作为人类赖以生存的主要能源物质,随着社会综合水平的提高,各行业对水资源的需求越是急切。而现阶段城市中大量污水给环境带来很多不利影响,环保公司针对城市污水处理不断在技术上进行突破、完善,将智能化节能技术运用到城市污水处理中,使设备、资源得到充分利用,为人们用水条件带来更加充沛、丰富的保障与支持。为有效处理城市污水,争取在城市污水处理发挥更大作用,带动城市环境可持续发展。     

不同给水管材对管壁附着生物膜铅、镉的解吸动力学研究

给水管壁生物膜会吸附水中的重金属元素积累在管壁生物膜中,在受到扰动时释放回到水体,危害饮用水水质安全。试验以上海管网末梢水为实验对象,研究了PVC、铸铁和紫铜等三种管材上生物膜对铅、镉的解吸特性。结果表明,PVC、铸铁和紫铜附着生物膜对铅的解吸容量qe分别为:5.92211μmol·m^-2、128.3051μmol·m^-2和21.1808,解吸速率常数k分别为:0.001060 m^2·μmol^-1·min^-1、0.000041 m^2·μmol^-1·min^-1和0.000503 m^2·μmol^-1·min^-1,对于镉元素三种材质的解吸容量qe分别为:14.71519μmol·m^-2、18.50481μmol·m^-2和2.25225μmol·m^-2;解吸速率常数k分别为:0.000102 m^2·μmol^-1·min^-1、0.001070 m^2·μmol^-1·min^-1和0.000103 m^2·μmol^-1·min^-1。     

关于城市河流水污染防治技术应用和研究

随着我国经济的不断发展,各种工厂也大量的成立,而这也使得很多废弃物及废水被过度排放到湖泊与河流之中,进而导致其出现了严重的污染问题。污染不仅对人们的生活质量产生了影响,同时也对生态的平衡发展产生了很大的阻碍,业已经成为社会各界高度关注和重视的问题。基于此,本文围绕城市河流水污染的现状进行了分析,对于污染产生的原因也进行了阐述,针对城市河流水污染防治技术的应用也进行了探讨和研究,以期可以有效解决我国出现的河流水污染问题,进而为人们及社会营造一个全新、绿色的河流环境。     

Listing for change? Exploring the politics of relief lists in Bangladesh after Cyclone Sidr

Ideal notions of efficient aid are challenged continuously by realities on the ground in the wake of major disasters, such as dire needs, limited resources, and opportunism. This paper demonstrates how ‘relief lists’ can be productive entry points for a systematic inquiry into the pervasive politics of disaster assistance. Through an analysis of qualitative data collected during the five years after Cyclone Sidr struck Bangladesh on 15 November 2007, it examines how relief lists featured in both physical and phantom forms and then developed beyond their transparency-making aims, becoming elevated sites of struggle for post-disaster resources. Three list processes, selected to indicate the temporal, material, and spatial dynamics of relief encounters, are assessed in depth. Although recipients of cyclone relief appreciated its value, the paper argues that list politics also stimulated structures of vulnerability, including inequality. Gradually, relief, as governed after Sidr, also served to restore the differential vulnerability of the country's coastal poor.     

土壤渗滤处理系统运行控制的模拟研究

通过建立地下水数学模型,回答了土壤渗滤工程运行控制中的两个难点问题:(1)工程运行水力负荷.当工程地块周边存在河流时,河流水位低时,有助于增加水力负荷,反之则降低水力负荷;实际土壤运行面积的增加和独立运行单元之间的间距增加也能够增加工程运行水力负荷.(2)地下水水质监测井的优化布设.模拟工程运行后地下水水质空间分布特征,在地下水水质最不利的位置和其他特别关注的位置布置监测井,从而能够以具有典型代表性且数目较少的监测井达到准确评估工程对地下水水质影响的目的.