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231.
环境激素具有类雌激素活性 ,能对生物和人体的内分泌机能造成影响 ;环境激素污染可导致各种生物的生殖功能下降和生殖器免疫力降低 ,并引起各种生理异常。本文对国内外环境重金属激素和有机激素的研究进行了综述 ,并总结了防治环境激素污染的主要技术手段 ;指出环境激素致毒生物化学机理研究、环境激素在环境介质中的迁移 转化 积累的行为研究、环境激素容量分析以及环境激素物质的进一步筛选是国际环境科学领域的重要研究方向和前沿领域。 相似文献
232.
Jochen Harnisch Reinhard Borchers Peter Fabian 《Environmental science and pollution research international》1995,2(4):229-232
Measurements of carbonyl sulfide (COS) and carbondisulfide (CS2) were carried out on samples drawn from a smoke stack of an aluminium smelter. Volume mixing ratios of 6 ppm COS and 0.1
ppm CS2 were measured for gases from the electrolysis unit that had previously passed an Al2O3 fluid bed reactor and electrostatic precipitators. Specific emissions of 1.6 kg COS and 0.03 kg CS2 per ton of primary aluminium were found. Extrapolating from this particular smelter’s conditions to a world mix specific
COS emissions of about 4 kg/t(Al) are calculated resulting in emissions of annually 0.08 Tg COS into the atmosphere due to
electrolytic aluminium production in 1995. Besides the photochemical conversion of anthropogenic CS2 aluminium production is established to be the second major industrial source of COS probably exceeding automotive tire wear’s
and coal combustion’s contributions. 相似文献
233.
气溶胶中多环芳烃光降解的初步研究 总被引:6,自引:0,他引:6
本文以大容量空气脱悬浮微粒采样器采集了大气中的气溶胶样品,以石英滤膜为载体,研究了气溶胶中的多环芳烃在紫外光照下的光降解规律。 相似文献
234.
Sergio Rodríguez Xavier Querol Andrés Alastuey Jesús de la Rosa 《Environmental Chemistry Letters》2007,5(1):1-7
This article synthesises the results obtained in several projects on atmospheric aerosol (particulate matter – PM) pollution
developed during the last years in the Western Mediterranean. It focuses on particulate matter sources and the strategies
for suitable monitoring in ambient air. The article has been structured in several sections that give response to the main
questions that prompted these studies. After analysing the main PM features in the Mediterranean, a brief review of the main
factors differentiating the particulate matter composition with respect to Central Europe is presented. Finally, the suitability
of the different metrics or parameters for monitoring ambient air PM levels in different types of environments is discussed.
Selected article from the 6th European Meeting on Environmental Chemistry, University of Belgrade, Serbia and Montenegro organized
by Prof. Dr. Branimir Jovancicevic (www.research.plymouth.ac.uk/ace). 相似文献
235.
用扫描电镜分析表征大气气溶胶单颗粒 总被引:6,自引:0,他引:6
1 IntroductionAtmosphericaerosolsarecomplexmixture,originatedfromavarietyofsources.Mostoftheanalyticaltechniquesusedforitscharacterizationarebulkmethodsthatgenerateonesetofdatapersample,describingtheoverallcompositionofthesample .Toworkoutusefulinformationonpollu tionsources,itrequiresdataofagreatnumberofsamplesandmultivariatedataanalysismethodsusuallyareneeded .Ontheotherhand ,scanningelectronmicroscope energydispersiveX rayanaly sissystem (SEM EDX)isabletoprovideanalyticaldataforeachsing… 相似文献
236.
The South pole aera offers one of the best locations on the Earth for studying the composition of the background aerosol. For this purpose, aerosol samples were collected in particle size fractions by 8 stages cascade impactors. Aerosol sampling was begun in Jan. and finished in Dec. 1986 at the St. Great Wall, South Pole. The samples were analysed by Proton Induced X-ray Emission (PIXE) method. In order to learn the enrichment factors of various elements all the results were separated into two groups: coarse (> 10μm) and fine (< 10μm) particles. The correlation coefficients of elements of both coarse and fine particles were discussed. The aerosol levels measured at St. Great Wall were compared to those recently measured at some other locations. It can be concluded the South Pole is a good background area on the Earth. 相似文献
237.
238.
为深入探究高ρ(PM2.5)地区重污染过程的发展变化规律,以石家庄市一次重污染过程(2017年1月13-20日)为例,结合空气质量监测数据、PM2.5组分测试数据、气象观测资料,从重污染发展阶段(简称"P1阶段")、维持阶段(简称"P2阶段")和清除阶段(简称"P3阶段")分析PM2.5及其化学组分的变化特征、气象条件和高低空天气形势演变特征,并利用WRF-Chem模型定量研究重污染过程气溶胶反馈效应对典型气象要素的影响.结果表明:①此次重污染过程属于逐步累积增长、快速清除型,在P2阶段ρ(PM2.5)平均值为241.0 μg/m3,最大值为367.5 μg/m3.②P1和P2阶段高低空大气环流配置稳定,大气边界层高度范围为620.6~712.2 m,风速范围为1.3~2.5 m/s,相对湿度范围为60%~80%.③P2阶段SOR(硫氧化率)和NOR(氮氧化率)均为0.3,ρ(SNA)(SNA为SO42-、NO3-和NH4+的统称)为128.8 μg/m3,占ρ(PM2.5)的56.2%;OM[有机质,ρ(OM)=ρ(POA)+ρ(SOA),其中,POA为一次有机气溶胶,SOA为二次有机气溶胶]是除SNA以外的第二大组分,在P1和P3阶段ρ(POA)大于ρ(SOA),而在P2阶段ρ(SOA)与ρ(POA)相等,均为28.0 μg/m3,表明在重污染过程中二次污染严重;整个污染过程ρ(NO3-)/ρ(SO42-)为1.0,表明石家庄市移动源和固定源对ρ(PM2.5)贡献相当.④WRF-Chem模型模拟结果表明,太阳辐射量、温度和大气边界层高度受气溶胶反馈效应的影响在P2阶段的下降量分别为75.1 W/m2、2.7℃和109.9 m,比P1阶段分别高33.6%、91.4%和18.6%,比P3阶段分别高147.0%、305.3%和24.1%.研究显示,此次静稳天气下的重污染过程二次污染严重,气溶胶反馈效应整体使得太阳辐射量、温度和大气边界层高度均向不利于污染扩散的趋势发展,造成石家庄市的ρ(PM2.5)进一步增加. 相似文献
239.
使用2015~2018年MODIS AOD产品融合地表气象资料反演了地面细颗粒物(PM2.5)浓度,并以反演的PM2.5浓度为依据,比较了地面PM2.5观测资料的各种空间插值方法.结果表明:2015~2018年反演的PM2.5平均浓度与地基观测平均浓度的R2达0.94;干季反演效果好于湿季,珠江三角洲反演效果好于非珠江三角洲地区,原因是湿季天气系统较不稳定,非珠江三角洲地区多山脉和秸秆燃烧,导致气溶胶标高、质量消光效率等假设误差较大.使用4种插值方法对地基观测的PM2.5浓度进行插值,插值结果大致相当,反距离加权插值法较好,站点分布不均、部分区域站点密度小影响插值效果,建议在站点稀疏地区增加地面PM2.5观测站点. 相似文献
240.
Human exposure to contaminants from electronic cigarettes(e-cigarettes) and the associated health effects are poorly understood.There has been no report on the speciation of arsenic in e-liquid(solution used for e-cigarettes) and aerosols.We report here determination of arsenic species in e-liquids and aerosols generated from vaping the e-liquid.Seventeen e-liquid samples of major brands,purchased from local and online stores in Canada and China,were analyzed for arsenic species using high-performance liquid chromatography and inductively coupled plasma mass spectrometry.Aerosols condensed from vaping the eliquids were also analyzed and compared for arsenic species.Six arsenic species were detected,including inorganic arsenate(iAs~Ⅴ),arsenite(iAs~Ⅲ),monomethylarsonic acid(MMA),and three new arsenic species not reported previously.In e-liquids,iAs~Ⅲ was detected in 59%,iAs~Ⅴ in 94%,and MMA in 47% of the samples.In the condensate of aerosols from vaping the e-liquids,iAs~Ⅲ was detected in 100%,iAsv in 88%,and MMA in 13% of the samples.Inorganic arsenic species were predominant in e-liquids and aerosols of e-cigarettes.The concentration of iAs~Ⅲ in the condensate of aerosols(median 3.27 μg/kg) was significantly higher than that in the e-liquid(median 1.08 μg/kg) samples.The concentration of inorganic arsenic in the vaping air was approximately 3.4 μg/m~3,which approaches to the permissible exposure limit(10 μg/m~3) set by the United States Occupational Safety and Health Administration(OSHA).According to the Environmental Protection Agency's unit risk factor(4.3 × 10~(-3) per μg/m~3) for inhalation exposure to inorganic arsenic in the air,the estimated excess lung cancer risk from lifetime exposure to inorganic arsenic in the ecigarette vaping air(3.4 μg/m~3),assuming e-cigarette vaping at 1% of the time,is as high as1.5 × 10~(-4).These results raise health concerns over the exposure to arsenic from electronic cigarettes. 相似文献