邯钢焦化厂回收系统废气净化工艺的改进

介绍了邯钢焦化厂煤气回收系统废气净化工艺的操作情况及存在的问题,指出了改造后的净化工艺的特点和效果。     

膜吸收器吸收CO2的影响因素研究

采用聚丙烯中空纤维膜吸收器,用水、NaOH和K2CO3 水溶液作为吸收剂进行高浓度CO2 吸收试验,考察了气体流率、吸收剂流率、质量分数以及流动方式对吸收率、传质系数和传质速率的影响.结果表明,随着气体流率增大,CO2的吸收率递减,总传质系数和总传质速率增加.在一定的气体流率下,吸收液流率增大,CO2的吸收率、总传质系数和总传质速率增大;吸收液浓度提高,吸收率增大,总传质系数和总传质速率提高.在气体流率较低时,质量分数为5%和8%的NaOH水溶液为吸收剂时的吸收率、总传质系数和总传质速率比较接近.随着气体流率增大,NaOH质量分数为8%时的吸收率、总传质系数和总传质速率增加的值大大超过NaOH质量分数为5%时增加的值.以水为吸收剂时,气体与吸收剂的流动方式为逆流时的吸收率、总传质系数和总传质速率高于并流时的值.     

敌百亩和阿米津的太赫兹透射光谱研究

为获得敌百亩和阿米津两种农药在太赫兹频段内的光学参数,完善常用农药太赫兹光谱数据库,利用太赫兹时域光谱技术(THz-TDS),在室温294 K和氮气环境(湿度小于4%)下,对两种农药标准样品进行测试。获得了两种农药的太赫兹时域信号,并利用傅里叶变换和菲涅尔公式得到0.3~1.5 THz频段内的折射率谱和吸收谱。结果表明,敌百亩和阿米津的平均折射率分别为1.59和1.55,敌百亩吸收谱有3个吸收峰,阿米津有2个吸收峰,且两者吸收峰的位置与峰值存在明显的差异。相对于阿米津,敌百亩对于太赫兹波有更好的吸收特性。试验光谱特征说明,利用THz-TDS可以实现对农药的检测与鉴别。     

粉末活性污泥处理含铀废水的特性

以生活污水处理厂剩余活性污泥为原料,制备粉末活性污泥(PAS)作为生物吸附剂,考察p H值,PAS投加量,U(Ⅵ)初始浓度和吸附时间对PAS吸附U(Ⅵ)的影响,探讨了PAS吸附U(Ⅵ)的作用机理。实验结果表明,在U(Ⅵ)初始浓度为10 mg/L时,其最佳吸附p H值为3,去除率97.77%,吸附平衡时间120 min;吸附过程较好地拟合了准二级动力学模型(R2≈1)和Freundlich等温模型(R2≈1);X射线能谱和离子交换实验分析表明,离子交换为其主要吸附方式,参与交换的主要离子为Ca2+;红外光谱分析表明,PAS吸附U(Ⅵ)后自身结构未发生改变。以0.1 mol/L的HCl溶液作为解吸液,初次解吸率达92.83%,循环利用3次仍具有较好的吸附效果。     

除草剂对植物光合作用和吸肥能力影响初探

本文应用P~(32)、C~(14)同位素示踪技术研究棉花与大豆施用三种除草剂对植物吸肥能力和光合作用的影响。结果表明,拿捕净抑制棉花对P~(32)的吸收,稳杀得反而起促进作用,禾草克影响不明显,三种除草剂对光合作用的抑制影响,稳杀得>拿捕净>禾草克。施药一周后,大豆和棉花的光合作用已恢复正常,施用拿捕净和稳杀得的两种作物对P~(32)的吸收均起促进作用,而施用禾草克的作物对P~(32)吸收已逐趋正常。     

Associations of trace elements in aerosol at the south Adriatic coast

We applied statistical methods to the data of a 5-year sampling period to characterize the features of trace elements in airborne particulate matter at the South Adriatic Coast. The analysis of surface soil samples was also performed. The data were processed by cluster analysis, enrichment factor determination and receptor rose statistics. It is shown that the principal element association consists of Fe, Mn and Ti originating from surface material resuspension. Hg and Se were shown to originate from more complex natural and anthropogenic processes. A strong emission source of Cd and Se was identified in the SSE direction.Selected article from the Regional Symposium on Chemistry and Environment Krusevac, Serbia, June 2003, organized by Dr. Branimir Jovancicevic.     

哈尔滨市松花江段水质自然净化机理分析与水环境保护策略

河流水体受污染后，在自然环境因素的影响下由各种物理、化学及生物作用能得到一定的净化。哈尔滨市松花江段河流水质净化作用主要包括稀释、吸附、江底沉积物的机械过滤与吸附和絮凝沉淀作用。哈尔滨市松花江断面正处于河流侵蚀与堆积交替动态平衡中，可不断提供新的活性表面，使河底沉积物的净化作用持久不衰。该特殊的地质条件是本段河流保持较强净化作用的关键，妥善利用水环境净化能力是一种经济有效的水污染控制手段。     

Canopy structure versus physiology effects on net photosynthesis of mountain grasslands differing in land use

The present paper aims at investigating how changes in canopy structure and species physiology associated with the abandonment of mountain meadows and pastures affect their net photosynthesis. For this purpose, a multi-layer vegetation–atmosphere transfer (VAT) model is employed, which explicitly takes into account the structural and functional properties of the various canopy components and species. Three sites differing in land use are investigated, a meadow, a pasture and an abandoned area. Model simulations agree reasonably with measured canopy net photosynthetic rates, the meadow featuring the highest daily net photosynthesis, followed by the pasture and, finally, the abandoned area. A detailed process analysis suggests this ranking to be mainly due to bulk canopy physiology, which decreases from the meadow to the pasture and the abandoned area, reflecting species composition and species-specific photosynthetic capacities. Differences between the canopies with regard to canopy structure are found to be of minor importance. The amounts of green, photosynthetically active plant matter are too similar at the three sites to be a major source of variation in net photosynthesis. Large differences exist between the canopies with regard to the amount of photosynthetically inactive phytoelements. Even though a model analysis showed them to be potentially important, most of them are accumulated close to the ground surface, where they exert little influence on canopy net photosynthesis.     

取代芳烃对绿藻、斜生栅列藻急性毒性的自相关拓扑指数

本文提出新的原子生物活性值 (ai) ,由其建构自相关拓扑指数 ( mL) . 1 6种氯代芳烃对绿藻的急性毒性 ( -lgEC50 )与其0 L ,1L的回归方程为 :-lgEC50 =0 6 1 99+2 6 1 6 3× 1 0 - 6　1L2 5+ 0 0 0 92 0 L ,r=0 936 3. 1 8种苯酚、苯胺类化合物对斜生栅列藻的急性毒性 ( -lgEC50 )可以表示为 :-lgEC50 =1 1 374 + 0 1 4 4 71L0 6+ 0 0 0 2 70 L,r=0 95 35 .用Jackknife法检验 ,以上模型具有总体稳健性 .     

原子吸收分光光度法测定植株中钙、镁的几种样品前处理方法的比较

本文比较了原子吸收分光光度法测定植株中钙、镁的三种样品前处理方法：干友化法、１ｍｏｌ／ＬＨＣｌ振荡提取法（振荡法）和１ｍｏｌ／ＬＨＣｌ静止浸泡提取法（浸泡法）．结果表明，振荡法和浸泡法对钙的测定结果平均分别为干灰化法的１０１％和９２．０％，对镁的测定结果平均分别为１０３％和９７．６％．振荡法和浸泡法与干灰化法之间不存在显著性差异（α＝０．０５），它们之间有极显著的正相关性（相关系数在０．９９以上）．因此，在大批量样品的常规分析中，１ｍｏｌ／ＬＨＣｌ提取法可代替干灰化法．