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991.
992.
Affum HA Oduro-Afriyie K Nartey VK Adomako D Nyarko BJ 《Environmental monitoring and assessment》2008,137(1-3):15-24
Lichens collected in an unpolluted forest (background) in November 2004, transplanted at 41 sampling sites along the Madina-Tetteh
Quarshie road, retrieved in February 2005 and analysed were found to contain higher concentrations of Manganese (Mn), Vanadium
(V), lead, Cadmium (Cd), Chromium (Cr) and Nickel (Ni) than in the background area. Observations showed that of all the heavy
metals studied, Manganese concentrations were highest at all sampling points with maximum values around a traffic light, an
intersection and car fitting/mechanic workshops. Significant correlations were found between Ni and Mn, Mn and Cr and Mn and
V. Statistical analysis also revealed a relatively even dispersion of the studied elements on the eastern side of the road
than on the western side. 相似文献
993.
The concentrations, distribution and sources of PAHs in agricultural soils and vegetables from Shunde, Guangdong, China 总被引:4,自引:0,他引:4
Li YT Li FB Chen JJ Yang GY Wan HF Zhang TB Zeng XD Liu JM 《Environmental monitoring and assessment》2008,139(1-3):61-76
The concentrations, distribution and sources of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in 30 agricultural
soil and 16 vegetable samples collected from subtropical Shunde area, an important manufacturing center in China. The total
PAHs ranged from 33.7 to 350 μg/kg in soils, and 82 to 1,258 μg/kg in vegetables. The most abundant individual PAHs are phenanthrene,
fluoranthene, chrysene, pyrene and benzo(b)fluoranthene for soil samples, and anthracene, naphthalene, phenanthrene, pyrene
and chrysene for vegetable samples. Average vegetable–soil ratios of total PAHs were 2.20 for leafy vegetables and 1.27 for
fruity vegetables. Total PAHs in vegetable samples are not significantly correlated to those in corresponding soil samples.
Principal component analyses were conducted to distinguish samples on basis of their distribution in each town, soil type
and vegetable specie. Relatively abundant soil PAHs were found in town Jun’an, Beijiao, Chencun, Lecong and Ronggui, while
abundant vegetable PAHs were observed in town Jun’an, Lecong, Xingtan, Daliang and Chenchun. The highest level of total PAHs
were found in vegetable soil, followed by pond sediment and “stacked soil” on pond banks. The PAHs contents in leafy vegetables
are higher than those in fruity vegetables. Some PAH compound ratios suggest the PAHs derived from incomplete combustion of
petroleum, coal and refuse from power generation and ceramic manufacturing, and paint spraying on furniture, as well as sewage
irrigation from textile industries. Soil PAHs contents have significant logarithmic correlation with total organic carbon,
which demonstrates the importance of soil organic matter as sorbent to prevent losses of PAHs. 相似文献
994.
Pesch R Pehlke H Jerosch K Schröder W Schlüter M 《Environmental monitoring and assessment》2008,136(1-3):313-325
In this article a concept is described in order to predict and map the occurrence of benthic communities within and near the
German Exclusive Economic Zone (EEZ) of the North Sea. The approach consists of two work steps: (1) geostatistical analysis
of abiotic measurement data and (2) calculation of benthic provinces by means of Classification and Regression Trees (CART)
and GIS-techniques. From bottom water measurements on salinity, temperature, silicate and nutrients as well as from punctual
data on grain size ranges (0–20, 20–63, 63–2,000 μ) raster maps were calculated by use of geostatistical methods. At first
the autocorrelation structure was examined and modelled with help of variogram analysis. The resulting variogram models were
then used to calculate raster maps by applying ordinary kriging procedures. After intersecting these raster maps with punctual
data on eight benthic communities a decision tree was derived to predict the occurrence of these communities within the study
area. Since such a CART tree corresponds to a hierarchically ordered set of decision rules it was applied to the geostatistically
estimated raster data to predict benthic habitats within and near the EEZ. 相似文献
995.
植物大气污染响应高光谱监测实例研究 总被引:2,自引:0,他引:2
选择某钢铁企业绿化树种桂花当年生叶片作为供试样本,测试叶片光谱反射率之后分别测试叶液pH值、叶片含硫量、叶绿素含量、叶片含水量,研究生长在S02 污染环境下桂花叶片光谱的变化以及相应的部分生理生化指标的变化.研究表明,污染较严重生产区采集的叶片光谱反射率和红边斜率均较生活区低.叶片含硫量随大气SO2 浓度的增减而相应地变化,叶片叶绿素含量、叶液pH值、叶片含水量的变化规律与叶片含硫量和大气SO2浓度的变化规律相反. 相似文献
996.
通过采集了2004~2006年北京市昌平区四个季节中大气PM10样品,采用超声抽提方法,使用GC/MS分析了该区PAHs含量和组成.结果显示,三年中四个季度的18种PAHs总量范围分别为21.64~656.39ng/m3、31.94~164.33ng/m3和7.294~209.3ng/m3,其中致癌性极强的苯并[a]芘含量范围为2.69~36.95 ng/m3、1.44~6.6ng/m3和0.256~8.625ng/m1,其变化趋势与PAHs总量有较好的相关性.PAHs的浓度是冬季>秋季>夏季>春季,这与夏季时雨水冲刷和阳光照射强度大导致PAHs光解,冬季时燃煤排放大等影响因素有关.文章还使用多种方法判断昌平区大气PM10中的PAHs主要来源于燃煤和汽车尾气,其它污染源贡献较小. 相似文献
997.
渭河干流(宝鸡段)表层沉积物Cu、Zn、Pb污染特征与评价 总被引:7,自引:2,他引:5
对渭河干流(宝鸡段)表层沉积物中重金属Cu、Zn、Pb含量进行了调查,用潜在生态危害系数法对其污染水平进行了评价,并与松花江(吉林市段)、淮河(江苏段)、长江(下游)、苏州河、珠江(广州段)5条河流表层沉积物中Cu、Zn、Pb的含量做了对比研究。结果表明,3种重金属元素平均含量均超出相应的土壤背景值,出现了一定程度上的富集;生态危害系数均〈40,属轻微生态危害。重金属含量水平在国内诸河中处于中间位置。 相似文献
998.
999.
研究了顶空固相微萃取-气相色谱质谱联用测定饮用水中二甲基异冰片和土味素的方法。结果表明,当选用聚二甲基硅氧烷(PDMS)萃取纤维萃取头,萃取温度为60℃,萃取时间为40min时,得到二甲基异冰片标准曲线方程为y=122.59+157.76x,相关系数(R)0.9998;土味素的标准曲线方程为y=14.847+180.99x,相关系数(R)0.9999;检出限为0.1ng/L,相对标准偏差在0.99%~4.05%之间,加标回收率86.4%~109.5%。 相似文献
1000.
Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant 总被引:1,自引:0,他引:1
A new dithiocarbamate-type heavy metal precipitant, sodium 1,3,5-hexahydrotriazinedithiocarbamate (HTDC), was prepared and used to remove coordinated copper from wastewater. In the reported dithiocarbamate-type precipitants, HTDC possesses the highest percentage of the effective functional groups. It could effectively precipitate copper to less than 0.5 mg l−1 from both synthetic and actual industrial wastewater containing CuEDTA in the range of pH 3–9. UV–vis spectral investigation and elemental analysis suggested that the precipitate was a kind of coordination supramolecular compound, [Cu3(HTDC)2]n. The toxicity characteristic leaching procedure (TCLP) and semi-dynamic leaching test (SDLT) indicated that the supramolecular precipitate was non-hazardous and stable in weak acid and alkaline conditions. Tests of an anion exchange resin D231 provided a clue to simultaneously remove excess HTDC and residual CuEDTA in practical process of wastewater treatment. 相似文献