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41.
Lead, one of the earliest metals recognized and used by humans, has a long history of beneficial use. However, it is now recognized as toxic and as posing a widespread threat to humans and wildlife. Treatment of lead from polluted water and wastewater has received a great deal of attention. Adsorption is one of the most common technologies for the treatment of lead-polluted water. This technique was evaluated here, with the goal of identifying innovative, low-cost adsorbent. This study presents experiments undertaken to determine the suitable conditions for the use of peach and apricot stones, produced from food industries as solid waste, as adsorbents for the removal of lead from aqueous solution. Chemical stability of adsorbents, effect of pH, adsorbents dose, adsorption time and equilibrium concentration were studied. The results reveal that adsorption of lead ions onto peach stone was stronger than onto apricot stone up to 3.36% at 3 h adsorption time. Suitable equilibrium time for the adsorption was 3–5 h (% Pb adsorption 93% for apricot and 97.64% for peach). The effective adsorption range for pH in the range was 7–8. Application of Langmuir and Freundlich isotherm models show high adsorption maximum and binding energies for using these adsorbents for the removal of lead ions from contaminated water and wastewater.  相似文献   
42.
Ethephon, which releases ethylene within plant tissues after application, was chosen to perform assessments of the relative sensitivity of crops to ethylene and to determine which stages of plant development were most sensitive. The species chosen were: barley, wheat, oats, canola and field pea, all of which are important crops in the province of Alberta, Canada. Plants were treated with ethephon at one of 7 different stages. Plants were assessed for their vegetative and reproductive growth, including height, biomass, yield and seed quality. Visual symptoms were photographed and documented to compare them with symptoms caused by ethylene applied as a gas. It was concluded that in barley, wheat and canola the late vegetative and early reproductive stages were most sensitive, at least when sensitivity was defined as reductions in yield and quality. As for field pea, ethephon had no effect on yield but did cause increased numbers of pods, which in certain conditions could lead to increased yields. Significant effects on vegetative growth were only observed in the early vegetative stages of development but with no effects on yield. The screening protocol successfully identified sensitive cultivars and growth stages for further investigation of the effects of ethylene exposure.  相似文献   
43.
非活体生物质对水中活性艳红X-3B的吸附研究   总被引:9,自引:3,他引:6  
研究了4种非活体生物质(米酒糟、花生壳、柚子皮、稻草秸秆)对模拟废水中活性艳红X-3B的吸附条件及吸附机理。结果表明,活性艳红X-3B初始浓度为100 mg/L、pH为1.0~2.0、吸附剂浓度为10 mg/L时,4种吸附剂对活性艳红X-3B的吸附率可达到80%。吸附在60 min左右达平衡后最大吸附量的顺序为:米酒糟(58.8 mg/g)花生壳(28.0mg/g)柚子皮(23.6 mg/g)稻草秸秆(19.5 mg/g)。在达最大吸附率时,米酒糟的用量可减少一半、pH范围可宽为1.0~6.0,且吸附量是另三者的2倍以上。综合比较,米酒糟具有较强的吸附废水中活性艳红X-3B的能力,可作为废水中活性染料的吸附剂使用。而花生壳、柚子皮和稻草秸秆的吸附能力相对较弱,不是理想的吸附材料。数学模型模拟表明,米酒糟和柚子皮的吸附过程更符合Freundlich方程,而花生壳和稻草秸秆更符合Langmuir方程;动力学研究表明4种吸附剂的吸附拟合更符合拟二级动力学方程。  相似文献   
44.
Carbonaceous aerosols were studied at three background sites in south and southwest China. Hok Tsui in Hong Kong had the highest concentrations of carbonaceous aerosols (OC = 8.7 ± 4.5 μg/m3, EC = 2.5 ± 1.9 μg/m3) among the three sites, and Jianfeng Mountains in Hainan Island (OC = 5.8 ± 2.6 μg/m3, EC = 0.8 ± 0.4 μg/m3) and Tengchong mountain over the east edge of the Tibetan Plateau (OC = 4.8 ± 4.0 μg/m3, EC = 0.5 ± 0.4 μg/m3) showed similar concentration levels. Distinct seasonal patterns with higher concentrations during the winter, and lower concentrations during the summertime were observed, which may be caused by the changes of the regional emissions, and monsoon effects. The industrial and vehicular emissions in East, Southeast and South China, and the regional open biomass burning in the Indo-Myanmar region of Asia were probably the two major potential sources for carbonaceous matters in this region.  相似文献   
45.
鄱阳湖典型苔草湿地生物量季节变化及固碳功能评价   总被引:4,自引:0,他引:4  
为进一步评估鄱阳湖湿地碳平衡,量化湿地固碳功能,于2009年9月~2011年5月,在鄱阳湖南矶湿地国家级自然保护区,选择以灰化苔草为建群种的洲滩湿地,采取收获法测定了灰化苔草4个生长季的地上、地下生物量及净初级生产力(NPP)。结果表明:1)苔草地上、地下生物量均具有明显的季节变化模式,变化范围分别为14608~1 77067 、1 80627~4 03256 g/m2;地下生物量与地上生物量的比例变化范围为208~1744,平均值为519。2)苔草地上地下生物量、NPP均表现为春季高于秋季。3)受洲滩淹水时间影响,苔草生物量、NPP具有显著的年际差异, 2010~2011年度苔草NPP仅相当于2009~2010年度的625%;NPP的下降地上部分较地下部分更明显。4)鄱阳湖湿地苔草固碳潜力巨大,2个年度固碳量分别为1 92383,1 23121 gC/m2  相似文献   
46.
江苏阳澄湖螺类群落的空间分布格局   总被引:3,自引:0,他引:3  
2008年1月~2009年10月对江苏阳澄湖螺类群落结构进行了季节调查研究。共采集到螺类4科5属6种,优势种为铜锈环棱螺,次优种为长角涵螺。阳澄湖螺类平均密度为220±47 ind./m2,平均生物量为2331±469 g/m2,螺类密度和生物量在年际和季节间均无明显差异,但群落结构存在显著的空间变化,密度在东湖区和中华绒螯蟹围网养殖区较大、西湖区最小,生物量围网养殖区最高、西湖区最低;铜锈环棱螺密度围网养殖区最高、西湖区最低,长角涵螺密度东湖区最高、围网养殖区次之、入湖河流及其它湖区极低。中华绒螯蟹养殖未导致围网养殖区螺类数量下降,螺类(主要是铜锈环棱螺)的投放可能是该区螺类密度、生物量及铜锈环棱螺所占比例较高的主要原因之一。逐步回归分析表明,水深是影响螺类群落整体密度和生物量空间分布差异的主要因子;典型对应分析(CCA)表明,铜锈环棱螺主要分布在叶绿素a较高的水域,而长角涵螺和纹沼螺则主要分布在透明度较大的地方  相似文献   
47.
人粪便中温好氧堆肥过程的有机物降解特性研究   总被引:2,自引:1,他引:1  
白帆  王晓昌 《环境工程学报》2011,5(8):1863-1866
利用密闭式小型堆肥反应器,以锯末作为堆肥载体,采用批量反应的操作方式,在35℃的温控条件下进行了人粪便的中温好氧堆肥实验。结果表明,在14 d的堆肥反应周期内,粪便中以COD为参数的有机物去除率可达到70%左右,且在10~12 d内基本完成有机物降解。在中温条件下,堆体容易保持适宜的含水率和pH值,维持适宜微生物繁殖生长的条件。运用磷脂法进行堆肥过程中微生物总量的分析,表明在一个堆肥周期内,微生物经历了环境适应期、稳定增殖期、生物量下降期等3个阶段,这一微生物繁衍规律与有机物的去除密切相关。与高温堆肥相比,中温堆肥能够减少设备加热的能量消耗,是缺水地区人粪便处置的可选方法之一。  相似文献   
48.
In this article, the technical feasibility of the use of activated carbon, synthetic resins, and various low-cost natural adsorbents for the removal of phenol and its derivatives from contaminated water has been reviewed. Instead of using commercial activated carbon and synthetic resins, researchers have worked on inexpensive materials such as coal fly ash, sludge, biomass, zeolites, and other adsorbents, which have high adsorption capacity and are locally available. The comparison of their removal performance with that of activated carbon and synthetic resins is presented in this study. From our survey of about 100 papers, low-cost adsorbents have demonstrated outstanding removal capabilities for phenol and its derivatives compared to activated carbons. Adsorbents that stand out for high adsorption capacities are coal-reject, residual coal treated with H3PO4, dried activated sludge, red mud, and cetyltrimethylammonium bromide-modified montmorillonite. Of these synthetic resins, HiSiv 1000 and IRA-420 display high adsorption capacity of phenol and XAD-4 has good adsorption capability for 2-nitrophenol. These polymeric adsorbents are suitable for industrial effluents containing phenol and its derivatives as mentioned previously. It should be noted that the adsorption capacities of the adsorbents presented here vary significantly depending on the characteristics of the individual adsorbent, the extent of chemical modifications, and the concentrations of solutes.  相似文献   
49.
Two acrylic adsorbents with different morphological structures and bearing amidoethylenamine and thiol groups were obtained and used for platinum sorption from chloride solution by the batch method. Physico-chemical parameters that influence adsorption such as initial Pt(IV) concentration, stirring time, pH, and adsorbent amount were investigated. The thermodynamic parameters of Pt(IV) sorption on the synthesized adsorbent were also evaluated based on Langmuir and Freundlich isotherms. Thermodynamic parameters estimated from Langmuir constants indicated that the adsorption is spontaneous, exothermic and there is a disordered state at the molecular level. The models used to analyze the sorption rate led to the conclusion that the most important step in the sorption of Pt(IV) could be both particle diffusion and chemical reaction of [PtCl6] with amine functional groups. Thus, both the ion exchange and complex formation mechanisms can occur via nitrogen atoms in the recovery of Pt(IV) on the studied adsorbent.  相似文献   
50.
Abstract

The soil oxidative and anaerobic processes, as well as, the microbial biomass were followed during three years in a cotton farm (Tatuí) where the recommended pesticides have been used for several years, and in an experimental field (São Paulo) treated first time with the same pesticides. The oxidative process was monitored by the dehydrogenase (DHA)‐activity using triphenyltetrazolium chloride (TTC) as substrate. The anaerobic process was followed by the iron‐oxide reduction, and the microbial biomass was estimated by the substrate (glucose)‐indiced respiration. Increases in DHA‐activity and in the microbial biomass occurred only in the farm soil, with concomitant decreases in iron‐reduction. In the experimental field soil, the increases in DHA‐activity were followed only by decreases in iron‐reduction. Soil characteristics were the determining factor for different biological parameters after pesticide inputs. All the pesticides produced at least one clear but transient effect.  相似文献   
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