全文获取类型
收费全文 | 800篇 |
免费 | 101篇 |
国内免费 | 344篇 |
专业分类
安全科学 | 52篇 |
废物处理 | 80篇 |
环保管理 | 52篇 |
综合类 | 592篇 |
基础理论 | 164篇 |
污染及防治 | 194篇 |
评价与监测 | 62篇 |
社会与环境 | 10篇 |
灾害及防治 | 39篇 |
出版年
2024年 | 3篇 |
2023年 | 11篇 |
2022年 | 29篇 |
2021年 | 32篇 |
2020年 | 38篇 |
2019年 | 29篇 |
2018年 | 42篇 |
2017年 | 36篇 |
2016年 | 53篇 |
2015年 | 57篇 |
2014年 | 50篇 |
2013年 | 136篇 |
2012年 | 84篇 |
2011年 | 54篇 |
2010年 | 51篇 |
2009年 | 55篇 |
2008年 | 58篇 |
2007年 | 64篇 |
2006年 | 64篇 |
2005年 | 58篇 |
2004年 | 30篇 |
2003年 | 29篇 |
2002年 | 24篇 |
2001年 | 27篇 |
2000年 | 28篇 |
1999年 | 19篇 |
1998年 | 18篇 |
1997年 | 9篇 |
1996年 | 10篇 |
1995年 | 13篇 |
1994年 | 6篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1973年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有1245条查询结果,搜索用时 15 毫秒
131.
利用毛细管气相色谱法测定水和废水中的丙烯酰胺 总被引:4,自引:2,他引:4
本文采用毛细管色谱法建立了水和废水中丙烯酰胺的测定程序。以活性炭柱吸附、浓缩样品中的丙烯酰胺,用甲醇洗脱,洗脱液用FID测定。方法回收率为83.1~99.0%,相对标准偏差为5.34%,检出限为0.016mg/L。 相似文献
132.
133.
The effect of methanol of low concentration on adsorption and leaching of atrazine and tebuconazole was studied in this paper. The adsorption coefficients and the retardation factors (Rm) of pesticides on EUROSOIL 3# log-linearly decreased as volumetric fraction of methanol (fc) was increased in the binary solvent mixtures of methanol and water. These data are consistent with solvophobic theory formerly outlined for describing the adsorption and transport of hydrophobic organic chemicals from mixed solvents. Nevertheless, the adsorption of these pesticides in soil–water system slightly increased when the soil was pre-washed with methanol in comparison with that pre-washed with water (pure water system). Furthermore, their adsorption coefficients were still higher in binary solvent systems with methanol of very low concentrations, i.e. fc<0.03 for atrazine and fc<0.01 for tebuconazole, than those in pure water system. The adsorption coefficients (logKw) of atrazine and tebuconazole predicted by solvophobic theory were 0.5792 and 1.6525, respectively, and their experimental logKw were 0.3701 and 1.6275 in pure water system. Obviously, the predicted logKw of the two pesticides was higher than the experimental log Kw in pure water system. The predicted Kw and the retardation factor (Rw) in pure water system by solvophobic theory are thus possibly inaccurate. 相似文献
134.
柱生物曝气法吸附处理含铬废水 总被引:7,自引:0,他引:7
利用复合生物吸附剂FY01与活性污泥作为吸附材料,探讨了柱式生物曝气法对高浓度含铬电镀废水的生物吸附效果。研究结果表明,FY01性能稳定,耐进水pH冲击能力较强。当进水pH=2—5、流速为500mL/h时,10gFY01和5g活性污泥联合处理60.4mg/L含铬电镀废水2h后,铬的去除率达78%以上;在4℃冰箱和23—28℃实验室保存50d的FY01对铬的去除分别在78%~83%和77%-84%之间。柱式生物曝气吸附法对含铬废水的处理效果理想,运行稳定。串联处理2000mL总Cr、Cu^2+和COD浓度分别为60.4、4.51和48.2mg/L的电镀废水2h后,去除率分别高达92.1%、99.2%和71.4%。 相似文献
135.
高气泡表面积通量浮选柱气浮除藻的研究 总被引:1,自引:0,他引:1
湖泊、水库等水源的富营养化,使藻类去除成为饮用水生产的重要任务。本研究采用高气泡表面积通量浮选柱气浮除藻,考察了混凝剂、气泡表面积通量和浮选柱高度等因素的影响。试验表明,高气泡表面积通量浮选柱气浮可高效地去除绿藻、硅藻和蓝藻,叶绿素a和藻类去除率达95%以上,比传统浮选柱气浮和沉降作业有较大幅度提高。与普通气浮柱比较,高气泡表面积通量浮选柱增加了气泡与藻的碰撞几率,防止因大表观充气速率造成的紊流和扰动,使气泡/藻结合体有相对静态的浮升环境,避免了气泡/藻结合体在浮升过程中的脱落,实现对藻类的迅速捕集和转移。 相似文献
136.
Yangtze River Delta(YRD) area is one of the important economic zones in China. However,this area faces increasing environmental problems. In this study, we use ground-based multi-axis differential optical absorption spectroscopy(MAX-DOAS) network in Eastern China to retrieve variations of NO_2, SO_2, and formaldehyde(HCHO) in the YRD area. Three cities of YRD(Hefei, Nanjing, and Shanghai) were selected for long-term observations. This paper presents technical performance and characteristics of instruments, their distribution in YRD, and results of vertical column densities(VCDs) and profiles of NO_2, SO_2, and HCHO.Average diurnal variations of tropospheric NO_2 and SO_2 in different seasons over the three stations yielded minimum values at noon or in the early afternoon, whereas tropospheric HCHO reached the maximum during midday hours. Slight reduction of the pollutants in weekends occurred in all the three sites. In general trace gas concentrations gradually reduced from Shanghai to Hefei. Tropospheric VCDs of NO_2, SO_2, and HCHO were compared with those from Ozone Monitoring Instrument(OMI) satellite observations, resulting in R~2 of 0.606, 0.5432, and 0.5566, respectively. According to analysis of regional transports of pollutants, pollution process happened in YRD under the north wind with the pollution dissipating in the southeast wind. The feature is significant in exploring transport of tropospheric trace gas pollution in YRD, and provides basis for satellite and model validation. 相似文献
137.
改性粉煤灰在处理锑矿选矿废水中的应用 总被引:9,自引:1,他引:8
针对锑矿选矿废水中锑和丁基黄原酸钠严重超标的问题,用酸改性粉煤灰对其进行吸附处理.试验结果表明,当改性粉煤灰处理选矿废水的最佳质量体积比(g.mL-1)为1:100,pH值为3,静置时间为4h时,可以将选矿废水中的锑浓度从28.611mg.L-1降到0.05mg.L-1以下,去除率达99.8%以上;废水中的丁基黄原酸钠浓度可从0.373mg.L-1降到0.02mg.L-1以下,去除率达95.0%以上.处理废水后的改性粉煤灰用硫酸-硝酸浸提,浸出液中重金属离子浓度均低于国家浸出毒性标准,表明改性粉煤灰是一种很好的锑矿选矿废水处理剂. 相似文献
138.
文章主要研究模拟高放废液加入沸石预处理经碱矿渣水泥固化后Cs+的浸出性能。实验结果表明,处理含Cs+高放废液固化体中加入沸石,能使Cs+浸出率降低";两步法"掺入沸石固化体抗Cs+浸出性能更有所提高;pH值升高Cs+的吸附比增大。 相似文献
139.
140.