石墨炉原子吸收光谱法测定海河下游水中痕量镉

原子吸收光谱法直接测定高盐水中痕量镉时,有很大背景吸收和误差。本文采用络合—萃取技术使共存元素与待测元素分离,既消除了基体干扰,又达到了富集作用,使测定结果准确可靠。     

2,4-dichlorophenoxyacetic acid (2,4-D) micropollutant herbicide removing from water using granular and powdered activated carbons: a comparison applied for water treatment and health safety

Abstract

Activated carbons are well-known porous materials as an effective adsorbent used for the removal of emerging contaminants, such as herbicides, which are increasingly present in water bodies. Most water treatment plants, specially in Brazil, are unable to completely remove such contaminants by the conventional process and advanced treatment using activated carbons is required. The aim of this paper was to verify the influence of the activated carbons granulometry and specific surface area on the 2,4-dichlorophenoxyacetic acid (2,4-D) herbicide removal efficiency using distilled-deionized water and filtered water collected from a conventional Water Treatment Plant. Commercial activated carbons samples used in this work were obtained from two different manufacturers. Activated carbons were analyzed by the specific surface area, pore size and volume distribution, nuclear magnetic resonance, infrared and x-ray spectroscopy, moisture, volatile matter and ash contents. Batch adsorption isotherms experiments were used and performed by Langmuir and Freundlich models. Granular and powdered activated carbons removed over 99% of 2,4-D in distilled water and near to 99% using filtered water. The activated carbons evaluated in this work presented high performance and played a key role in water treatment by removing 2,4-D herbicide, ensuring the protection of human health and the ecosystem.     

机械加T振动公害控制

根据多年从事机械、环保科研设计及工厂的实践,仔细分析了机械加工振动污染源对操作者及周围居民的危害.并提出了对其所造成的公害进行适应控制的基本措施.     

丰水期乌江上游干流水库-河流体系硫同位素组成

2007年7月对乌江上游河流、乌江干流上的3座不同库龄的梯级水库（洪家渡水库、东风水库、乌江渡水库）表层及垂直剖面水体的可溶性硫酸盐的硫同位素组成进行了研究。在垂直剖面上，洪家渡水库硫同位素值（δ34S）介于+03‰~+31‰，下泄水为-07‰；东风水库δ34S值介于-75‰~-55‰，下泄水为-68‰；乌江渡水库δ34S值介于-43‰~-06‰，下泄水为-29‰。上述结论表明，硫同位素组成变化反映了水库硫的不同来源及生物地球化学过程。不同水库表层和垂直剖面水体的硫同位素平均值有差别，水库表层的硫同位素比值主要受输入水体的控制，垂直剖面由表层向下硫同位素比值偏负，主要是由于生物作用以及有机硫的氧化造成的。     

论高科技发展与环境承载力

本文从高科技发展角度论述了高科技发展与环境承载力之间的关系,并对已有的环境承载力理论做了补充和改进,使之更能体现可持续发展的新发展观。本文还对不同国家在处理高科技发展与可持续发展关系的途径做了概要阐释。最后指出,高科技污染也是一个不容忽视的问题。     

UNCERTAINTY OF EXTREME FLOOD ESTIMATES INCORPRATING HISTORICAL DATA1

ABSTRACT: The ability to predict extreme floods is an important part of the planning process for any water project for which failure will be very costly. The length of a gage record available for use in estimating extreme flows is generally much shorter than the recurrence interval of the desired flows, resulting in estimates having a high degree of uncertainty. Maximum likelihood estimators of the parameters of the three parameter lognormal (3PLN) distribution, which make use of historical data, are presented. A Monte Carlo study of extreme flows estimated from samples drawn from three hypothetical 3PLN populations showed that inclusion of historical flows with the gage record reduced the bias and variance of extreme flow estimates. Asymptotic theory approximations of parameter variances and covariances calculated using the second and mixed partial derivatives of the log likelihood function agreed well with Monte Carlo results. First order approximations of the standard deviations of the extreme flow estimates did not agree with the Monte Carlo results. An alternative method for calculating those standard deviations, the “asymptotic simulation” method, is described. The standard deviations calculated by asymptotic simulation agree well with the Monte Carlo results.     

区域优势自然资源的评价——以河南省黄河两岸地区为例

本文试图从区域、自然资源本身和资源的外部条件出发,通过分析区域优势自然资源的概念,选择建立了衡量区域优势自然资源的6项标准体系,并以河南省黄河两岸地区为例,借助与高层次区域的比较研究,确定了该区域的优势自然资源是:铝土矿为第一优势资源,天然气为第二优势资源,以下资源次序为石油、煤、金矿、水泥灰岩、耐火粘土和水资源等。这为合理开发区域优势自然资源提供了重要科学依据.     

HYDROLOGIC RESPONSES OF AN AGRICULTURAL WATERSHED TO VARIOUS HYDROLOGIC AND MANAGEMENT CONDITIONS1

ABSTRACT: The hydrologic responses from an agricultural watershed in southeast Nebraska were investigated under an array of physiographic, hydrologic, meteorologic, and management conditions. For analytical purposes, the hydrologic responses were narrowed to include only runoff and sediment yield. The study was performed by utilizing the ANSWERS (Areal Nonpoint Source Watershed Environment Response Simulation) hydrologic-simulation model. Results of this study indicate that, generally, nonstructural (agronomic) Best Management Practices (BMPs) have a more significant impact in controlling erosion and nonpoint-source pollution than structurally oriented BMPs. The percentage of reduction in average soil loss as a result of changing tilage systems from conventional to chisel plow was in the mid-40s. The corresponding percentages of reduction in sediment yield from the watershed under minimum tillage and no-till systems were in the mid-60s and mid-80s, respectively. The impact of these management strategies on runoff varied considerably. That is primarily based on the watershed's antecedent soil moisture condition, land use, and the growth stage of crops. Generally, an intense, short, thunderstorm type of rainfall event had more relative impact on runoff, and therefore sediment yield than a long, gentle, and steady event.     

江西某地"癌症高发区"地质环境现状及评价

江西某地“癌症高发区”的报道引起了社会的广泛关注。通过对该地土壤、水体、降尘地质环境调查评价,认为调查区土壤环境质量较好,为清洁区,仅镍元素达轻度污染级。地下水质量为较差级,外围为优良级。饮用水源地水质综合评价为较差级,有机氯农药检出2项,多环芳烃检出10项,萘达到轻度污染级。区域地质、水文地质背景不具特殊性,土壤、水体地质环境与周边南昌地区无明显异常,是否与癌症发病有直接的关系,尚需作进一步的调查研究工作。降尘污染较为严重,污染因子主要为镉,应引起重视。     

化学需氧量-重铬酸钾法结果出现偏差原因的探讨

水样的化学需氧量,可由于加入氧化剂的种类及浓度,反应溶液的酸度,反应温度和时间,以及催化剂的有无而获得不同的结果.因此,化学需氧量亦是一个条件性的指标,必须严格按操作步骤进行.